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公开(公告)号：WO2008015228A3
公开(公告)日：2008-04-03
申请号：PCT/EP2007057953
申请日：2007-08-01
Applicant: BASELL POLYOLEFINE GMBH , BAITA PIETRO , PENZO GIUSEPPE , MEI GABRIELE
Inventor： BAITA PIETRO , PENZO GIUSEPPE , MEI GABRIELE
CPC classification number: B01J8/24 , B01J8/003 , B01J2219/00006 , C08F6/005 , C08F6/02 , C08F210/16 , C08L23/00 , C08F210/14 , C08F2500/12 , C08F2500/24
Abstract: A process to perform the finishing of polyolefins produced by gas-phase catalytic polymerization of one or more a-olefms in the presence of a polymerization diluent selected from a C 3 -C 5 alkane, wherein the polyolefm granules discharged from the gas-phase reactor are subjected to: (1) a first degassing step in which said polyolefm is counter-currently contacted with a gaseous stream containing at least 85% by mol of a stripping agent selected from a C 3 -C 5 alkane, said gaseous stream being continuously derived from the monomer recovery section of the polymerization plant; (2) a second degassing step in which said polyolefm is counter-currently contacted with steam, the amount of steam being from 10 to 200 Kg per 1000 kg of polyolefin.
Abstract translation: 一种在选自C 3 -C 5 O 3的聚合稀释剂的存在下，通过一种或多种α-烯烃的气相催化聚合制备的聚烯烃的精制方法 烷烃，其中从气相反应器排出的聚烯烃颗粒经受：（1）第一脱气步骤，其中所述聚烯烃与包含至少85摩尔％选择的汽提剂的气流反向接触 来自C 3 -C 5烷烃，所述气流连续地衍生自聚合装置的单体回收部分; （2）第二脱气步骤，其中所述聚烯烃与蒸汽反向接触，每1000kg聚烯烃的蒸汽量为10-200Kg。
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公开(公告)号：WO2004000891A1
公开(公告)日：2003-12-31
申请号：PCT/EP2003/006351
申请日：2003-06-17
Applicant: BASELL POLIOLEFINE ITALIA S.P.A. , BIGIAVI, Daniele , ARICH DE FINETTI, Nicolò , MEI, Gabriele , PENZO, Giuseppe , COVEZZI, Massimo , BAITA, Pietro , TONTI, Maria, Silvia
Inventor： BIGIAVI, Daniele , ARICH DE FINETTI, Nicolò , MEI, Gabriele , PENZO, Giuseppe , COVEZZI, Massimo , BAITA, Pietro , TONTI, Maria, Silvia
IPC: C08F6/00
CPC classification number: C08F6/003 , B01J2219/00006 , B01J2219/0004 , Y02P20/544 , C08L23/20
Abstract: Method for continuously removing the unreacted butene-1, and optionally other volatile components, from a polymeric solution obtained by liquid phase (co)polymerization of butene-1, the method comprising the steps of: subjecting the polymeric solution to heating and mixing conditions such that a mixture is formed consisting substantially of: (1) a polybutene melt containing entrapped butene-1 and (2) supercritical gaseous butene-1; subjecting the above mixture to a sequence of devolatilization steps operating at decreasing pressures.
