ORGANIC IRIDIUM COMPOSITIONS AND THEIR USE IN ELECTRONIC DEVICES
    6.
    发明申请
    ORGANIC IRIDIUM COMPOSITIONS AND THEIR USE IN ELECTRONIC DEVICES 审中-公开
    有机铱组合物及其在电子器件中的用途

    公开(公告)号:WO2008014037A2

    公开(公告)日:2008-01-31

    申请号:PCT/US2007068620

    申请日:2007-05-10

    IPC分类号: C07F15/00 C09K11/06

    摘要: The present invention provides compositions comprising at least one novel organic iridium compound which comprises at least one cyclometallated ligand and at least one ketopyrrole ligand. The organic iridium compositions of the present invention are referred to as Type (1) organic iridium compositions and are constituted such that no ligand of the novel organic iridium compound has a number average molecular weight of 2,000 grams per mole or greater (as measured by gel permeation chromatography). Type (1) organic iridium compositions are referred to herein as comprising "organic iridium complexes". The novel organic iridium compositions are useful in optoelectronic electronic devices such as OLED devices and photovoltaic devices. In one aspect, the invention provides novel organic iridium compositions useful in the preparation of OLED devices exhibiting enhanced color properties and light output efficiencies.

    摘要翻译: 本发明提供包含至少一种新型有机铱化合物的组合物,其包含至少一个环金属化配体和至少一个酮吡咯配体。 本发明的有机铱组合物被称为(1)型有机铱组合物,并且构成为使新型有机铱化合物的配体不具有2,000克/摩尔或更大的数均分子量(如通过凝胶 渗透色谱法)。 类型(1)有机铱组合物在本文中被称为包含“有机铱配合物”。 新颖的有机铱组合物可用于光电子电子器件如OLED器件和光伏器件。 一方面,本发明提供了用于制备显示增强的颜色性质和光输出效率的OLED器件的新型有机铱组合物。

    POLYMER FOR OPTOELECTRONIC DEVICE
    7.
    发明申请
    POLYMER FOR OPTOELECTRONIC DEVICE 审中-公开
    光电器件聚合物

    公开(公告)号:WO2011059553A1

    公开(公告)日:2011-05-19

    申请号:PCT/US2010/048360

    申请日:2010-09-10

    摘要: A polymer useful in an optoelectronic device comprises structural unit of formula I: wherein R 1 is, independently at each occurrence, a C 1- C 20 aliphatic radical, a C 3- C 20 aromatic radical, or a C 3- C 20 cyclo aliphatic radical; a is, independently at each occurrence, an integer ranging from 0-4; Ar 1 is aryl or heteroaryl; Ar 2 is fluorene; R 2 is alkylene, substituted alkylene, oxaalkylene, CO, or CO 2 ; R 3 , R 4 and R 5 are independently hydrogen, alkyl, alkoxy, alkylaryl, aryl, arylalkyl, heteroaryl, substituted alkyl; substituted alkoxy, substituted alkylaryl, substituted aryl, substituted arylalkyl, or substituted heteroaryl; and L is derived from phenylpyridine, tolylpyridine, benzothienylpyridine, phenylisoquinoline, dibenzoquinozaline, fluorenylpyridine, ketopyrrole, 2-(1- naphthyl)benzoxazole)), 2-phenylbenzoxazole, 2 phenylbenzothiazole, coumarin, thienylpyridine, phenylpyridine, benzothienylpyridine, 3 methoxy-2-phenylpyridine, thienylpyridine, phenylimine, vinylpyridine, pyridylnaphthalene, pyridylpyrrole, pyridylimidazole, phenylindole, derivatives thereof or combinations thereof.

    摘要翻译: 可用于光电子器件的聚合物包括式I的结构单元:其中R 1在每次出现时独立地为C 1 -C 20脂族基,C 3 -C 20芳族基或C 3 -C 20环脂族基; a在每次出现时独立地为0-4的整数; Ar 1是芳基或杂芳基; Ar2是芴; R2是亚烷基,取代的亚烷基,氧杂亚烷基,CO或CO 2; R3,R4和R5独立地是氢,烷基,烷氧基,烷基芳基,芳基,芳基烷基,杂芳基,取代的烷基; 取代的烷氧基,取代的烷基芳基,取代的芳基,取代的芳基烷基或取代的杂芳基; 苯甲酰吡啶,二苯并喹嗪,芴基吡啶,酮吡咯,2-(1-萘基)苯并恶唑,2-苯基苯并恶唑,苯基苯并噻唑,香豆素,噻吩并吡啶,苯基吡啶,苯并噻吩基吡啶,3-甲氧基-2-苯基吡啶, 噻吩基吡啶,苯基亚胺,乙烯基吡啶,吡啶基萘,吡啶基吡咯,吡啶基咪唑,苯基吲哚,其衍生物或其组合。

    ELECTRON-TRANSPORTING MATERIALS COMPRISING AND PROCESSES FOR MAKING THE SAME
    8.
    发明申请
    ELECTRON-TRANSPORTING MATERIALS COMPRISING AND PROCESSES FOR MAKING THE SAME 审中-公开
    电子传输材料的制作及其制造方法

