公开(公告)号：WO2011114089A1

公开(公告)日：2011-09-22

申请号：PCT/GB2011/000283

申请日：2011-03-03

Applicant: QINETIQ LIMITED ,  CLARIDGE, Robert, Peter ,  COMBES, David, Johnathon

Inventor： CLARIDGE, Robert, Peter ,  COMBES, David, Johnathon

IPC: F42B33/02 ,  F42C15/184 ,  F42C15/34 ,  C06C7/00 ,  C06C7/02

CPC classification number: F42B33/0207 ,  C06B21/0033 ,  C06C7/00 ,  C06C7/02 ,  F42C15/184 ,  F42C15/34 ,  Y10T29/49002

Abstract: This invention relates to a MEMS detonator, in particular the production of MEMS scale detonators via the use of a microreactor (3). The invention further lies in a reproducible manufacturing method of MEMS scale detonators, for use in safety and arming units (SAU), which are used in warheads and munitions. A warhead comprising a MEMS detonator may find particular use in increasing the IM compliance of munitions. The method involves the use of high pressure input of two solutions (2, 2a) into a microreactor (3) to form an in-situ precipitation reaction, which furnishes an initiatory (ι.e. primary) explosive, wherein the explosive and supernatant liquid is directly fed into a microchamber, using the microcavities in the septum as a MEMS sieve to retain the explosive and form a MEMS detonator.

Abstract translation: 本发明涉及一种MEMS雷管，特别是通过使用微反应器（3）来生产MEMS标尺雷管。 本发明进一步在MEMS重力制造方法的MEMS尺度雷管中，用于在弹头和弹药中使用的安全和装备单元（SAU）。 包括MEMS雷管的弹头可以特别用于增加弹药的IM符合性。 该方法包括使用两个溶液（2,2a）的高压输入到微反应器（3）中以形成原位沉淀反应，其提供引发剂（？原代）爆炸物，其中所述爆炸物和上清液 将液体直接进料到微室中，使用隔膜中的微腔作为MEMS筛子来保留炸药并形成MEMS雷管。

公开(公告)号：WO2012013926A1

公开(公告)日：2012-02-02

申请号：PCT/GB2011001119

申请日：2011-07-26

Applicant: QINTETIQ LTD ,  CHURCH PHILIP DUNCAN ,  CLARIDGE ROBERT PETER ,  GOULD PETER JOHN ,  TOWNSLEY RICHARD GORDON

Inventor： CHURCH PHILIP DUNCAN ,  CLARIDGE ROBERT PETER ,  GOULD PETER JOHN ,  TOWNSLEY RICHARD GORDON

IPC: F42B1/032

CPC classification number: F42B1/032 ,  E21B43/117

Abstract: An oil and gas welI shaped charge perforator capable of providing an exothermic reaction after detonation is provided, comprising a housing (2), a high explosive (3), and a reactive liner (6) where the high explosive is positioned between the reactive liner and the housing. The reactive liner (6) is produced from a reactive composition which is capable of sustaining an exothermic reaction during the formation of the cutting jet. The composition is a pressed i.e. compacted particulate composition comprising at least two metals, wherein one of the metals is present as spherical particulate, and the other metal is present as a non-spherical particulate. There may also be at least one further metal, which is not capable of an exothermic reaction with the reactive composition, present in an amount greater than 10% w/w of the liner. To aid consolidation a binder may also be added.

Abstract translation: 提供了能够在爆震之后提供放热反应的油气焊接成形电荷穿孔器，包括壳体（2），高爆炸物（3）和反应性衬套（6），其中高爆炸物位于反应性衬垫 和房屋。 反应性衬垫（6）由能够在切割射流形成期间维持放热反应的反应性组合物制备。 该组合物是压制的，即压实的颗粒组合物，其包含至少两种金属，其中金属之一以球形颗粒存在，而另一种金属以非球形颗粒存在。 还可以存在至少一种另外的金属，其不能与反应性组合物发生放热反应，其量大于衬管的10％w / w。 为了帮助固结，还可以添加粘合剂。

公开(公告)号：WO2004106268A3

公开(公告)日：2005-03-24

申请号：PCT/GB2004002305

申请日：2004-05-27

Applicant: QINETIQ NANOMATERIALS LTD ,  VINE TRACY ,  CLARIDGE ROBERT PETER ,  JORDAN TERRY ,  COMFORT NIGEL PAUL ,  DAMERELL WILLIAM NORMAN