Abstract translation: 从通过丁烯-1的液相（共）聚合获得的聚合物溶液中连续除去未反应的丁烯-1和任选的其它挥发性组分的方法，该方法包括以下步骤：将聚合物溶液加热和混合条件如 形成的混合物基本上由以下组成：（1）含有截留的丁烯-1和（2）超临界气态丁烯-1的聚丁烯熔体; 使上述混合物经历在降低的压力下操作的一系列脱挥发分步骤。
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公开(公告)号：WO2006120187A1
公开(公告)日：2006-11-16
申请号：PCT/EP2006/062148
申请日：2006-05-09
Applicant: BASELL POLIOLEFINE ITALIA S.R.L. , MEI, Gabriele , PATER, T.M. Joachim , MEIER, Gerben , BAITA, Pietro
Inventor： MEI, Gabriele , PATER, T.M. Joachim , MEIER, Gerben , BAITA, Pietro
CPC classification number: C08F210/06 , B01J8/1863 , B01J8/388 , B01J19/2435 , B01J2208/00548 , B01J2208/00557 , B01J2219/00164 , B01J2219/00166 , C08F210/16 , Y10S526/901 , C08F2/01 , C08F2/34 , C08F2/001 , C08F2500/12 , C08F2500/05 , C08F210/14
Abstract: A process for the gas-phase polymerization of α-olefÊns CH 2 =CHR, where R is hydrogen or a hydrocarbon radical having 1-12 carbon atoms, carried out in a first and a second interconnected polymerization zones, wherein the growing polymer particles flow through the first of said polymerization zones (riser) under fast fluidization conditions, leave said riser and enter the second of said polymerization zones (downcomer) through which they flow downward in a densified form, leave said downcomer and are reintroduced into said riser, in which process: (a) the gas mixture present in the riser is totally or partially prevented from entering the downcomer, and (b) the gaseous composition inside a portion of the downcomer is maintained substantially similar to the gaseous composition reacting in the riser.
Abstract translation: 其中R是氢或具有1-12个碳原子的烃基的α-烯烃CH 2 R 2 = CHR的气相聚合方法是在第一和第二互连聚合区 ，其中生长的聚合物颗粒在快速流化条件下流过第一个所述聚合区（提升管），离开所述提升管并进入其中以致密化形式向下流动的所述聚合区（降液管）中的第二个，离开所述降液管和 重新引入所述提升管中，在该过程中：（a）存在于提升管中的气体混合物完全或部分地被阻止进入降液管，并且（b）降液管的一部分内的气态组合物保持基本上类似于气体 组合物在提升管中反应。
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公开(公告)号：WO2005058982A1
公开(公告)日：2005-06-30
申请号：PCT/EP2004/013372
申请日：2004-11-24
Applicant: BASELL POLYOLEFINE GMBH , BAITA, Pietro , COVEZZI, Massimo , MEI, Gabriele , MORINI, Giampiero , PATER, Joachim, T., M.
Inventor： BAITA, Pietro , COVEZZI, Massimo , MEI, Gabriele , MORINI, Giampiero , PATER, Joachim, T., M.
IPC: C08F10/02
CPC classification number: C08F10/00 , C08F10/02 , C08F210/16 , C08F4/6494 , C08F4/651 , C08F2/001 , C08F210/14 , C08F2500/12 , C08F2500/08 , C08F2500/07 , C08F210/08
Abstract: A process for preparing a broad molecular weight polyethylene carried out in the presence of a catalyst system comprising (i) a solid catalyst component comprising Mg, Ti, halogen, and optionally an internal electron donor compound, and (ii) an Al-alkyl cocatalyst said process comprising at least two step of polymerization (a) and (b), in which, - in a first step (a) ethylene is polymerized in the presence of a molecular weight regulator in order to produce a ethylene (co)polymer, and in a further step (b), which is carried out in the presence of an external electron donor compound added to this polymerization step as a fresh reactant, ethylene is copolymerized with an alpha olefin of formula CH2=CHR, in which R is a C1-C20 hydrocarbon group, to produce an ethylene copolymer having a molecular weight higher than that of the copolymer produced in step (b).
