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公开(公告)号:WO2012084580A1
公开(公告)日:2012-06-28
申请号:PCT/EP2011/072508
申请日:2011-12-13
申请人: SOLVAY SPECIALTY POLYMERS ITALY S.P.A. , ABUSLEME, Julio A , BIANCARDI, Roberto , ROBLOT, Fabien , BERTASA, Anna Maria , BRINATI, Giulio
发明人: ABUSLEME, Julio A , BIANCARDI, Roberto , ROBLOT, Fabien , BERTASA, Anna Maria , BRINATI, Giulio
IPC分类号: C08F251/02 , B01D71/78 , C08J5/22 , C08F290/04 , C08F290/10 , C08F290/02
CPC分类号: C08F14/22 , B01D71/32 , B01D71/78 , B01D2323/38 , C08F8/00 , C08F214/225 , C08F251/02 , C08F290/02 , C08F290/10 , C08F214/22
摘要: The present invention pertains to a process for the manufacture of a grafted fluorinated polymer comprising at least one grafted side chain comprising one or more glycosidic recurring units [polymer (F)], said process comprising polymerizing: - vinylidene fluoride (VDF), - optionally, one or more other fluorinated monomers [monomers (F)], and - optionally, one or more (meth)acrylic monomers [monomers (MA)], in the presence of at least one polysaccharide derivative [derivative (P)], said polysaccharide derivative having a dynamic viscosity of less than 15 mPa x s, as measured according to ASTM D445 at 20°C in an aqueous solution at a concentration of 2% by weight, and by further providing novel polymers (F) as defined above.
摘要翻译: 本发明涉及制备接枝氟化聚合物的方法,该接枝氟化聚合物包含至少一个包含一个或多个糖苷重复单元[聚合物(F)]的接枝侧链,所述方法包括聚合: - 偏二氟乙烯(VDF), - 任选地 ,一种或多种其它氟化单体[单体(F)]和任选的一种或多种(甲基)丙烯酸单体[单体(MA)]在至少一种多糖衍生物[衍生物(P)]的存在下,所述 在20℃,浓度为2重量%的水溶液中,根据ASTM D445测定动态粘度小于15mPa xs的多糖衍生物,并进一步提供如上所述的新型聚合物(F)。
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公开(公告)号:WO2012080098A1
公开(公告)日:2012-06-21
申请号:PCT/EP2011/072260
申请日:2011-12-09
申请人: SOLVAY SPECIALTY POLYMERS ITALY S.P.A. , COLAIANNA, Pasqua , BESANA, Giambattista , DI NICOLO, Emanuele , BRAGANTE, Letanzio , MARCHIONNI, Giuseppe , BRINATI, Giulio
发明人: COLAIANNA, Pasqua , BESANA, Giambattista , DI NICOLO, Emanuele , BRAGANTE, Letanzio , MARCHIONNI, Giuseppe , BRINATI, Giulio
IPC分类号: C08J9/00
CPC分类号: C08K5/42 , C08J9/0019 , C08J2327/12
摘要: The invention pertains to foamable thermoplastic fluoropolymer composition comprising: - at least one fluoropolymer [polymer (A)]; and - at least one perfluoroalkoxysulphonic derivative of either of formulae: (X n+ ) 1/n -O 3 S-CF 2 CF 2 O-R d f -OCF 2 CF 2 -SO 3 -(X n+ ) 1/n and R m f -OCF 2 CF 2 -SO 3 -(X n+ ) 1/n wherein R d f is a divalent C 1 -C 12 perfluorocarbon group, possibly comprising one or more ethereal oxygen atom; Rmf is a monovalent C 1 -C 12 perfluorocarbon group, possibly comprising one or more ethereal oxygen atom, optionally comprising heteroatoms, generally selected from S, N, P; X = H, a metal cation, or an ammonium group; n is the valence of the cation X, preferably 1 or 2.
