公开(公告)号：WO2017089339A1

公开(公告)日：2017-06-01

申请号：PCT/EP2016/078411

申请日：2016-11-22

Applicant: SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. ,  SHELL OIL COMPANY

Inventor： URADE, Vikrant, Nanasaheb ,  DEL PAGGIO, Alan, Anthony ,  MEHTA, Dhairya, Dilip ,  CHILKOOR SOUNDARARAJAN, Laxmi, Narasimhan

IPC: C10G1/06 ,  C10G1/08 ,  C10G3/00 ,  C10G45/48 ,  C10G45/52 ,  C10G45/06 ,  C10G45/10

CPC classification number: C10G1/06 ,  C10G1/086 ,  C10G3/45 ,  C10G3/46 ,  C10G3/50 ,  C10G45/06 ,  C10G45/10 ,  C10G45/48 ,  C10G45/52 ,  Y02P30/20

Abstract: The present invention provides a process for producing liquid hydrocarbon products from at least one of a biomass-containing feedstock and a biomass-derived feedstock, said process comprising the steps of: a) contacting the biomass-containing feedstock and/or biomass-derived feedstock with a hydropyrolysis catalyst composition and molecular hydrogen in a hydropyrolysis reactor vessel at a temperature in the range of from 350 to 600°C, a pressure in the range of from 0.50 to 7.50MPa and a WHSV in the range of greater than 2.0 kg(biomass)/hour/kg(catalyst), to produce a product stream comprising a partially deoxygenated hydrocarbon product, H 2 O, H 2 , CO 2 , CO, C 1 - C 3 gases, char and catalyst fines; b) removing all or a portion of said char and catalyst fines from said product stream; c) cooling the remaining product stream to a temperature in the range of from 150 to 400°C; and d) hydroconverting all or a portion of said partially deoxygenated hydrocarbon product in a hydroconversion reactor in the presence of one or more catalyst compositions suitable for hydrodeoxygenation and aromatic saturation of the partially deoxygenated hydrocarbon product in the presence of H2O, CO2, CO, H2, and C1 - C3 gas generated in step a), to produce a vapour phase product comprising a C4+ hydrocarbon product, H2O, CO, CO2, and C1 – C3 gases.

Abstract translation: 本发明提供了从含生物质的原料和生物质衍生的原料中的至少一种生产液体烃产物的方法，所述方法包括以下步骤：a）将含生物质的原料 原料和/或生物质衍生的原料与加氢热解催化剂组合物和分子氢在加氢热解反应器容器中在350-600℃的温度范围内，0.50-7.50MPa的压力和 大于2.0kg（生物量）/小时/ kg（催化剂）的范围，以产生包含部分脱氧的烃产物H 2 O，H 2 O， ，CO 2，CO，C 1 -C 3气体，焦炭和催化剂细粒; b）从所述产品物流中除去全部或部分所述焦炭和催化剂细粒; c）将剩余的产物流冷却至150-400℃的温度; 和d）将所有或部分所述部分脱氧的烃产物在加氢转化反应器中在一种或多种催化剂组合物存在下加氢转化，所述催化剂组合物适于在H 2 O，CO 2，CO，H 2存在下使部分脱氧的烃产物加氢脱氧和芳族化合物饱和 和步骤a）中产生的C 1 -C 3气体，以产生包含C 4+烃产物，H 2 O，CO，CO 2和C 1 -C 3气体的气相产物。

公开(公告)号：WO2016062868A1

公开(公告)日：2016-04-28

申请号：PCT/EP2015/074622

申请日：2015-10-23

Applicant: NESTE OIL OYJ

Inventor： MYLLYOJA, Jukka ,  PIILOLA, Rami ,  KETTUNEN, Mika

IPC: C10G3/00 ,  C07C45/48 ,  B01J23/04 ,  C10G65/04

CPC classification number: C07C45/48 ,  B01J21/063 ,  B01J23/04 ,  B01J23/42 ,  B01J23/883 ,  B01J29/85 ,  B01J35/0006 ,  C10G3/42 ,  C10G3/46 ,  C10G3/47 ,  C10G3/50 ,  C10G45/58 ,  C10G65/043 ,  C10G2300/1011 ,  C10G2400/10 ,  Y02P30/20 ,  C07C49/04

Abstract: The present invention relates to a method for producing ketones which method comprises the steps of: a) providing a feedstock of biological origin comprising fatty acids and/or fatty acid derivatives having an average chain length of 24 C-atoms or less, b) subjecting said feedstock to a catalytic ketonisation reaction in the presence of a K 2 O/TiO 2 -catalyst, c) obtaining from said ketonisation reaction a product stream comprising ketones, which ketones have a longer average hydrocarbon chain length than the average hydrocarbon chain length in said feedstock, wherein step b) is carried out directly on said feedstock and in the presence of said K 2 O/TiO 2 -catalyst as the sole catalyst applied in said ketonisation reaction.

