Abstract:
Composition and process for low temperature curing of polyuretdione-polyol compositions in which the polyuretdione is prepared from a polyisocyanate with isocyanate groups and a polyol containing primary hydroxyl groups. The catalyst for the composition and process is an amine catalyst containing the group -N=C-N-, being aprotic, having a pKa greater than 20 and upon addition to the liquid coating composition causing a phase-change of the coating composition from liquid to solid at 250C and 1atm. within one week.
Abstract:
Polyurethane elastomers having solids contents greater than 40% by weight are produced from a sprayable polyurethane-forming system composed of an isocyanate component and an isocyanate-reactive component. The isocyanate component has a solids content of from 40 to 80 wt. %, based on total weight of isocyanate component and is made up of at least one aromatic polyisocyanate having an NCO content of from 24 to 33%, a functionality of from 2 to 3 and at least one solid filler. The isocyanate-reactive component has a solids content of from 40 to 80 wt. %, based on total weight of the isocyanate-reactive component and is composed of at least one polyether polyol having a hydroxyl number of from 25 to 40 and a functionality of from 2 to 4, and at least one solid filler.
Abstract:
Disclosed are methods for coating a substrate. These methods include: (a) preparing a two-component coating composition by mixing a first component and a second component to make a mixture thereof, and (b) depositing the mixture over the substrate to form a film having a 60° gloss of no more than 35 gloss units (measured according to ASTM D523-89). In these methods: (i) the first component includes: (A) an aqueous anionic, aliphatic polyurethane dispersion comprising a polyurethane having terminal methylol groups; and (ii) the second component comprises an aqueous anionic acrylic polymer solution having a viscosity of 25,000 to 60,000 mPa•s at 20 °C when measured according to DIN EN ISO 3219 at a non-volatile content of 9 % to 11 % by weight, based on the total weight of the solution, measured according to DIN 53189.
Abstract translation:公开了涂布基材的方法。 这些方法包括:(a)通过混合第一组分和第二组分以制备其混合物来制备双组分涂料组合物,和(b)将所述混合物沉积在基材上以形成具有60°光泽度的膜 超过35个光泽单位(根据ASTM D523-89测量)。 在这些方法中:(i)第一组分包括:(A)包含具有末端羟甲基的聚氨酯的含水阴离子脂族聚氨酯分散体; 和(ii)第二组分包含水性阴离子丙烯酸类聚合物溶液,其在20℃下的粘度为25,000至60,000mPa·s,当根据DIN EN ISO 3219测量,其非挥发物含量为9%至11% ,基于根据DIN 53189测量的溶液的总重量。
Abstract:
This invention relates' to polyurethane/polyureas with improved catalysis and to a process for the preparation of these polyureihane/polyureas. These materials, comprise the reaction product of (A) a (cyclojaliphatic polyisocyanate or (cyclo)aliphatic polyisocyanate prepolymer, with (B) an isocyanate-reactive component comprising at least one aromatic diamine compound containing from 1 to 8 thiomethyl groups, in the presence of (C) one or more catalysts selected from the group consisting of tin (II) catalysts, bismuth (III) catalysts and mixtures thereof. Preferably, the materials are optically clear.
Abstract:
This invention relates to po!yurethane/polyureas. These poiyureihane/po!yurea materials comprise the reaction product of (A) a poiyisocyanate prepolymer having an NCO group content of about 4 to about 30% and an average functionality of 1.8 to 6, and (B) an isocyanate- reactive component comprising at least one aromatic diamine compound, The (A) poiyisocyanate prepoiymers herein comprise the reaction product of (1) at least one {cyclo)aliphalic poiyisocyanate with (2) an organic compound having 1,8 to 5 hydroxy! groups and a hydroxy! equivalent weight of 150 to 2000 g/eq., and which is selected from the group consisting of OH- functional poiybutadienes, OH-funcfional polyalkylene, OH-functional polyalkylene phthalates, OH-functional polyalkylene isophthalates, OH- functional polyalkylene terephthaiates and mixtures thereof.
Abstract:
The present invention provides a rapidly employable window cover comprising a laminate panel comprising two or more layers of polycarbonate having layered therebetween one or more layers of a thermoplastic polyurethane, having a plurality of openings arranged around the periphery thereof and the plurality of openings extending through the panel; and a plurality of fasteners; wherein the plurality of openings are sized and shaped to receive the plurality of fasteners therethrough, and wherein the fasteners attach the panel to a structure in which the window is embedded such that the panel shields the window.
Abstract:
The present invention provides a composition comprising a polycarbonate, and infrared (IR) reflective additive and an epoxy-functional silicone, wherein the composition exhibits a reduced melt flow change over a comparable compound not containing an epoxy-functional silicone.
Abstract:
This invention relates to coated polyurethane foams and to a process for preparing coated polyurethane foams. More specifically, these coated polyurethane foams comprise (a) a polyurethane foam substrate, and (b) at least one bilayer of a coating composition on the foam substrate which comprises (1 ) a layer of a positively or negatively charged carbon allotrope, and (2) a layer of a positively or negatively charged polymer. When the carbon allotrope is positively charged, the other material is negatively charged, and vice versa. The final product (i.e. coated polyurethane foam) contains at least 1% by weight of the coating composition, based on 100% by weight of the coated polyurethane foam. The foams described herein have a surface resistivity of less than or equal to 10 12 ohms per square.
Abstract:
Polymer polyols having a solids content of greater than 40 wt.%, a total ethylene oxide content of up to 25 wt.%, and a viscosity at 25°C of less than 15,000 centistokes are produced by reacting (1) a base polyol having active hydrogen atoms with an ethylene oxide content of from 15 to 40 wt.% that has been formed in the presence of a double metal cyanide (DMC) catalyst, (2) one or more unsaturated monomers, (3) at least one radical initiator, optionally (4) a preformed stabilizer and optionally (5) a chain transfer agent. These polymer polyols (PMPOs) are useful in the preparation of polyurethane foams and elastomers.
Abstract:
This invention relates to a semi-batch process for the production of polyoxyalkylene polyether polyols. These polyoxyalkylene polyether polyols have hydroxy I (OH) numbers of from 112 to 400. This process comprises establishing oxyalkylation condition in a reactor in the presence of a DMC catalyst, continuously introducing alkylene oxide and a suitable starter into the reactor, and recovering an oxyalkyated polyether polyol. The oxyalkylation initially occurs at a temperature that is sufficiently high enough to avoid or prevent deactivation of the DMC catalyst, or for from 2% to 50% of the total oxide feed amount, and the oxyalkylation is then continued at a lower temperature.