摘要翻译: 本发明涉及可发泡热塑性含氟聚合物组合物,其包含: - 至少一种含氟聚合物[聚合物(A)]; 和(Xn +)1 / n -O3S-CF2CF2O-Rdf-OCF2CF2-SO3-(Xn +)1 / n和Rmf-OCF2CF2-SO3-(Xn +)1 / n的至少一种全氟代烷氧基磺酸衍生物 其中Rd f是可能包含一个或多个醚类氧原子的二价C1-C12全氟化碳基团; Rmf是单价C1-C12全氟化碳基团,可能包含一个或多个醚性氧原子,任选地包含杂原子,通常选自S,N,P; X = H,金属阳离子或铵基; n是阳离子X的化合价,优选1或2。
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公开(公告)号:WO2007082924A1
公开(公告)日:2007-07-26
申请号:PCT/EP2007/050523
申请日:2007-01-19
CPC分类号: B32B27/08 , B32B1/08 , B32B7/10 , B32B27/304 , B32B27/34 , B32B2250/24 , B32B2270/00 , B32B2597/00 , C08L51/06 , C08L77/00 , F16L11/04 , F16L2011/047 , C08L2666/02
摘要: The invention relates to a multilayer polymer structure e.g shaped article such as tubes [structure (S)] comprising a layer (alpha) comprising at least one aromatic polyamide [polymer (AA)], said layer (alpha) being linked to a layer (γ) comprising at least one melt-processible fluoropolymer substantially free from recurring units derived from functional monomers [polymer (F)] via a layer (β), said layer (β) comprising a polymer composition (C-1), said polymer composition (C-1) comprising from 100 % to 3 % by weight of at least one functional fluoropolymer [polymer (I) ] , with respect to the total weight of the composition, and from 0 to 97 % by weight of at least one melt-processible fluoropolymer substantially free from recurring units derived from functional monomers [polymer (F)], with respect to the total weight of the composition, wherein said polymer (I) is a functional per (halo) fluoropolymer comprising recurring units derived from at least one fluorinated functional monomer. The multilayer structures of the invention enables obtaining structures with excellent adhesion between fluoropolymers and polyamides, whose components can withstand high processing temperature, such as those required for instance for aromatic polyamide processing and extremely harsh environment.
摘要翻译: 本发明涉及一种多层聚合物结构,例如成型制品例如包含包含至少一种芳族聚酰胺[聚合物(AA)]的层(α)的管[结构(S)],所述层(α)连接到层 包含至少一种可熔融加工的含氟聚合物,所述含氟聚合物基本上不含通过层(ß)衍生自官能单体[聚合物(F)]的重复单元,所述层(ß)包含聚合物组合物(C-1) (C-1),包含100重量%至3重量%的至少一种官能含氟聚合物[聚合物(I)],相对于组合物的总重量,和0至97重量%的至少一种熔体 - 相对于组合物的总重量,基本上不含有衍生自官能单体[聚合物(F)]的重复单元的可加工的含氟聚合物,其中所述聚合物(I)是包含至少衍生的重复单元的功能性(卤素)含氟聚合物 一个氟化功能单体 河 本发明的多层结构能够获得在含氟聚合物和聚酰胺之间具有优异粘附性的结构,其组分可以承受高的加工温度,例如芳族聚酰胺加工和极恶劣环境所需的那些。
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公开(公告)号:WO2013010936A1
公开(公告)日:2013-01-24
申请号:PCT/EP2012/063778
申请日:2012-07-13
申请人: SOLVAY SPECIALTY POLYMERS ITALY S.P.A. , STANGA, Milena , PIERI, Riccardo , BERTASA, Anna Maria , KENT, Bradley Lane , BRINATI, Giulio
IPC分类号: C08L27/16 , C09D127/16 , C08K3/04 , H01M4/04 , H01M10/0525
CPC分类号: H01M4/623 , C08L27/16 , C09D127/16 , H01M4/0402 , H01M4/0404 , H01M4/133 , H01M4/1393 , H01M4/622 , H01M10/0525
摘要: The present invention pertains to an aqueous composition comprising: (A) an aqueous latex comprising at least one vinylidene fluoride (VDF) polymer [polymer (F)] comprising recurring units derived from vinylidene fluoride (VDF) and at least one (meth)acrylic monomer (MA) having formula (I) here below: wherein: - R 1 , R 2 and R 3 , equal to or different from each other, are independently selected from a hydrogen atom and a C 1 -C 3 hydrocarbon group, and - R OH is a hydrogen atom or a C 1 -C 5 hydrocarbon moiety comprising at least one hydroxyl group, (B) at least one powdery electrode material, and (C) optionally, less than 10% by weight, based on the total weight of the aqueous composition, of at least one organic solvent (S), wherein the polymer (F) in the aqueous latex is under the form of primary particles having an average primary particle size of less than 1 μm, as measured according to ISO 13321. The present invention also pertains to a process for manufacturing an electrode using said aqueous composition, to an electrode comprising a metal substrate coated on at least one surface with said aqueous composition and to use of said electrode for manufacturing a non-aqueous-type electrochemical device.