    公开(公告)号:WO2010080472A1

    公开(公告)日:2010-07-15

    申请号:PCT/US2009/068392

    申请日:2009-12-17

    IPC分类号: C07D401/14 H01L51/05

    CPC分类号: C07D213/16 C07D213/53

    摘要: Compound of formula C is made by reacting a compound of formula A with an pyridyl boronic acid or pyridyl borate esier to form a compound of formula B; and combining the compound of formula B with a pyridyl dihalide to form the compound of C; wherein R 3 R 4 , R 5 , R 6 and R 7 are, independently at each occurrence, a C 1 -C 20 aliphatic radical, a C 3 -C 20 aromatic radical or a C 3 -C 20 , cycioaliphatic radical; X is. independently at each occurrence, CH or N; Y is chloro or bromo; Z is bromo or iodo: and when Y is bromo, Z is iodo; d, e, and g are, independently at each occurrence, an integer ranging from 0-4; f is an integer ranging from 0-2; and h is an integer ranging from 0-3.

    摘要翻译: 式C的化合物通过使式A的化合物与吡啶基硼酸或吡啶基硼酸盐反应形成式B的化合物来制备; 并将式B化合物与吡啶基二卤化物结合形成C的化合物; 其中R3 R4,R5,R6和R7在每次出现时独立地为C 1 -C 20脂族基团,C 3 -C 20芳族基团或C 3 -C 20环脂族基团; X是。 在每次出现时独立地为CH或N; Y是氯或溴; Z是溴或碘:当Y是溴时,Z是碘; d,e和g各自独立地为0-4的整数; f是0-2的整数; h为0-3的整数。

    ORGANIC METAL COMPLEXES FOR USE IN OPTOELECTRONIC DEVICES
    9.
    发明申请
    ORGANIC METAL COMPLEXES FOR USE IN OPTOELECTRONIC DEVICES 审中-公开
    用于光电器件的有机金属复合物

    公开(公告)号:WO2010074957A1

    公开(公告)日:2010-07-01

    申请号:PCT/US2009/067115

    申请日:2009-12-08

    IPC分类号: C07F15/00 C09K11/06 H01L51/50

    摘要: The invention provides an organic metal complex represented by the formula (I), wherein M is a metal selected from Rh, Ir, or Pt; Y represents N or O; R 1 represents a hydrogen, a halogen, a nitro group, an amino group, a hydroxyl group, a C 3 -C 40 aromatic radical, a C 1 -C 50 aliphatic radical, and a C 3 -C 50 cycloaliphatic radical; R 2 represents a hydrogen, C 3 - C 20 aromatic radical, C 1 -C 50 aliphatic radical, or a C 3 -C 50 cycloaliphatic radical; or R 1 and R 2 , together with the adjacent Y, may form a ring, preferably a 5- or 6-membered ring; n1 has a value of from O to 3; and n2 has a value of O to 2; mi has a value of at least 1; and m 2 has a value of at least 1 provided that m 1 +m 2 is 3.

    摘要翻译: 本发明提供由式(I)表示的有机金属络合物,其中M为选自Rh,Ir或Pt的金属; Y表示N或O; R1表示氢,卤素,硝基,氨基,羟基,C3-C40芳族基,C1-C50脂族基和C3-C50脂环族基; R 2表示氢,C 3 -C 20芳族基团,C 1 -C 50脂族基团或C 3 -C 50脂环族基团; 或R 1和R 2与相邻的Y一起可以形成环,优选5-或6-元环; n1的值从0到3; n2的值为0〜2; mi的值至少为1; 如果m1 + m2为3,则m2的值至少为1。

    PHOSPHORESCENT IRIDIUM COMPLEXES
    10.
    发明申请
    PHOSPHORESCENT IRIDIUM COMPLEXES 审中-公开
    磷酸盐复合物

    公开(公告)号:WO2010051100A1

    公开(公告)日:2010-05-06

    申请号:PCT/US2009/056160

    申请日:2009-09-08

    摘要: Metal complexes of formula I and IA and polymers derived from the complexes are useful in optoelectronic devices (see I and IA) wherein M is Ir, Co or Rh; XX is a cyclometallated ligand (see XX); R 1 is hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, or substituted arylalkyl; R 2 is hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, substituted arylalkyl; and at least one of R 1 and R 2 is other than hydrogen; R 1a is hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, or substituted arylalkyl; R 2a is hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, substituted arylalkyl; and at least one of R 1a and R 2a is substituted alkyl, substituted aryl, substituted arylalkyl, and at least one substitutent of the substituted alkyl, substituted aryl, or substituted arylalkyl is a polymehzable group.

    摘要翻译: 式I和IA的金属络合物和衍生自络合物的聚合物可用于光电器件(见I和IA),其中M是Ir,Co或Rh; XX是环金属配体(参见XX); R 1是氢,烷基,取代的烷基,芳基,取代的芳基,芳基烷基或取代的芳基烷基; R2是氢,烷基,取代的烷基,芳基,取代的芳基,芳基烷基,取代的芳基烷基; 并且R 1和R 2中的至少一个不是氢; R 1a是氢,烷基,取代的烷基,芳基,取代的芳基,芳基烷基或取代的芳基烷基; R2a是氢,烷基,取代的烷基,芳基,取代的芳基,芳基烷基,取代的芳基烷基; 并且R 1a和R 2a中的至少一个是取代的烷基,取代的芳基,取代的芳烷基,并且取代的烷基,取代的芳基或取代的芳烷基的至少一个取代基是可聚合的基团。