公开(公告)号：WO2012166402A3

公开(公告)日：2012-12-06

申请号：PCT/US2012/038747

申请日：2012-05-21

Applicant: UOP LLC ,  TRAYNOR, Thomas ,  BRANDVOLD, Timothy A. ,  ABRAHAMIAN, Jennifer F.

Inventor： TRAYNOR, Thomas ,  BRANDVOLD, Timothy A. ,  ABRAHAMIAN, Jennifer F.

IPC: C10G45/08 ,  B01J23/28 ,  B01J23/74 ,  C10G3/00 ,  C10G65/00

Abstract: Embodiments of methods and catalysts for deoxygenating a biomass-derived pyrolysis oil are provided. The method comprises the step of contacting the biomass-derived pyrolysis oil with a first deoxygenating catalyst in the presence of hydrogen at first predetermined hydroprocessing conditions to form a first low-oxygen biomass-derived pyrolysis oil effluent. The first deoxygenating catalyst comprises a neutral catalyst support, nickel, cobalt, and molybdenum. The first deoxygenating catalyst comprises nickel in an amount calculated as an oxide of from 0.1 to 1.5 wt. %.

公开(公告)号：WO2012166402A2

公开(公告)日：2012-12-06

申请号：PCT/US2012038747

申请日：2012-05-21

Applicant: UOP LLC ,  TRAYNOR THOMAS ,  BRANDVOLD TIMOTHY A ,  ABRAHAMIAN JENNIFER F

Inventor： TRAYNOR THOMAS ,  BRANDVOLD TIMOTHY A ,  ABRAHAMIAN JENNIFER F

IPC: C10G45/08 ,  B01J23/28 ,  B01J23/74 ,  C10G3/00 ,  C10G65/00

CPC classification number: B01J23/883 ,  C10G3/46 ,  C10G65/04 ,  C10G2300/1011 ,  Y02P30/20

Abstract: Embodiments of methods and catalysts for deoxygenating a biomass-derived pyrolysis oil are provided. The method comprises the step of contacting the biomass-derived pyrolysis oil with a first deoxygenating catalyst in the presence of hydrogen at first predetermined hydroprocessing conditions to form a first low-oxygen biomass-derived pyrolysis oil effluent. The first deoxygenating catalyst comprises a neutral catalyst support, nickel, cobalt, and molybdenum. The first deoxygenating catalyst comprises nickel in an amount calculated as an oxide of from 0.1 to 1.5 wt. %.

Abstract translation: 提供了用于脱氧生物质衍生的热解油的方法和催化剂的实施方案。 该方法包括在第一预定加氢处理条件下，在氢存在下使生物质衍生的热解油与第一脱氧催化剂接触的步骤，以形成第一低氧生物质衍生的热解油流出物。 第一脱氧催化剂包括中性催化剂载体，镍，钴和钼。 第一脱氧催化剂包含以0.1至1.5重量％的氧化物计算的量的镍。 ％。

公开(公告)号：WO2012018520A3

公开(公告)日：2012-05-10

申请号：PCT/US2011044498

申请日：2011-07-19

Applicant: UOP LLC ,  TRAYNOR THOMAS ,  BRANDVOLD TIMOTHY A ,  ABRAHAMIAN JENNIFER F

Inventor： TRAYNOR THOMAS ,  BRANDVOLD TIMOTHY A ,  ABRAHAMIAN JENNIFER F

IPC: C10G45/04 ,  C10G3/00 ,  C10G45/08 ,  C10G45/10 ,  C10L1/02

CPC classification number: C10L1/02 ,  C10L1/04 ,  Y02P30/20

Abstract: Methods for deoxygenating treated biomass-derived pyrolysis oil are provided. The treated biomass-derived pyrolysis oil is exposed to a catalyst having a neutral catalyst support such as a non-alumina metal oxide support, a theta alumina support, or both. The non-alumina metal oxide support may be a titanium oxide (TiO2) support, a silicon oxide support, a zirconia oxide (ZrO2) support, a niobium oxide (Nb2O5) support, or a support having a mixture of non-alumina metal oxides. The catalyst may include a noble metal or a Group VIII non-noble metal and a Group VIB non-noble metal on the neutral catalyst support. The treated biomass-derived pyrolysis oil is introduced into a hydroprocessing reactor in the presence of the catalyst under hydroprocessing conditions to produce low oxygen biomass-derived pyrolysis oil.

Abstract translation: 提供了用于使经处理的生物质衍生的热解油脱氧的方法。 将经处理的生物质衍生的热解油暴露于具有中性催化剂载体（例如非氧化铝金属氧化物载体，θ氧化铝载体或两者）的催化剂。 非氧化铝金属氧化物载体可以是氧化钛（TiO 2）载体，氧化硅载体，氧化锆（ZrO 2）载体，氧化铌（Nb 2 O 5）载体或具有非氧化铝金属氧化物混合物的载体 。 催化剂可以在中性催化剂载体上包含贵金属或第VIII族非贵金属和第VIB族非贵金属。 处理的生物质衍生的热解油在加氢处理条件下在催化剂存在下加入加氢处理反应器中以产生低氧生物质衍生的热解油。

公开(公告)号：WO2012018520A2

公开(公告)日：2012-02-09

申请号：PCT/US2011/044498

申请日：2011-07-19

Applicant: UOP LLC ,  TRAYNOR, Thomas ,  BRANDVOLD, Timothy, A. ,  ABRAHAMIAN, Jennifer, F.