摘要翻译: 本发明涉及一种水性组合物,其包含:(A)包含至少一种含偏二氯乙烯(VDF)的重复单元和至少一种(甲基)丙烯酸酯的偏二氟乙烯(VDF)聚合物[聚合物(F) 具有式(I)的单体(MA)如下:其中:-R 1,R 2和R 3彼此相同或不同,独立地选自氢原子和C1-C3烃基,和-ROH是氢 原子或包含至少一个羟基的C 1 -C 5烃部分,(B)至少一种粉末状电极材料,和(C)任选地,基于水性组合物的总重量,小于10重量% 至少一种有机溶剂(S),其中根据ISO 13321测量,水性胶乳中的聚合物(F)是平均一次粒径小于1μm的初级颗粒的形式。本发明还涉及 一种使用所述水溶液制造电极的方法 涉及包含涂覆在至少一个表面上的金属基材与所述水性组合物的电极,并且使用所述电极来制造非水型电化学装置。
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公开(公告)号:WO2012084579A1
公开(公告)日:2012-06-28
申请号:PCT/EP2011/072507
申请日:2011-12-13
发明人: MARRANI, Alessio , BRINATI, Giulio
IPC分类号: C08F214/22
CPC分类号: C08F214/225 , C08F214/22
摘要: The present invention pertains to a fluoropolymer [polymer (F)] comprising: - recurring units derived from vinylidene fluoride (VDF); - from 10% to 50% by moles of recurring units derived from trifluoroethylene (TrFE); and - from 0.01 % to 10% by moles of recurring units derived from at least one (meth)acrylic monomer [monomer (MA)] having formula (I) here below, wherein: - R 1 , R 2 and R 3 , equal to or different from each other, are independently selected from a hydrogen atom and a C 1 -C 3 hydrocarbon group, and - R OH represents a hydrogen atom or a C 1 -C 5 hydrocarbon moiety comprising at least one hydroxyl group. The invention also pertains to a process for the manufacture of said polymer (F) and to use of said polymer (F) as ferroelectric, piezoelectric, pyroelectric or dielectric material in electrical and electronic devices.
摘要翻译: 本发明涉及含氟聚合物[聚合物(F)],其包含: - 衍生自偏二氟乙烯(VDF)的重复单元; - 10%至50%摩尔的衍生自三氟乙烯(TrFE)的重复单元; 和 - 0.01%至10%摩尔的衍生自具有下式(I)的至少一种(甲基)丙烯酸单体[单体(MA)]的重复单元,其中:-R 1,R 2和R 3等于或不同 彼此独立地选自氢原子和C1-C3烃基,-ROH表示氢原子或包含至少一个羟基的C 1 -C 5烃部分。 本发明还涉及制造所述聚合物(F)的方法以及所述聚合物(F)在电气和电子设备中用作铁电,压电,热电或介电材料的方法。
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公开(公告)号:WO2007006646A1
公开(公告)日:2007-01-18
申请号:PCT/EP2006/063589
申请日:2006-06-27
CPC分类号: C08L27/16 , C08L27/18 , C08L71/00 , C08L2205/02 , C08L2205/03 , C08L2666/02
摘要: The invention pertains to a thermoplastic halopolymer composition comprising - at least one thermoplastic halopolymer [polymer (A)]; - from 0.01 to 5 % by weight of (A) of at least one (per)fluoropolyether [polymer (B)]; and - from 0.3 to 10 % by weight of (A) of at least one per(halo)fluoropolymer [polymer (C)]. The addition of a (per)fluoropolyether (B) and of a per(halo)fluoropolymer (C) advantageously enables improvement of rheological behavior of thermoplastic halopolymer (A), making possible processing in less severe conditions and yielding final parts with outstanding surface aspect and good homogeneity and coherency. Still objects of the inventions are the process for manufacturing said thermoplastic halopolymer composition and the articles thereof.