Abstract translation: 本发明涉及一种生产酮的方法，该方法包括以下步骤：a）提供生物来源的原料，其包含平均链长为24个C原子或更少的脂肪酸和/或脂肪酸衍生物，b） 所述原料在K 2 O / TiO 2 - 催化剂存在下进行催化酮化反应，c）从所述酮化反应获得包含酮的产物流，所述酮具有比所述原料中的平均烃链长更长的平均烃链长度， 其中步骤b）直接在所述原料上并在所述K 2 O / TiO 2催化剂存在下作为在所述酮化反应中应用的唯一催化剂进行。

公开(公告)号：WO2016003892A1

公开(公告)日：2016-01-07

申请号：PCT/US2015/038297

申请日：2015-06-29

Applicant: GAS TECHNOLOGY INSTITUTE

Inventor： FELIX, Larry, G. ,  LINCK, Martin, B. ,  MARKER, Terry, L. ,  ROBERTS, Michael, J.

IPC: C01B3/34 ,  C10G3/00 ,  C10K1/32 ,  C10G1/06

CPC classification number: C10G1/002 ,  C01B3/34 ,  C01B2203/0233 ,  C01B2203/0405 ,  C01B2203/043 ,  C01B2203/062 ,  C01B2203/1235 ,  C01B2203/1264 ,  C01B2203/148 ,  C10G1/06 ,  C10G3/42 ,  C10G3/46 ,  C10G3/50 ,  C10G3/52 ,  C10G2300/1003 ,  C10K1/32 ,  Y02P30/20

Abstract: Various techniques are disclosed for pretreating municipal solid waste (MSW) and other biomass-containing feedstocks that may be of a poorer quality and consequently more difficult, or even impossible, to convert to higher value liquid products (e.g., transportation fuels) using conventional processes. Such conventional processes may otherwise be satisfactory for the conversion of the biomass portion of the feedstock alone. The pretreatment of biomass-containing feedstocks may generally include steps carried out prior to a hydropyrolysis step and optionally further steps, in order to change one or more characteristics of the feedstock, rendering it more easily upgradable.

Abstract translation: 公开了各种技术用于预处理城市固体废物（MSW）和其他可能具有较差质量的生物质原料，因此更难或甚至不可能使用常规方法转化为更高价值的液体产品（例如运输燃料） 。 否则这种常规方法可能对于单独的原料的生物质部分的转化是令人满意的。 含生物质的原料的预处理通常可以包括在加氢热解步骤之前进行的步骤和任选的进一步的步骤，以改变原料的一种或多种特性，使其更容易升级。

公开(公告)号：WO2015144993A1

公开(公告)日：2015-10-01

申请号：PCT/FI2015/050208

申请日：2015-03-26

Applicant: NESTE OIL OYJ

Inventor： MYLLOJA, Jukka Pekka ,  PIILOLA, Rami

IPC: C10G50/00 ,  C10L1/06 ,  C10G3/00 ,  C07C59/347

CPC classification number: C07C51/353 ,  B01J21/04 ,  B01J21/063 ,  B01J21/08 ,  B01J23/002 ,  B01J23/04 ,  B01J23/10 ,  B01J23/30 ,  B01J23/883 ,  B01J35/002 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1019 ,  C07C51/367 ,  C07C59/347 ,  C07D307/33 ,  C10G3/46 ,  C10G3/47 ,  C10G3/48 ,  C10G3/50 ,  C10G50/00 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/04 ,  C10L1/06 ,  C10L1/08 ,  C10L2200/0469 ,  C10L2270/04 ,  Y02P30/20

Abstract: The present invention relates to catalytic conversion of ketoacids, including methods for increasing the molecular weight of ketoacids, the method comprising the steps of providing in a reactor a feedstock comprising at least one ketoacid. The feedstock is then subjected to one or more C-C-coupling reaction(s) in the presence of hydrogen, and in the presence of a catalyst system having both hydrogenation activity and C-C-coupling activity.

