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    COMPOSITE MATERIAL HAVING A THERMALLY-REACTIVE-ENDCAPPED IMIDE OLIGOMER AND CARBON NANOFILLERS
    1.
    发明申请
    COMPOSITE MATERIAL HAVING A THERMALLY-REACTIVE-ENDCAPPED IMIDE OLIGOMER AND CARBON NANOFILLERS 审中-公开
    具有热反应终止酰亚胺低聚物和碳纳米填料的复合材料

    公开(公告)号：WO2008054864A3

    公开(公告)日：2008-07-31

    申请号：PCT/US2007067386

    申请日：2007-04-25

    Applicant: U S A AS REPRESENTED BY THE AD ,  CONNELL JOHN W ,  SIOCHI EMILIE J ,  GHOSE SAYATA ,  DELOZIER DONAVON M ,  WATSON KENT A ,  WORKING DENNIS C

    Inventor： CONNELL JOHN W ,  SIOCHI EMILIE J ,  GHOSE SAYATA ,  DELOZIER DONAVON M ,  WATSON KENT A ,  WORKING DENNIS C

    IPC: C08J5/00

    CPC classification number: C08J5/005 ,  B82Y30/00 ,  C08J2379/08 ,  C08K3/04 ,  C08K7/24 ,  C08K2201/011 ,  C08L79/08

    Abstract: Embodiments of the invention provide a composite material having sufficient strength to form structural components of an aerospace vehicle, while also having sufficient electrical conductivity to dissipate electrostatic charge. As such, a composite material comprises an imide oligomer having thermally reactive endcaps and carbon nanofillers. The imide oligomer may comprise a phenyl ethynyl terminated imide. The phenylethynyl terminated imide may have a molecular weight of less than about 5000, or may have a molecular weight in the range of about 250 to about 5000. In particular, the phenylethynyl terminated imide may have a molecular weight of about 1500. The carbon nanofillers may be selected from the group consisting of carbon nanotubes, carbon nanofibcrs, expanded graphite, exfoliated graphite and combinations thereof. The carbon nanotubes may be selected from the group consisting of single-walled carbon nanotubes, double-walled carbon nanotubes, multi-walled carbon nanotubes and combinations thereof.

    Abstract translation: 本发明的实施例提供具有足够强度的复合材料以形成航天飞行器的结构部件，同时还具有足够的导电性以消散静电荷。 如此，复合材料包含具有热反应性端帽的酰亚胺低聚物和碳纳米填料。 酰亚胺低聚物可以包含苯基乙炔基封端的酰亚胺。 苯乙炔基封端的酰亚胺可具有小于约5000的分子量，或可具有约250至约5000的分子量。特别地，苯乙炔基封端的酰亚胺可具有约1500的分子量。碳纳米填料 可以选自碳纳米管，碳纳米纤维，膨胀石墨，膨胀石墨及其组合。 碳纳米管可以选自由单壁碳纳米管，双壁碳纳米管，多壁碳纳米管及其组合组成的组。

    MIXTURES COMPRISING THIOPHENE/ANION DISPERSIONS AND CERTAIN ADDITIVES FOR PRODUCING COATINGS EXHIBITING IMPROVED CONDUCTIVITY, AND METHODS RELATED THERETO
    2.
    发明申请
    MIXTURES COMPRISING THIOPHENE/ANION DISPERSIONS AND CERTAIN ADDITIVES FOR PRODUCING COATINGS EXHIBITING IMPROVED CONDUCTIVITY, AND METHODS RELATED THERETO 审中-公开
    包含噻吩/阴离子分散体和特定添加剂的混合物用于制备表现出改进的导电性的涂层，以及与其相关的方法

    公开(公告)号：WO2004021366A2

    公开(公告)日：2004-03-11

    申请号：PCT/US2003/001842

    申请日：2003-01-21

    Applicant: ELECON, INC. ,  GO, Pin ,  FREITAG, Dieter ,  CONNELL, John, W.