摘要翻译: 本发明涉及一种热塑性卤代聚合物组合物,其包含 - 至少一种热塑性卤代聚合物[聚合物(A)]; (A)至少一种(全)氟聚醚[聚合物(B)]的0.01至5重量% 和(A)至少一种每(卤代)含氟聚合物[聚合物(C)] 0.3至10重量%。 加入(全)氟聚醚(B)和全(卤)氟聚合物(C)有利地有助于改善热塑性卤代聚合物(A)的流变行为,使得在较不严格的条件下可能的加工,并产生具有突出表面方面的最终部件 良好的均匀性和一致性。 本发明的另一个目的是制造所述热塑性卤代聚合物组合物及其制品的方法。
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公开(公告)号:WO2013023983A1
公开(公告)日:2013-02-21
申请号:PCT/EP2012/065571
申请日:2012-08-09
申请人: SOLVAY SPECIALTY POLYMERS ITALY S.P.A. , CHERNYSHEVA, Liubov , COMINO, Giovanni , BRINATI, Giulio
IPC分类号: C08F214/22
CPC分类号: C08L27/20 , C08F214/22 , C08F214/222 , C08F214/225 , C08L27/12 , C08L27/16 , C08L2205/02 , C08L2205/025
摘要: The invention pertains to a process for cryogenic milling mixtures of (per)fluoroelastomers and semicrystalline thermoplastic VDF polymers, and to free-flowing micronized pellets obtainable therefrom, said micronized pellets advantageously yielding, after extrusion and compounding, excellent mechanical properties, even improved over those of base fluoroelastomer matrix.
摘要翻译: 本发明涉及一种用于(全)含氟弹性体和半结晶热塑性VDF聚合物的低温研磨混合物的方法以及由其获得的自由流动的微粉化颗粒,所述微粉化颗粒在挤出和混合后有利地产生优异的机械性能,甚至比那些 的基础氟弹性体基体。
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公开(公告)号:WO2007096347A1
公开(公告)日:2007-08-30
申请号:PCT/EP2007/051591
申请日:2007-02-20
IPC分类号: C08F214/26 , C09D127/18 , H01B3/44
CPC分类号: C08F214/184 , C08F214/262 , C09D127/18 , H01B3/445
摘要: Use in LAN cable applications, as materials for the coating of the primary cable and for the external jacket, of TFE thermoprocessable perfluoropolymers comprising perfluoroalkylvinylethers in the following amounts, expressed as per cent by weight on the total of the monomers: a) 0-5.5 % of perfluoromethylvinylether (PMVE); b) 0.4-4.5 % of perfluoroethylvinylether (PEVE) and/or perfluoropropylvinylether (PPVE); when a) is present, then a) + b) ranges from 1.5 % to 5.5 % by weight on the total of the monomers; optionally c) 0-6 % of hexafluoropropene (HFP); the TFE amount being the complement to 100 % by weight.