Abstract translation: 本发明涉及酮酸的催化转化，包括增加酮酸的分子量的方法，所述方法包括以下步骤：在反应器中提供包含至少一种酮酸的原料。 然后在氢存在下，在具有氢化活性和C-C偶联活性的催化剂体系的存在下，将原料进行一种或多种C-C偶联反应。

公开(公告)号：WO2015144856A1

公开(公告)日：2015-10-01

申请号：PCT/EP2015/056655

申请日：2015-03-26

Applicant: NESTE OIL OYJ

Inventor： LINDBLAD, Marina ,  IKONEN, Elias ,  SELÄNTAUS, Maaria ,  KÄLDSTRÖM, Mats

IPC: C10G50/00 ,  B01J35/10 ,  C07C59/347 ,  C10G3/00

CPC classification number: C07C51/353 ,  B01J21/04 ,  B01J21/063 ,  B01J21/08 ,  B01J23/002 ,  B01J23/04 ,  B01J23/10 ,  B01J23/30 ,  B01J23/883 ,  B01J35/002 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1019 ,  C07C51/367 ,  C07C59/347 ,  C07D307/33 ,  C10G3/46 ,  C10G3/47 ,  C10G3/48 ,  C10G3/50 ,  C10G50/00 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/04 ,  C10L1/06 ,  C10L1/08 ,  C10L2200/0469 ,  C10L2270/04 ,  Y02P30/20

Abstract: The present invention relates to catalytic conversion of ketoacids, including methods for increasing the molecular weight of ketoacids, the method comprising the steps of providing in a reactor a feedstock comprising at least one ketoacid. The feedstock is then subjected to one or more C-C-coupling reaction(s) in the presence of a catalyst system comprising a first metal oxide and a second metal oxide.

Abstract translation: 本发明涉及酮酸的催化转化，包括增加酮酸的分子量的方法，所述方法包括以下步骤：在反应器中提供包含至少一种酮酸的原料。 然后在包含第一金属氧化物和第二金属氧化物的催化剂体系的存在下，将原料进行一种或多种C-C偶联反应。

公开(公告)号：WO2015028677A1

公开(公告)日：2015-03-05

申请号：PCT/EP2014/068563

申请日：2014-09-02

Applicant: SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. ,  SHELL OIL COMPANY

Inventor： AZGHAY, Ali ,  ESPINOSA ALONSO, Leticia ,  FRANSSEN, Nicole Maria Gerarda ,  RIGUTTO, Marcello Stefano ,  SCHAVERIEN, Colin John

IPC: B01J23/755 ,  B01J37/02 ,  C10G1/00 ,  C10G3/00

CPC classification number: B01J23/755 ,  B01J21/08 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0018 ,  B01J37/0045 ,  B01J37/02 ,  B01J37/03 ,  C10G3/44 ,  C10G3/46 ,  C10G3/50 ,  C10G2300/1011 ,  Y02P30/20

Abstract: Process for converting a biomass-derived pyrolysis oil comprising the following steps: i) preparing a catalyst, preferably containing one or more Group VIII metals in an amount of equal to or more than 30wt%, based on the total weight of the catalyst, by a method including - mixing one or more Group VIII metal components; a waterborne refractory oxide component comprising a refractory oxide selected from the Group consisting of titania, zirconia, silica and mixtures thereof; and a water-soluble base; in an aqueous solvent to prepare an metal-containing aqueous mixture; and - subjecting the metal-containing aqueous mixture to precipitation conditions; and ii) contacting a feed containing the biomass-derived pyrolysis oil with hydrogen at a temperature in the range from 50°C to 350°C in the presence of the catalyst.

Abstract translation: 用于转化生物质衍生的热解油的方法，包括以下步骤：i）制备催化剂，优选含有基于催化剂总重量等于或大于30重量％的一种或多种第VIII族金属，通过 一种方法，包括 - 混合一种或多种VIII族金属组分; 包含选自二氧化钛，氧化锆，二氧化硅及其混合物的耐火氧化物的水性难熔氧化物组分; 和水溶性碱; 在水性溶剂中制备含金属的水性混合物; 和 - 对含金属的含水混合物进行沉淀条件; 和ii）在催化剂存在下，将含有生物质衍生的热解油的进料与氢气在50℃至350℃的温度下接触。

公开(公告)号：WO2014179302A3

公开(公告)日：2014-12-24

申请号：PCT/US2014035859

申请日：2014-04-29

Applicant: SHELL OIL CO ,  SHELL INT RESEARCH

Inventor： POWELL JOSEPH BROUN ,  BOS ALOUISIUS NICOLAAS RENEE ,  KLUSENER PETER ANTON AUGUST ,  PLOEMEN INGMAR HUBERTUS JOSEPHINA