Inventor： VINE TRACY ,  CLARIDGE ROBERT PETER ,  JORDAN TERRY ,  COMFORT NIGEL PAUL ,  DAMERELL WILLIAM NORMAN

IPC: B41M3/00 ,  B64G1/26 ,  B64G1/40 ,  C06B21/00 ,  C06B45/00 ,  C06C5/00 ,  C06C9/00 ,  C06C15/00 ,  C09D11/00 ,  C09D11/02

CPC classification number: C09D11/30 ,  B41M3/006 ,  B64G1/26 ,  B64G1/403 ,  C06B21/0083 ,  C06B45/00 ,  C06C5/00 ,  C06C9/00 ,  C06C15/00 ,  C09D11/02

Abstract: An explosive device is provided, containing an explosive formulation or explosive ink, which is capable of being disposed 'onto a substrate for the device by well known printing and depositing techniques, such as screen printing, ink jet printing or gravure methods. The formulation contains an ink resin binder, a metal and a non-metal in particulate form where the diameter of the particles is less than l0µm, such that when the formulation is heated, a reactive output results.' The substrate can be chosen from any inert material or alternatively an energetic material for which the formulation provides a means of initiation. Preferred metals are aluminium iron or titanium and non-metals are carbon, silicon, boron or metal oxides such as copper oxide, nickel oxide or molybdenum oxide. Devices according to the invention may take the form of a; pyrotechnic train, initiators, fuseheads, initiators for gas generators, microthrusters, and may form part of a larger system containing energetic materials.

Abstract translation: 提供一种爆炸装置，其包含爆炸性制剂或爆炸性油墨，其能够通过公知的印刷和沉积技术（例如丝网印刷，喷墨印刷或凹版印刷方法）设置在装置的基材上。 该制剂含有油墨树脂粘合剂，金属和颗粒形式的非金属，其中颗粒的直径小于10μm，使得当配方被加热时，产生反应性输出。 基材可以选自任何惰性材料，或者选择性地为制剂提供引发手段的高能材料选择。 优选的金属是铝铁或钛，非金属是碳，硅，硼或金属氧化物，例如氧化铜，氧化镍或氧化钼。 根据本发明的装置可以采取以下形式： 烟火列车，启动器，保险丝头，气体发生器的启动器，微型推进器，并且可以形成包含高能材料的较大系统的一部分。

公开(公告)号：WO2004106268A2

公开(公告)日：2004-12-09

申请号：PCT/GB2004/002305

申请日：2004-05-27

Applicant: QINETIQ NANOMATERIALS LIMITED ,  VINE, Tracy ,  CLARIDGE, Robert, Peter ,  JORDAN, Terry ,  COMFORT, Nigel, Paul ,  DAMERELL, William, Norman

Inventor： VINE, Tracy ,  CLARIDGE, Robert, Peter ,  JORDAN, Terry ,  COMFORT, Nigel, Paul ,  DAMERELL, William, Norman

IPC: C06C9/00

CPC classification number: C09D11/30 ,  B41M3/006 ,  B64G1/26 ,  B64G1/403 ,  C06B21/0083 ,  C06B45/00 ,  C06C5/00 ,  C06C9/00 ,  C06C15/00 ,  C09D11/02

Abstract: An explosive device is provided, containing an explosive formulation or explosive ink, which is capable of being disposed 'onto a substrate for the device by well known printing and depositing techniques, such as screen printing, ink jet printing or gravure methods. The formulation contains an ink resin binder, a metal and a non-metal in particulate form where the diameter of the particles is less than l0µm, such that when the formulation is heated, a reactive output results.' The substrate can be chosen from any inert material or alternatively an energetic material for which the formulation provides a means of initiation. Preferred metals are aluminium iron or titanium and non-metals are carbon, silicon, boron or metal oxides such as copper oxide, nickel oxide or molybdenum oxide. Devices according to the invention may take the form of a; pyrotechnic train, initiators, fuseheads, initiators for gas generators, microthrusters, and may form part of a larger system containing energetic materials.