摘要翻译: 在LAN电缆应用中,用作主电缆和外部护套涂层的材料,TFE热可加工全氟聚合物包含以下量的全氟烷基乙烯基醚,以单体总重量的百分比表示:a)0-5.5 %的全氟甲基乙烯基醚(PMVE); b)0.4-4.5%的全氟乙基乙烯基醚(PEVE)和/或全氟丙基乙烯基醚(PPVE); 当a)存在时,a)+ b)的范围为单体总重量的1.5重量%至5.5重量% 任选地c)0-6%的六氟丙烯(HFP); TFE量是100重量%的补充。
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公开(公告)号:WO2007006645A1
公开(公告)日:2007-01-18
申请号:PCT/EP2006/063586
申请日:2006-06-27
CPC分类号: C08L27/16 , C08L27/18 , C08L71/00 , C08L2205/02 , C08L2205/03 , C08L2666/02 , C08L2666/14
摘要: The invention pertains to a thermoplastic fluoropolymer composition comprising : at least one thermoplastic partially fluorinated fluoropolymer having a melt flow index (MFI) of less than 10 g/10 min, as measured according to ASTM D-1238 under a piston load of 5 kg [polymer (A)]; from 0.05 to 5 % by weight of (A) of at least one (per)fluoropolyether [polymer (B)]; and from 0 to 10 % by weight of (A) of at least one per(halo)fluoropolymer [polymer (C)]. The addition of a (per)fluoropolyether (B) and, optionally, of a per(halo)fluoropolymer (C) advantageously enables improvement of rheological behavior of thermoplastic partially fluorinated fluoropolymer (A), making possible processing in less severe conditions and yielding final parts with outstanding surface aspect and good homogeneity and coherency. Still objects of the inventions are the process for manufacturing said thermoplastic fluoropolymer composition and the articles thereof.
摘要翻译: 本发明涉及一种热塑性含氟聚合物组合物,其包含:至少一种热塑性部分氟化含氟聚合物,其熔体流动指数(MFI)小于10g / 10min,根据ASTM D-1238在5kg活塞负载下测量[ 聚合物(A)]; (A)至少一种(全)氟聚醚[聚合物(B)]的0.05至5重量% 和(A)至少一种每(卤)含氟聚合物[聚合物(C)] 0至10重量%。 加入(全)氟聚醚(B)和任选的(卤代)含氟聚合物(C)有利地有助于改善热塑性部分氟化的含氟聚合物(A)的流变行为,使得在较不严格的条件下可能加工并产生最终 表面表面突出,均匀性和一致性好的部件。 本发明的另一个目的是制造所述热塑性含氟聚合物组合物及其制品的方法。
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公开(公告)号:WO2012175414A1
公开(公告)日:2012-12-27
申请号:PCT/EP2012/061409
申请日:2012-06-15
申请人: SOLVAY SPECIALTY POLYMERS ITALY S.P.A. , KENT, Bradley Lane , KAPELYUSHKO, Valeriy , BRINATI, Giulio , VENERONI, Alessandro
IPC分类号: C08F14/22 , C08F214/22
CPC分类号: C08K5/42 , C08F14/22 , C08F214/22 , C08F2/16
摘要: A process for manufacturing a dispersion of a vinylidene fluoride (VDF) thermoplastic polymer [polymer (F)], said process comprising polymerizing VDF in an aqueous phase comprising from 0.5 to 1.5 g/l of at least one surfactant of formula F-(CF 2 CF 2 ) 3 -CH 2 CH 2 -SO 3 X a , wherein X a is H, a alkali metal or a NR H 4 group, with R H being H or a C 1 -C 6 hydrocarbon group [surfactant (T)] and an organic oxidizing agent [agent (O)] as polymerization initiator.
摘要翻译: 一种制备偏二氟乙烯(VDF)热塑性聚合物[聚合物(F)]的分散体的方法,所述方法包括在包含0.5至1.5g / l的至少一种式F-(CF 2 CF 2)的表面活性剂的水相中聚合VDF )3-CH 2 CH 2 -SO 3 Xa,其中Xa为H,碱金属或NRH 4基,RH为H或C1-C6烃基[表面活性剂(T)]和有机氧化剂[试剂(O)]为 聚合引发剂。
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