IPC: C10G3/00 ,  C07C29/09 ,  C08H7/00 ,  C08L1/10 ,  C10G1/00 ,  C10G1/06 ,  C10G1/08

CPC classification number: C07C29/09 ,  C07B41/00 ,  C08H8/00 ,  C10G1/002 ,  C10G1/006 ,  C10G1/065 ,  C10G1/08 ,  C10G1/083 ,  C10G3/42 ,  C10G3/46 ,  C10G3/48 ,  C10G3/50 ,  C10G3/55 ,  C10G2300/1014 ,  Y02P30/20

Abstract: Maintaining long residence times during hydrothermal digestion of cellulosic biomass solids may be complicated by a number of factors, including biomass compaction. Advantages in this regard may be realized by digesting cellulosic biomass solids in an inclined digestion unit. Such methods can comprise: introducing cellulosic biomass solids to a hydrothermal digestion unit comprising one or more inclined surfaces therein; introducing a fluid phase digestion medium containing a slurry catalyst to the hydrothermal digestion unit, the slurry catalyst being capable of activating molecular hydrogen; supplying an upwardly directed flow of molecular hydrogen from a source disposed along each inclined surface as the cellulosic biomass solids descend along each inclined surface; and heating the cellulosic biomass solids as they descend along each inclined surface in the presence of the slurry catalyst and the molecular hydrogen, thereby forming an alcoholic component derived from the cellulosic biomass solids.

Abstract translation: 在热液消化纤维素生物质固体的过程中保持较长的停留时间可能会因许多因素而复杂化，包括生物质压实。 在这方面的优点可以通过在倾斜的消化装置中消化纤维素生物质固体来实现。 这种方法可以包括：将纤维素生物质固体引入其中包含一个或多个倾斜表面的水热消化单元; 将含有浆料催化剂的流体相消化介质引入到水热消化装置中，所述浆料催化剂能够活化分子氢; 当纤维素生物质固体沿着每个倾斜表面下降时，从沿着每个倾斜表面设置的源提供分子氢的向上指向流; 以及在浆料催化剂和分子氢存在下沿着每个倾斜表面下降时加热纤维素生物质固体，从而形成源自纤维素生物质固体的醇组分。

公开(公告)号：WO2014179302A2

公开(公告)日：2014-11-06

申请号：PCT/US2014/035859

申请日：2014-04-29

Applicant: SHELL OIL COMPANY ,  SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

Inventor： POWELL, Joseph Broun ,  BOS, Alouisius Nicolaas Renee ,  KLUSENER, Peter Anton August ,  PLOEMEN, Ingmar Hubertus Josephina

CPC classification number: C07C29/09 ,  C07B41/00 ,  C08H8/00 ,  C10G1/002 ,  C10G1/006 ,  C10G1/065 ,  C10G1/08 ,  C10G1/083 ,  C10G3/42 ,  C10G3/46 ,  C10G3/48 ,  C10G3/50 ,  C10G3/55 ,  C10G2300/1014 ,  Y02P30/20

Abstract: Maintaining long residence times during hydrothermal digestion of cellulosic biomass solids may be complicated by a number of factors, including biomass compaction. Advantages in this regard may be realized by digesting cellulosic biomass solids in an inclined digestion unit. Such methods can comprise: introducing cellulosic biomass solids to a hydrothermal digestion unit comprising one or more inclined surfaces therein; introducing a fluid phase digestion medium containing a slurry catalyst to the hydrothermal digestion unit, the slurry catalyst being capable of activating molecular hydrogen; supplying an upwardly directed flow of molecular hydrogen from a source disposed along each inclined surface as the cellulosic biomass solids descend along each inclined surface; and heating the cellulosic biomass solids as they descend along each inclined surface in the presence of the slurry catalyst and the molecular hydrogen, thereby forming an alcoholic component derived from the cellulosic biomass solids.

Abstract translation: 在纤维素生物质固体的热液消解过程中保持长停留时间可能由于诸如生物质压实的许多因素而复杂化。 在这方面的优点可以通过在倾斜的消化单元中消化纤维素生物质固体来实现。 这样的方法可以包括：将纤维素生物质固体引入包括其中的一个或多个倾斜表面的水热消解单元; 将含有浆料催化剂的流体相消解介质引入水热消解单元，该浆料催化剂能够活化分子氢; 当纤维素生物质固体沿着每个倾斜表面下降时，从沿着每个倾斜表面设置的源供应向上指向的分子氢流; 以及在浆料催化剂和分子氢存在下沿着每个倾斜表面下降时加热纤维素生物质固体，从而形成衍生自纤维素生物质固体的醇组分。