Abstract translation: 一种制备在催化剂体系存在下进行的宽分子量聚乙烯的方法，包括（i）包含Mg，Ti，卤素和任选的内电子给体化合物的固体催化剂组分，和（ii）Al-烷基助催化剂 所述方法包括至少两个聚合步骤（a）和（b）），其中 - 在第一步（a）中，在分子量调节剂存在下聚合乙烯以产生乙烯（共）聚合物， 并且在另外的步骤（b）中，其在作为新的反应物加入到该聚合步骤中的外部电子给体化合物存在下进行，乙烯与式CH 2 = CHR的α-烯烃共聚，其中R是 C1-C20烃基，得到分子量高于步骤（b）中制备的共聚物的乙烯共聚物。
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公开(公告)号：WO2012041813A1
公开(公告)日：2012-04-05
申请号：PCT/EP2011/066682
申请日：2011-09-26
Applicant: BASELL POLYOLEFINE GMBH , BAITA, Pietro , BRITA, Diego , FERRARI, Paolo , MAVRIDIS, Harilaos , MEI, Gabriele , PICA, Roberta , WIESECKE, Jens
Inventor： BAITA, Pietro , BRITA, Diego , FERRARI, Paolo , MAVRIDIS, Harilaos , MEI, Gabriele , PICA, Roberta , WIESECKE, Jens
CPC classification number: C08F10/02 , C08F10/00 , C08F210/16 , C08F210/08 , C08F2500/08 , C08F2500/12 , C08F2500/26 , C08F4/6494 , C08F2/005 , C08F210/14
Abstract: Extruded articles, particularly films, comprising an ethylene polymer obtained by a polymerization process carried out in the presence the products obtained by contacting the following components: (a) a solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and optionally one or more internal electron donor compounds, (b) an aluminum hydrocarbyl compound, (c) optionally an external electron donor compound, and (d) a polyalcohol partially esterified with carboxylic acids with alkyl groups having at least 10 carbon atoms.
Abstract translation: 挤出制品，特别是包含通过聚合方法获得的乙烯聚合物的薄膜，所述聚合方法在存在下通过接触下列组分获得的产物进行：（a）固体催化剂组分，其包含卤化镁，至少具有Ti- 卤素键和任选的一种或多种内部电子给体化合物，（b）铝烃基化合物，（c）任选的外部电子给体化合物，和（d）与具有至少10个碳原子的烷基的羧酸部分酯化的多元醇 。
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Patent Agency Ranking
公开(公告)号：WO2010076289A1
公开(公告)日：2010-07-08
申请号：PCT/EP2009/067906
申请日：2009-12-23
Applicant: BASELL POLIOLEFINE ITALIA S.R.L. , BAITA, Pietro , KARER, Rainer , MEIER, Gerhardus , FUNK, Guido , MEI, Gabriele
Inventor： BAITA, Pietro , KARER, Rainer , MEIER, Gerhardus , FUNK, Guido , MEI, Gabriele
CPC classification number: B01J8/0015 , B01J8/1827 , B01J2208/00752 , B01J2208/00769 , C08F10/00 , C08F210/16 , C08F2/34 , C08F210/08 , C08F2500/12
Abstract: A process for introducing a catalyst powder based on a titanium compound supported on magnesium halide into a gas-phase olefin polymerization reactor, characterized in that it comprises: (a) storing the catalyst powder under an atmosphere of a liquid C 3 -C 12 alkane; (b) withdrawing from step (a) a measured amount of said catalyst powder by means of a rotary valve; (c) transferring said metered amount of catalyst powder to a catalyst activation section by a continuous pick-up flow of a liquid C 3 -C 12 alkane; (d) contacting the catalyst powder with a liquid phase comprising an organo-aluminum compound and optionally an external donor compound, at a temperature ranging from -20 °C to 60 °C; (e) introducing the activated catalyst powder in one or more gas-phase olefin polymerization reactors, where a gaseous mixture comprising at least one alpha-olefin is subjected to polymerization.
