AN IMPROVED PROCESS FOR TELOMERIZATION OF BUTADIENE
    3.
    发明申请
    AN IMPROVED PROCESS FOR TELOMERIZATION OF BUTADIENE 审中-公开
    一种改进的丁二烯的通用化方法

    公开(公告)号:WO2010019360A3

    公开(公告)日:2010-04-08

    申请号:PCT/US2009051347

    申请日:2009-07-22

    IPC分类号: C07C41/06 C07C43/188

    摘要: In an improved process for telomerizing butadiene, contact butadiene and an organic hydroxy compound represented by formula ROH (I), wherein R is a substituted or unsubstituted C1-C20-hydrocarbyl and the organic hydroxy compound is not glycerol, in a reaction fluid in the presence of a palladium catalyst and a phosphine ligand represented by formula PAr3 (II), wherein each Ar is independently a substituted or unsubstituted aryl having a hydrogen atom on at least one ortho position, at least two Ar groups are ortho-hydrocarbyloxyl substituted aryls. The phosphine ligand has a total of two (2), three (3), four (4), five (5), or six (6) substituted or unsubstituted C1-C20-hydrocarbyloxyls, and optionally, any two adjacent substituents on an Ar group can be bonded to form a 5- to 7-membered ring.

    摘要翻译: 在丁二烯调聚反应的改进方法中,将接触丁二烯和由式ROH(I)表示的有机羟基化合物(其中R为取代或未取代的C1-C20-烃基并且有机羟基化合物不是甘油) 钯催化剂和由式PAr3(II)表示的膦配体的存在,其中每个Ar独立地为在至少一个邻位上具有氢原子的取代或未取代的芳基,至少两个Ar基团为邻烃氧基取代的芳基。 膦配体总共具有两个(2),三个(3),四个(4),五(5)或六个(6)取代或未取代的C 1 -C 20烃氧基,以及任选地任选两个 Ar基团可以键合形成5-至7-元环。

    AN IMPROVED PROCESS FOR TELOMERIZATION OF BUTADIENE
    5.
    发明申请
    AN IMPROVED PROCESS FOR TELOMERIZATION OF BUTADIENE 审中-公开
    改进二苯乙烯的方法

    公开(公告)号:WO2010019360A2

    公开(公告)日:2010-02-18

    申请号:PCT/US2009/051347

    申请日:2009-07-22

    IPC分类号: C07C41/06 C07C43/188

    摘要: In an improved process for telomerizing butadiene, contact butadiene and an organic hydroxy compound represented by formula ROH (I), wherein R is a substituted or unsubstituted C 1 -C 20 -hydrocarbyl and the organic hydroxy compound is not glycerol, in a reaction fluid in the presence of a palladium catalyst and a phosphine ligand represented by formula PAr 3 (II), wherein each Ar is independently a substituted or unsubstituted aryl having a hydrogen atom on at least one ortho position, at least two Ar groups are ortho-hydrocarbyloxyl substituted aryls. The phosphine ligand has a total of two (2), three (3), four (4), five (5), or six (6) substituted or unsubstituted C 1 -C 20 -hydrocarbyloxyls, and optionally, any two adjacent substituents on an Ar group can be bonded to form a 5- to 7-membered ring.

    摘要翻译: 在用于调聚丁二烯的改进方法中,接触丁二烯和由式ROH(I)表示的有机羟基化合物,其中R是取代或未取代的C 1 -C 20 - 烃基,有机羟基化合物不是甘油,在 存在钯催化剂和由式PAr 3(II)表示的膦配体,其中每个Ar独立地是在至少一个邻位具有氢原子的取代或未取代的芳基,至少两个Ar基团是邻 - 烃氧基取代的芳基。 膦配体共有二(2),三(3),四(4),五(5)或六(6)取代或未取代的C1-C20烃氧基,任选地,任何两个相邻的取代基 Ar基团可以键合形成5-至7-元环。