公开(公告)号：WO2014167181A1

公开(公告)日：2014-10-16

申请号：PCT/FI2014/050251

申请日：2014-04-08

Applicant: STORA ENSO OYJ

Inventor： RÄSÄNEN, Jari ,  HARLIN, Ali ,  AALTONEN, Olli ,  LINNEKOSKI, Juha ,  ANTHONYKUTTY, Jinto

IPC: C10G3/00 ,  C07C1/207 ,  C07C4/06 ,  C07C11/02 ,  C07C15/08 ,  C07C51/265 ,  C10G45/02 ,  C10G49/04 ,  C10G65/12

CPC classification number: C10G3/50 ,  C07C4/06 ,  C07C51/16 ,  C07C51/265 ,  C10G3/46 ,  C10G3/49 ,  C10G9/36 ,  C10G2300/1014 ,  Y02P30/20 ,  C07C63/06

Abstract: The present invention relates to a method of deoxygenating tall oil pitch, yielding aliphatic and aromatic hydrocarbons. The invention even comprises turning the aliphates into polymerizable olefins by steam cracking, and turning the aromates into polymerizable terephthalic acid by oxygenation and, as necessary, rearrangement. The monomers can be used for the production of polymers of partially or completely biologic origin. According to the invention, tall oil pitch is first heated to turn it into liquid, which is then fed into a catalyst bed and catalytically deoxygenated with hydrogen. The deoxygenation catalyst is preferably a NiMo catalyst and, in addition, a cracking catalyst can be used, such as an acidic zeolite catalyst. The deoxygenated product stream is cooled down so as to obtain a liquid, which is distilled for separation of the aliphatic and aromatic hydrocarbons for use in the production of the respective monomers and finally polymers.

Abstract translation: 本发明涉及一种使妥尔油沥青脱氧，产生脂族和芳族烃的方法。 本发明甚至包括通过蒸汽裂化将脂族物转化为可聚合烯烃，并且通过氧合将需要的芳烃转化成可聚合的对苯二甲酸，并且根据需要进行重排。 单体可用于生产部分或完全生物来源的聚合物。 根据本发明，首先将妥尔油沥青加热以将其转化成液体，然后将其进料到催化剂床中并用氢气催化脱氧。 脱氧催化剂优选为NiMo催化剂，此外，可以使用裂化催化剂，例如酸性沸石催化剂。 将脱氧产物流冷却，以获得液体，蒸馏用于分离用于生产各单体和最终聚合物的脂族和芳族烃。

公开(公告)号：WO2014161724A1

公开(公告)日：2014-10-09

申请号：PCT/EP2014/055630

申请日：2014-03-20

Applicant: UPM-KYMMENE CORPORATION

Inventor： LINDBERG, Teemu ,  NOUSIAINEN, Jaakko ,  LAUMOLA, Heli ,  RISSANEN, Arto

IPC: C10G3/00 ,  C10L1/02 ,  C11C3/12

CPC classification number: C10G3/50 ,  C10G3/45 ,  C10G3/46 ,  C10G3/49 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/026 ,  C10L1/04 ,  C10L1/08 ,  C10L2200/043 ,  C10L2200/0446 ,  C10L2200/0469 ,  C10L2270/026 ,  C10L2270/04 ,  C10L2290/543 ,  C11B3/00 ,  C11C3/12 ,  Y02E50/13 ,  Y02P30/20 ,  Y02T50/678

Abstract: The present invention provides a composition comprising 10- 40 mass! of C 8-30 linear alkanes, up to 20 mass% of C 7-20 aromatic hydrocarbons, at least 90 mass% of which are monoaromatic, and no more than 1 massl in total of oxygen containing compounds; wherein the total amount of C 8-30 alkanes in the composition is 50-95 mass% ( and the total amount of C 8-30 alkanes, C 7-20 aromatic hydrocarbons and C 8-30 cycloalkanes is at least 95 massl; and wherein the amounts are based on the mass of the composition. Also provided is a method for producing the composition comprising the step of hydroprocessing a biological feedstock using a catalyst and the step of fractionating the product of the hydroprocessing step.

Abstract translation: 本发明提供一种组合物，其包含10-40质量％ 的C8-30直链烷烃，至多20质量％的C7-20芳烃，其中至少90质量％是单芳族的，并且不超过1质量％的含氧化合物; 其中所述组合物中的C 8-30烷烃的总量为50-95质量％（并且C8-30烷烃，C7-20芳族烃和C8-30环烷烃的总量为至少95质量份;并且其中所述量为 还提供了一种制备组合物的方法，其包括使用催化剂加氢处理生物原料的步骤和分级加氢处理步骤的产物的步骤。