Abstract translation: 将基于负载在卤化镁上的钛化合物的催化剂粉末引入气相烯烃聚合反应器的方法，其特征在于，其包括：（a）将催化剂粉末在液体C 3 -C 12烷烃的气氛下储存; （b）通过旋转阀从步骤（a）中取出测量量的所述催化剂粉末; （c）通过液体C 3 -C 12烷烃的连续提取流将所述计量的催化剂粉末转移到催化剂活化部分; （d）在-20℃至60℃的温度范围内使催化剂粉末与包含有机铝化合物和任选的外部供体化合物的液相接触; （e）将活化的催化剂粉末引入一个或多个气相烯烃聚合反应器中，其中包含至少一种α-烯烃的气体混合物进行聚合。
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公开(公告)号：WO2005058979A1
公开(公告)日：2005-06-30
申请号：PCT/EP2004/013550
申请日：2004-11-29
Applicant: BASELL POLIOLEFINE ITALIA S.p.A. , PENZO, Giuseppe , BIGIAVI, Daniele , COVEZZI, Massimo , TONTI, Maria, Silvia , FAIT, Anna , BAITA, Pietro
Inventor： PENZO, Giuseppe , BIGIAVI, Daniele , COVEZZI, Massimo , TONTI, Maria, Silvia , FAIT, Anna , BAITA, Pietro
IPC: C08F6/06
CPC classification number: C08F6/003 , C08F6/02 , C08F10/08 , C08F110/08 , C08F210/08 , C08F2/005 , C08F2/06 , C08F2500/12 , C08F2500/17 , C08F210/16
Abstract: A solution process for polymerizing one or more α-olefins of the formula CH 2 =CHR, where R is H or an alkyl radical C 1 -C 18 , to produce a polymer that is soluble in the reaction medium, comprising the steps of: - continuously polymerizing in a liquid phase the α-olefin in the presence of a catalyst system based on a transition metal compound to obtain a solution of polymer in the reaction medium; - the polymeric solution obtained from step a) is then mixed in one or more mixing stages with an aqueous mixture comprising one or more organic compounds having at least a hydroxy or epoxy group, said aqueous mixture having a dynamic viscosity at 30°C higher than 50 cP (centiPoise).
Abstract translation: 用于聚合一种或多种式CH 2 = CHR的α-烯烃（其中R为H或烷基C1-C18）以产生可溶于反应介质的聚合物的溶液方法包括以下步骤： - 连续聚合 在液相中，在基于过渡金属化合物的催化剂体系的存在下，得到聚合物在反应介质中的溶液; 然后将由步骤a）获得的聚合物溶液在一个或多个混合阶段与包含一种或多种至少具有羟基或环氧基的有机化合物的含水混合物混合，所述含水混合物的动态粘度在30℃高于 50厘泊（厘泊）。
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8.发明申请
公开(公告)号：WO2012041811A1
公开(公告)日：2012-04-05
申请号：PCT/EP2011/066680
申请日：2011-09-26
Applicant: BASELL POLYOLEFINE GMBH , BAITA, Pietro , FERRARI, Paolo , MINGOZZI, Ines , PEDRIALI, Lorella , DI DIEGO, Maria , PICA, Roberta
Inventor： BAITA, Pietro , FERRARI, Paolo , MINGOZZI, Ines , PEDRIALI, Lorella , DI DIEGO, Maria , PICA, Roberta
CPC classification number: C08F4/16 , C08F10/00 , C08F110/02 , C08F210/16 , C08F2410/02 , C08F2/005 , C08F2500/07 , C08F2500/12 , C08F210/08 , C08F4/6494 , C08F4/6495
Abstract: A method for feeding an antistatic compound to a polymerization reactor comprising the steps of: a) dispersing, under mixing conditions, a catalyst powder and an antistatic compound in an oil, so as to form a suspension of catalyst powder and antistatic compound in said oil; b) successively adding, under mixing conditions, a molten thickening agent to said suspension from step a), while maintaining said suspension at a temperature such that said thickening agent solidifies on contact with said suspension; c) transferring the product obtained from b) to a polymerization reactor.