Abstract translation: 提供一种爆炸装置，其包含爆炸性制剂或爆炸性油墨，其能够通过公知的印刷和沉积技术（例如丝网印刷，喷墨印刷或凹版印刷方法）设置在装置的基材上。 该制剂含有油墨树脂粘合剂，金属和颗粒形式的非金属，其中颗粒的直径小于10μm，使得当配方被加热时，产生反应性输出。 基材可以选自任何惰性材料，或者选择性地为制剂提供引发手段的高能材料选择。 优选的金属是铝铁或钛，非金属是碳，硅，硼或金属氧化物，例如氧化铜，氧化镍或氧化钼。 根据本发明的装置可以采取以下形式： 烟火列车，启动器，保险丝头，气体发生器的启动器，微型推进器，并且可以形成包含高能材料的较大系统的一部分。

公开(公告)号：WO1997022590A1

公开(公告)日：1997-06-26

申请号：PCT/GB1996003020

申请日：1996-12-09

Applicant: THE SECRETARY OF STATE FOR DEFENCE ,  MILLAR, Ross, Wood ,  CLARIDGE, Robert, Peter ,  SANDALL, John, Paul, Benet ,  THOMPSON, Claire

Inventor： THE SECRETARY OF STATE FOR DEFENCE

IPC: C07D213/76

CPC classification number: C07D213/76 ,  C07C201/10 ,  C07C201/16 ,  C07C381/10 ,  C07D213/61 ,  C07D239/42 ,  C07D241/16 ,  C07D241/20 ,  C07D251/44 ,  C07D251/46 ,  C07C205/12 ,  C07C205/06

Abstract: A method of nitrating electron-deficient carbocyclic or heterocyclic aromatic compounds such as pyridines, diazines and triazines and benzenoid aromatics having electron-withdrawing substituents involves first reacting the aromatic species with a sulphilimine species or with the corresponding N-alkali metal salt thereof to generate an N-(hetero)aryl-S,S-dialkyl, diaryl or alkylarylsulphilimine derivative. This intermediate may then be readily oxidised under relatively mild conditions using a peroxycarboxylic acid such as m-chloroperbenzoic acid, peracetic or peroxytrifluoroacetic acid. Good yields of nitrated products are obtained including some previously unprepared. The novel N-alkali(alkylaryl)sulphilimine reagents are prepared by reacting an alkali metal hydride, an alkali metal hydrogenous base or an alkyl lithium with the corresponding sulphilimine. Preferred salts are the N-lithio types and the preferred sulphilimine is diphenylsulphilimine. Where the salt is used reaction should be in an aprotic solvent but if the sulphilimine per se is the reagent a polar solvent is used.

Abstract translation: 硝化电子缺乏的碳环或杂环芳族化合物如吡啶，二嗪和三嗪的方法和具有吸电子取代基的苯系芳族化合物包括首先使芳族物质与亚硫酰胺物质或其相应的N-碱金属盐反应，生成 N-（杂）芳基-S，S-二烷基，二芳基或烷基芳基亚磺酰亚胺衍生物。 然后可以使用过氧羧酸如间氯过苯甲酸，过乙酸或过氧三氟乙酸在相对温和的条件下容易地氧化该中间体。 获得了硝化产物的良好产率，包括一些以前没有准备的产品。 通过使碱金属氢化物，碱金属氢碱或烷基锂与相应的硫化亚胺反应制备新型N-碱（烷基芳基）亚硫酰胺试剂。 优选的盐是N-亚硫基类型，优选的亚硫酰亚胺是二苯基亚硫酰亚胺。 在使用盐的情况下，反应应在非质子溶剂中，但如果亚硫酰胺本身是试剂，则使用极性溶剂。

公开(公告)号：WO2012013926A8

公开(公告)日：2012-02-02

申请号：PCT/GB2011/001119

申请日：2011-07-26

Applicant: QINETIQ LIMITED ,  CHURCH, Philip, Duncan ,  CLARIDGE, Robert, Peter ,  GOULD, Peter, John ,  TOWNSLEY, Richard, Gordon

Inventor： CHURCH, Philip, Duncan ,  CLARIDGE, Robert, Peter ,  GOULD, Peter, John ,  TOWNSLEY, Richard, Gordon

IPC: F42B1/032

Abstract: An oil and gas welI shaped charge perforator capable of providing an exothermic reaction after detonation is provided, comprising a housing (2), a high explosive (3), and a reactive liner (6) where the high explosive is positioned between the reactive liner and the housing. The reactive liner (6) is produced from a reactive composition which is capable of sustaining an exothermic reaction during the formation of the cutting jet. The composition is a pressed i.e. compacted particulate composition comprising at least two metals, wherein one of the metals is present as spherical particulate, and the other metal is present as a non-spherical particulate. There may also be at least one further metal, which is not capable of an exothermic reaction with the reactive composition, present in an amount greater than 10% w/w of the liner. To aid consolidation a binder may also be added.