Inventor： TRAYNOR, Thomas ,  BRANDVOLD, Timothy, A. ,  ABRAHAMIAN, Jennifer, F.

IPC: C10G45/04 ,  C10G3/00 ,  C10L1/02 ,  C10G45/08 ,  C10G45/10

CPC classification number: C10L1/02 ,  C10L1/04 ,  Y02P30/20

Abstract: Methods for deoxygenating treated biomass-derived pyrolysis oil are provided. The treated biomass-derived pyrolysis oil is exposed to a catalyst having a neutral catalyst support such as a non-alumina metal oxide support, a theta alumina support, or both. The non-alumina metal oxide support may be a titanium oxide (TiO2) support, a silicon oxide support, a zirconia oxide (ZrO2) support, a niobium oxide (Nb2O5) support, or a support having a mixture of non-alumina metal oxides. The catalyst may include a noble metal or a Group VIII non-noble metal and a Group VIB non-noble metal on the neutral catalyst support. The treated biomass-derived pyrolysis oil is introduced into a hydroprocessing reactor in the presence of the catalyst under hydroprocessing conditions to produce low oxygen biomass-derived pyrolysis oil.

Abstract translation: 提供了处理过的生物质衍生的热解油的脱氧方法。 将经处理的生物质衍生的热解油暴露于具有中性催化剂载体的催化剂，例如非氧化铝金属氧化物载体，θ氧化铝载体或两者。 非氧化铝金属氧化物载体可以是氧化钛（TiO 2）载体，氧化硅载体，氧化锆（ZrO 2）载体，氧化铌（Nb 2 O 5）载体或具有非氧化铝金属氧化物的混合物的载体 。 催化剂可以在中性催化剂载体上包括贵金属或VIII族非贵金属和VIB族非贵金属。 经处理的生物质衍生的热解油在加氢处理条件下在催化剂存在下引入加氢处理反应器，以产生低氧生物质衍生的裂解油。

公开(公告)号：WO2011097127A3

公开(公告)日：2011-12-08

申请号：PCT/US2011022907

申请日：2011-01-28

Applicant: UOP LLC ,  KRAWCZYK MARK A ,  POPP KRISTOFFER E ,  NICHOLAS CHRISTOPHER P ,  ABRAHAMIAN JENNIFER F

Inventor： KRAWCZYK MARK A ,  POPP KRISTOFFER E ,  NICHOLAS CHRISTOPHER P ,  ABRAHAMIAN JENNIFER F

IPC: C07C6/04 ,  B01J23/30 ,  B01J37/02 ,  B01J37/08 ,  C07C11/06

CPC classification number: B01J23/30 ,  B01J21/08 ,  B01J35/1019 ,  B01J35/1023 ,  B01J37/0207 ,  B01J37/06 ,  C07C6/04 ,  C07C2521/08 ,  C07C2523/30 ,  Y02P20/52 ,  Y02P20/582 ,  C07C11/06

Abstract: Acid washing of silica supports, used for supported tungsten catalysts, improves the activity of the resulting catalyst (i.e., its conversion level at a given temperature) for the metathesis of olefins, without compromising its selectivity to the desired conversion product(s). Exemplary catalysts and processes include those for the production of valuable light olefins such as propylene from a hydrocarbon feedstock comprising ethylene and butylene.

Abstract translation: 用于负载型钨催化剂的二氧化硅载体的酸洗可改善所得催化剂的活性（即其在给定温度下的转化水平）用于烯烃复分解，而不损害其对所需转化产物的选择性。 示例性的催化剂和工艺包括用于从包含乙烯和丁烯的烃原料生产有价值的轻质烯烃如丙烯的那些催化剂和工艺。

公开(公告)号：WO2011097127A2

公开(公告)日：2011-08-11

申请号：PCT/US2011/022907

申请日：2011-01-28

Applicant: UOP LLC ,  KRAWCZYK, Mark A. ,  POPP, Kristoffer E. ,  NICHOLAS, Christopher P. ,  ABRAHAMIAN, Jennifer F.

Inventor： KRAWCZYK, Mark A. ,  POPP, Kristoffer E. ,  NICHOLAS, Christopher P. ,  ABRAHAMIAN, Jennifer F.

IPC: C07C6/04 ,  C07C11/06 ,  B01J23/30 ,  B01J37/02 ,  B01J37/08

CPC classification number: B01J23/30 ,  B01J21/08 ,  B01J35/1019 ,  B01J35/1023 ,  B01J37/0207 ,  B01J37/06 ,  C07C6/04 ,  C07C2521/08 ,  C07C2523/30 ,  Y02P20/52 ,  Y02P20/582 ,  C07C11/06

Abstract: Acid washing of silica supports, used for supported tungsten catalysts, improves the activity of the resulting catalyst (i.e., its conversion level at a given temperature) for the metathesis of olefins, without compromising its selectivity to the desired conversion product(s). Exemplary catalysts and processes include those for the production of valuable light olefins such as propylene from a hydrocarbon feedstock comprising ethylene and butylene.

Abstract translation: 用于支撑的钨催化剂的二氧化硅载体的酸洗可改善所得催化剂的活性（即，在给定温度下的转化水平）用于烯烃的复分解，而不损害其对所需转化产物的选择性。 示例性催化剂和方法包括用于从包含乙烯和丁烯的烃原料生产有价值的轻质烯烃如丙烯的催化剂和方法。