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    PROCESS FOR SELECTIVE OXIDATION OF OLEFINS TO EPOXIDES
    1.
    发明申请
    PROCESS FOR SELECTIVE OXIDATION OF OLEFINS TO EPOXIDES 审中-公开
    烯烃选择性氧化成环氧化物的方法

    公开(公告)号：WO2007050678A2

    公开(公告)日：2007-05-03

    申请号：PCT/US2006/041617

    申请日：2006-10-25

    Applicant: UNIVERSITY OF KANSAS ,  BUSCH, Daryle, H. ,  SUBRAMANIAM, Bala ,  LEE, Hyun-jin ,  SHI, Tie-pan

    Inventor： BUSCH, Daryle, H. ,  SUBRAMANIAM, Bala ,  LEE, Hyun-jin ,  SHI, Tie-pan

    IPC: C07D301/12

    CPC classification number: C07D301/12 ,  Y02P20/582

    Abstract: A process for the selective oxidation of olefins to epoxides comprising the step of contacting the olefin (propylene) with an oxidant (hydrogen peroxide) in the presence of a Lewis acid oxidation catalyst (MTO), organic base (pyridine or its N-oxide), in a solvent system comprising an organic water-miscible solvent (methanol); and adding a pressurizing gas (nitrogen) to increase the pressure, whereby olefin is further dissolved in organic solvent system to increase the selectivity and yield of the desired epoxide (propylene oxide).

    Abstract translation: 一种将烯烃选择性氧化成环氧化物的方法，包括在路易斯酸氧化催化剂（MTO），有机碱（如乙酸乙酯）存在下使烯烃（丙烯）与氧化剂（过氧化氢）接触的步骤， （吡啶或其N-氧化物）在包含有机水混溶性溶剂（甲醇）的溶剂体系中; 并加入加压气体（氮气）以增加压力，由此将烯烃进一步溶于有机溶剂体系中以提高所需环氧化物（环氧丙烷）的选择性和收率。

    PROCESS FOR PRODUCING BOTH BIOBASED SUCCINIC ACID AND 2,5-FURANDICARBOXYLIC ACID
    2.
    发明申请
    PROCESS FOR PRODUCING BOTH BIOBASED SUCCINIC ACID AND 2,5-FURANDICARBOXYLIC ACID 审中-公开
    生产双重琥珀酸和2,5-呋喃甲酸的方法

    公开(公告)号：WO2013033081A2

    公开(公告)日：2013-03-07

    申请号：PCT/US2012/052641

    申请日：2012-08-28

    Applicant: THE UNIVERSITY OF KANSAS ,  ARCHER DANIELS MIDLAND COMPANY ,  SUBRAMANIAM, Bala ,  ZUO, Xiaobin ,  BUSCH, Daryle H. ,  VENKITASUBRAMANIAM, Padmesh

    Inventor： SUBRAMANIAM, Bala ,  ZUO, Xiaobin ,  BUSCH, Daryle H. ,  VENKITASUBRAMANIAM, Padmesh

    IPC: C07C51/42 ,  C07C55/10 ,  C07D307/46

    CPC classification number: C07D307/68 ,  C07C51/245 ,  C07D307/46 ,  C07C55/10

    Abstract: A process is provided for carrying out an oxidation on a feed including levulinic acid and/or a levulinic acid oxidation precursor to succinic acid, one or more furanic oxidation precursors of 2,5-furandicarboxylic acid and a catalytically effective combination of cobalt, manganese, and bromide components for catalyzing the oxidation of the levulinic acid component and of the one or more furanic oxidation precursors to produce both succinic acid and 2,5-furandicarboxylic acid products, which process comprises supplying the feed to a reactor vessel, supplying an oxidant, reacting the levulinic acid component and the one or more furanic oxidation precursors with the oxidant to produce both succinic acid and 2,5-furandicarboxylic acid (FDCA) and then recovering the succinic acid and FDCA products. A crude dehydration product from the dehydration of fructose, glucose or both, including 5-hydroxymethylfurfural, can be directly oxidized by the process to produce 2,5-furandicarboxylic acid and succinic acid.

    Abstract translation: 提供了一种用于在包括乙酰丙酸和/或乙酰丙酸氧化前体的进料上对琥珀酸进行氧化的方法，一种或多种2,5-呋喃二甲酸的呋喃类氧化前体和 用于催化乙酰丙酸组分和一种或多种呋喃氧化前体氧化以产生琥珀酸和2,5-呋喃二甲酸产物的催化有效组合，所述方法包括将所述进料 反应器容器，供应氧化剂，使乙酰丙酸组分和一种或多种呋喃氧化前体与氧化剂反应以产生琥珀酸和2,5-呋喃二甲酸（FDCA），然后回收琥珀酸和FDCA产物。 由果糖，葡萄糖或二者的脱水产生的粗脱水产物（包括5-羟甲基糠醛）可通过该方法直接氧化以产生2,5-呋喃二甲酸和琥珀酸。

