公开(公告)号：WO2007140954A1

公开(公告)日：2007-12-13

申请号：PCT/EP2007/004901

申请日：2007-06-01

Applicant: UMICORE AG & CO. KG ,  GRELA, Karol ,  BARBASIEWICZ, Michal ,  SZADKOWSKA, Anna

Inventor： GRELA, Karol ,  BARBASIEWICZ, Michal ,  SZADKOWSKA, Anna

IPC: B01J31/18

CPC classification number: C07F15/0046 ,  B01J31/181 ,  B01J31/1825 ,  B01J2231/14 ,  B01J2231/52 ,  B01J2531/821 ,  B01J2531/825 ,  C07C67/333 ,  C07D207/48 ,  C07D307/28

Abstract: Complexes of ruthenium and osmium according to the invention are represented by formula (1), in which M denotes ruthenium or osmium, L denotes a neutral ligand selected from the group comprising amines, imines, phosphines (preferably stilbines, arsines, alcohols, thiols, ethers and thioethers or an N- heterocyclic carbene (NHC) ligand). The compounds of formula (1) occur in the form of two isomers: trans and cis. The method of production of complexes of ruthenium and osmium of formula (1) according to the invention is based on reacting an intermediate of formula (5) with a carbene complex of ruthenium or osmium. The invention also relates to the use of the complexes according to the invention for carrying out metathesis reactions.

Abstract translation: 根据本发明的钌和锇的络合物由式（1）表示，其中M表示钌或锇，L表示选自胺，亚胺，膦（优选芪，胂，醇，硫醇， 醚和硫醚或N-杂环卡宾（NHC）配体）。 式（1）的化合物以两种异构体的形式存在：反式和顺式。 制备根据本发明的式（1）的钌和锇络合物的方法是基于使式（5）的中间体与钌或锇的卡宾络合物反应。 本发明还涉及根据本发明的复合物用于进行复分解反应的用途。

公开(公告)号：WO2012168183A1

公开(公告)日：2012-12-13

申请号：PCT/EP2012/060498

申请日：2012-06-04

Applicant: UMICORE AG & CO. KG ,  GRELA, Karol ,  BARBASIEWICZ, Michal ,  MICHALAK, Michal

Inventor： GRELA, Karol ,  BARBASIEWICZ, Michal ,  MICHALAK, Michal

IPC: B01J31/22

CPC classification number: C08F132/08 ,  B01J31/2278 ,  B01J2231/54 ,  B01J2531/821 ,  C07C67/333 ,  C07C253/30 ,  C07C329/06 ,  C07D211/70 ,  C07D307/28 ,  C07D309/22 ,  C07F15/0046

Abstract: The present invention provides new ruthenium complexes of Formula (1), which contain a chelate ring created by a halogen atom X. The invention concerns also a method for the preparation of the new ruthenium complexes and their application in metathesis reactions.

Abstract translation: 本发明提供了含有由卤素原子X产生的螯合环的式（1）的新的钌络合物。本发明还涉及制备新钌络合物的方法及其在复分解反应中的应用。