Abstract translation: 一种将抗静电化合物进料到聚合反应器中的方法，包括以下步骤：a）在混合条件下在油中分散催化剂粉末和抗静电化合物，以便在所述油中形成催化剂粉末和抗静电化合物的悬浮液 ; b）在混合条件下，将熔融增稠剂连续地加入到步骤a）的所述悬浮液中，同时将所述悬浮液保持在使所述增稠剂与所述悬浮液接触时固化的温度; c）将从b）获得的产物转移到聚合反应器中。
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公开(公告)号：WO2008015228A2
公开(公告)日：2008-02-07
申请号：PCT/EP2007/057953
申请日：2007-08-01
Applicant: BASELL POLYOLEFINE GMBH , BAITA, Pietro , PENZO, Giuseppe , MEI, Gabriele
Inventor： BAITA, Pietro , PENZO, Giuseppe , MEI, Gabriele
CPC classification number: B01J8/24 , B01J8/003 , B01J2219/00006 , C08F6/005 , C08F6/02 , C08F210/16 , C08L23/00 , C08F210/14 , C08F2500/12 , C08F2500/24
Abstract: A process to perform the finishing of polyolefins produced by gas-phase catalytic polymerization of one or more α-olefms in the presence of a polymerization diluent selected from a C 3 -C 5 alkane, wherein the polyolefm granules discharged from the gas-phase reactor are subjected to: (1) a first degassing step in which said polyolefm is counter-currently contacted with a gaseous stream containing at least 85% by mol of a stripping agent selected from a C 3 -C 5 alkane, said gaseous stream being continuously derived from the monomer recovery section of the polymerization plant; (2) a second degassing step in which said polyolefm is counter-currently contacted with steam, the amount of steam being from 10 to 200 Kg per 1000 kg of polyolefin.
Abstract translation: 在聚合稀释剂存在下进行通过气相催化聚合一种或多种α-烯烃生产的聚烯烃的精制方法，所述聚合稀释剂选自C 3 - 其中从气相反应器排出的聚烯烃颗粒经历：（1）第一脱气步骤，其中所述聚烯烃与包含至少85的气流逆流接触 摩尔％的选自C 3 -C 5链烷烃的汽提剂，所述气体物流连续得自聚合装置的单体回收部分; （2）第二脱气步骤，其中所述聚烯烃与蒸汽逆流接触，蒸汽量为每1000kg聚烯烃10至200Kg。
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公开(公告)号：WO2005019280A1
公开(公告)日：2005-03-03
申请号：PCT/EP2004/008063
申请日：2004-07-19
Applicant: BASELL POLIOLEFINE ITALIA S.P.A. , MEIER, Gerben , COVEZZI, Massimo , BAITA, Pietro , MEI, Gabriele
Inventor： MEIER, Gerben , COVEZZI, Massimo , BAITA, Pietro , MEI, Gabriele
IPC: C08F10/02
CPC classification number: B01J8/0055 , B01J8/1854 , B01J8/24 , B01J19/2435 , B01J2208/00619 , B01J2219/00006 , B01J2219/0004 , B01J2219/00184 , C08F210/16 , C08L23/06 , C08L23/0815 , C08L2205/02 , Y10S526/905 , C08F2/34 , C08F2/001 , C08L2666/06 , C08F210/14 , C08F2500/04 , C08F2500/07 , C08F2500/12 , C08F2500/17 , C08F210/08
Abstract: Process for preparing a broad molecular weight polyethylene by polymerizing ethylene in the presence of a polymerization catalyst, the process comprising the following steps, in any mutual order: a) polymerizing ethylene, optionally together with one or more a-olefinic comonomers having from 3 to 12 carbon atoms, in a gas-phase reactor in the presence of hydrogen, b) copolymerizing ethylene with one or more a-olefinic comonomers having from 3 to 12 carbon atoms in another gas-phase reactor in the presence of an amount of hydrogen less than step a), where in at least one of said gas-phase reactors the growing polymer particles flow upward through a first polymerization zone under fast fluidization or transport conditions, leave said first polymerization zone and enter a second polymerization zone through which they flow downward under the action of gravity.
Abstract translation: 通过在聚合催化剂存在下聚合乙烯制备宽分子量聚乙烯的方法，所述方法包括以下步骤：a）将乙烯，任选与一种或多种α-烯烃共聚单体一起聚合，所述α-烯烃共聚单体具有3〜 12个碳原子，在氢存在下在气相反应器中，b）在另一种气相反应器中在一定量的氢气存在下使乙烯与一种或多种具有3至12个碳原子的α-烯烃共聚单体共聚 其中在至少一个所述气相反应器中，生长的聚合物颗粒在快速流化或运输条件下通过第一聚合区向上流动，留下所述第一聚合区并进入第二聚合区，通过它们向下流动 在重力的作用下。
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