    PROCESS FOR SELECTIVE OXIDATION OF OLEFINS TO EPOXIDES
    5.
    发明申请
    PROCESS FOR SELECTIVE OXIDATION OF OLEFINS TO EPOXIDES 审中-公开
    烯烃选择性氧化成环氧化物的方法

    公开(公告)号：WO2007050678A3

    公开(公告)日：2007-09-27

    申请号：PCT/US2006041617

    申请日：2006-10-25

    Applicant: UNIV KANSAS ,  BUSCH DARYLE H ,  SUBRAMANIAM BALA ,  LEE HYUN-JIN ,  SHI TIE-PAN

    Inventor： BUSCH DARYLE H ,  SUBRAMANIAM BALA ,  LEE HYUN-JIN ,  SHI TIE-PAN

    IPC: C07D303/00

    CPC classification number: C07D301/12 ,  Y02P20/582

    Abstract: A process for the selective oxidation of olefins to epoxides comprising the step of contacting the olefin (propylene) with an oxidant (hydrogen peroxide) in the presence of a Lewis acid oxidation catalyst (MTO), organic base (pyridine or its N-oxide), in a solvent system comprising an organic water-miscible solvent (methanol); and adding a pressurizing gas (nitrogen) to increase the pressure, whereby olefin is further dissolved in organic solvent system to increase the selectivity and yield of the desired epoxide (propylene oxide).

    Abstract translation: 一种将烯烃选择性氧化成环氧化物的方法，包括在路易斯酸氧化催化剂（MTO），有机碱（吡啶或其N-氧化物）存在下使烯烃（丙烯）与氧化剂（过氧化氢）接触的步骤， ，在包含有机水混溶性溶剂（甲醇）的溶剂体系中; 并加入加压气体（氮气）以增加压力，从而使烯烃进一步溶解在有机溶剂体系中以提高所需环氧化物（环氧丙烷）的选择性和产率。

    PEROXYNITRITE DECOMPOSITION CATALYST
    6.
    发明申请
    PEROXYNITRITE DECOMPOSITION CATALYST 审中-公开
    过氧化物分解催化剂

    公开(公告)号：WO9843637A9

    公开(公告)日：2001-05-03

    申请号：PCT/US9805567

    申请日：1998-03-26

    Applicant: MONSANTO CO ,  UNIV KANSAS ,  RILEY DENNIS P ,  BUSCH DARYLE H ,  ZHANG XIAOPING

    Inventor： RILEY DENNIS P ,  BUSCH DARYLE H ,  ZHANG XIAOPING

    IPC: A61K31/555 ,  A61K31/435

    CPC classification number: A61K31/555

    Abstract: A class of complexes having the formula M(R)X2Y, where M is a transition metal, X is halogen, Y is a pharmaceutically acceptable counterion or ligand, and R is meso-2,12-dimethyl-3,7,11,17-tetraazabicyclo[11.3.1]-heptadeca-1(17), 13, 15-triene, is an effective catalyst for the decomposition of peroxynitrite at physiological pH.

    Abstract translation: 一类具有式M（R）X2Y的络合物，其中M是过渡金属，X是卤素，Y是药学上可接受的抗衡离子或配位体，R是内消旋-2,12-二甲基-3,7,11， 17-四氮杂双环[11.3.1] - 十七碳烯-1（17），13,15-三烯是在生理pH下分解过氧亚硝酸盐的有效催化剂。

    PROCESS FOR PRODUCING BOTH BIOBASED SUCCINIC ACID AND 2,5-FURANDICARBOXYLIC ACID
    7.
    发明申请
    PROCESS FOR PRODUCING BOTH BIOBASED SUCCINIC ACID AND 2,5-FURANDICARBOXYLIC ACID 审中-公开
    生产双酚化酸和2,5-呋喃糖基酸的方法

    公开(公告)号：WO2013033081A3

    公开(公告)日：2013-05-30

    申请号：PCT/US2012052641

    申请日：2012-08-28

    Applicant: UNIV KANSAS ,  ARCHER DANIELS MIDLAND CO ,  SUBRAMANIAM BALA ,  ZUO XIAOBIN ,  BUSCH DARYLE H ,  VENKITASUBRAMANIAM PADMESH

    Inventor： SUBRAMANIAM BALA ,  ZUO XIAOBIN ,  BUSCH DARYLE H ,  VENKITASUBRAMANIAM PADMESH

    IPC: C07C51/42 ,  C07C55/10 ,  C07D307/46

    CPC classification number: C07D307/68 ,  C07C51/245 ,  C07D307/46 ,  C07C55/10

    Abstract: A process is provided for carrying out an oxidation on a feed including levulinic acid and/or a levulinic acid oxidation precursor to succinic acid, one or more furanic oxidation precursors of 2,5-furandicarboxylic acid and a catalytically effective combination of cobalt, manganese, and bromide components for catalyzing the oxidation of the levulinic acid component and of the one or more furanic oxidation precursors to produce both succinic acid and 2,5-furandicarboxylic acid products, which process comprises supplying the feed to a reactor vessel, supplying an oxidant, reacting the levulinic acid component and the one or more furanic oxidation precursors with the oxidant to produce both succinic acid and 2,5-furandicarboxylic acid (FDCA) and then recovering the succinic acid and FDCA products. A crude dehydration product from the dehydration of fructose, glucose or both, including 5-hydroxymethylfurfural, can be directly oxidized by the process to produce 2,5-furandicarboxylic acid and succinic acid.

    Abstract translation: 提供了一种方法，用于对包含乙酰丙酸和/或乙酰丙酸氧化前体的进料进行氧化，所述前体包含琥珀酸，一种或多种呋喃二恶烷的呋喃型氧化前体和钴，锰， 以及用于催化乙酰丙酸组分和一种或多种呋喃氧化前体的氧化以产生琥珀酸和2,5-呋喃二羧酸产物的溴化物组分，该方法包括将进料供应到反应器容器中，供应氧化剂， 使乙酰丙酸组分和一种或多种呋喃氧化前体与氧化剂反应以产生琥珀酸和2,5-呋喃二羧酸（FDCA），然后回收琥珀酸和FDCA产物。 由脱水果糖，葡萄糖或两者（包括5-羟甲基糠醛）的粗脱水产物可直接氧化，生成2,5-呋喃二羧酸和琥珀酸。

    SPRAY PROCESS FOR SELECTIVE OXIDATION
    8.
    发明申请
    SPRAY PROCESS FOR SELECTIVE OXIDATION 审中-公开

    公开(公告)号：WO2010111288A3

    公开(公告)日：2010-09-30

    申请号：PCT/US2010/028343

    申请日：2010-03-23

    Applicant: UNIVERSITY OF KANSAS ,  SUBRAMANIAM, Bala ,  BUSCH, Daryle, H. ,  NIU, Fenghui

    Inventor： SUBRAMANIAM, Bala ,  BUSCH, Daryle, H. ,  NIU, Fenghui

    IPC: C07C51/255 ,  C07C63/00 ,  B01J19/26 ,  B01J8/00 ,  B01J12/00

    Abstract: Oxidation process can include: introducing small droplets of liquid reaction mixture having oxidizable reactant, catalyst, and solvent into a reaction zone containing oxygen and diluent gas; and oxidizing the reactant with the oxygen at a suitable reaction temperature and a suitable reaction pressure to produce an oxidized product. The liquid reaction mixture can have an aromatic feedstock having an oxidizable substituent as the oxidizable reactant. The oxidized product can include an aromatic compound having at least one carboxylic acid. For example, the aromatic feedstock can include a benzene ring having at least one oxidizable alkyl substituent, furan hetero-ring having at least one oxidizable alkyl substituent, a naphthalene poly-ring having at least one oxidizable alkyl substituent, derivatives thereof, and mixtures thereof.

    SPRAY PROCESS FOR SELECTIVE OXIDATION
    9.
    发明申请
    SPRAY PROCESS FOR SELECTIVE OXIDATION 审中-公开
    用于选择性氧化的喷雾方法

    公开(公告)号：WO2010111288A2

    公开(公告)日：2010-09-30

    申请号：PCT/US2010028343

    申请日：2010-03-23

    Applicant: UNIV KANSAS ,  SUBRAMANIAM BALA ,  BUSCH DARYLE H ,  NIU FENGHUI

    Inventor： SUBRAMANIAM BALA ,  BUSCH DARYLE H ,  NIU FENGHUI

    IPC: C07C51/255 ,  B01J8/00 ,  B01J12/00 ,  B01J19/26 ,  C07C63/00

    CPC classification number: C07C51/255 ,  B01J4/002 ,  B01J10/007 ,  B01J2219/00006 ,  B01J2219/00063 ,  B01J2219/00065 ,  B01J2219/00162 ,  C07C51/265 ,  C07C63/00

    Abstract: Oxidation process can include: introducing small droplets of liquid reaction mixture having oxidizable reactant, catalyst, and solvent into a reaction zone containing oxygen and diluent gas; and oxidizing the reactant with the oxygen at a suitable reaction temperature and a suitable reaction pressure to produce an oxidized product. The liquid reaction mixture can have an aromatic feedstock having an oxidizable substituent as the oxidizable reactant. The oxidized product can include an aromatic compound having at least one carboxylic acid. For example, the aromatic feedstock can include a benzene ring having at least one oxidizable alkyl substituent, furan hetero-ring having at least one oxidizable alkyl substituent, a naphthalene poly-ring having at least one oxidizable alkyl substituent, derivatives thereof, and mixtures thereof.

    Abstract translation: 氧化过程可以包括：将具有可氧化反应物，催化剂和溶剂的小液滴的液体反应混合物引入含有氧气和稀释气体的反应区; 并在合适的反应温度和合适的反应压力下用氧氧化反应物以产生氧化产物。 液体反应混合物可具有具有可氧化取代基的芳族原料作为可氧化反应物。 氧化产物可以包括具有至少一个羧酸的芳族化合物。 例如，芳族原料可以包括具有至少一个可氧化烷基取代基的苯环，具有至少一个可氧化烷基取代基的呋喃异环，具有至少一个可氧化烷基取代基的萘多环，其衍生物及其混合物 。

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