    Inventor： GO, Pin ,  FREITAG, Dieter ,  CONNELL, John, W.

    IPC: H01B1/00

    CPC classification number: H01B1/12 ,  H01B1/122 ,  H01G9/028 ,  H01L51/0037 ,  H01L51/5206 ,  H05K3/188 ,  Y02E10/549 ,  Y02P70/521

    Abstract: Disclosed are mixtures comprising aqueous thiophene/anion dispersions, such as polythiophene/polystyrene sulfonate aqueous dispersions, and additives, as well as coatings produced therefrom. Coatings produced from these mixtures yield significant improvements in electrical conductivity without the need for a high temperature treatment as compared to coatings produced from unmodified aqueous polythiophene dispersions (e.g., Baytron®P) and to coatings produced from state-of the-art aqueous polythiophene-additive mixtures. These conductivity improvements are achieved without detracting from the optical transparency of the coating. Because characteristics of volume resistivity of less than 6.6 ohm-cm and optical transmission greater than 80% are important for conductive coating applications, coatings produced from the mixtures of the present invention have significant advantages over coatings produced from the state-of-the-art mixtures in many applications. Also disclosed are a variety of substrates or articles of manufacture coated with the mixtures of the present invention for use in various applications where a combination of high electrical conductivity, -excellent optical transparency and low temperature processing are important, such as electronic and optoelectronic devices.

    Abstract translation: 所公开的是包含含水噻吩/阴离子分散体如聚噻吩/聚苯乙烯磺酸盐水分散体和添加剂的混合物，以及由其制成的涂层。 与由未改性的含水聚噻吩分散体（例如BaytronP）生产的涂层相比，由这些混合物生产的涂层产生显着的电导率改进，而不需要高温处理，并且由现有技术的含水聚噻吩 - 添加混合物。 这些导电性改进是在不减损涂层的光学透明度的情况下实现的。 由于体积电阻率小于6.6ohm-cm且光学透射率大于80％的特性对于导电涂层应用是重要的，因此由本发明的混合物生产的涂层与由现有技术生产的涂层相比具有显着的优点 许多应用中的混合物。 还公开了用本发明混合物涂覆的各种基材或制品，用于高导电性，优异的光学透明性和低温处理的重要组合的各种应用中，例如电子和光电子器件。

    COMPOSITE MATERIAL HAVING A THERMALLY-REACTIVE-ENDCAPPED IMIDE OLIGOMER AND CARBON NANOFILLERS
    4.
    发明申请
    COMPOSITE MATERIAL HAVING A THERMALLY-REACTIVE-ENDCAPPED IMIDE OLIGOMER AND CARBON NANOFILLERS 审中-公开
    具有热反应性终止的低聚物和碳纳米管的复合材料

    公开(公告)号：WO2008054864A2

    公开(公告)日：2008-05-08

    申请号：PCT/US2007/067386

    申请日：2007-04-25

    Applicant: U.S.A. AS REPRESENTED BY THE ADMINISTRATOR OF THE NATIONAL AERONAUTICS AND SPACE ADMINISTRATION ,  CONNELL, John, W. ,  SIOCHI, Emilie, J. ,  GHOSE, Sayata ,  DELOZIER, Donavon, M. ,  WATSON, Kent, A. ,  WORKING, Dennis, C.

    Inventor： CONNELL, John, W. ,  SIOCHI, Emilie, J. ,  GHOSE, Sayata ,  DELOZIER, Donavon, M. ,  WATSON, Kent, A. ,  WORKING, Dennis, C.

    IPC: B32B27/02

    CPC classification number: C08J5/005 ,  B82Y30/00 ,  C08J2379/08 ,  C08K3/04 ,  C08K7/24 ,  C08K2201/011 ,  C08L79/08

    Abstract: Embodiments of the invention provide a composite material having sufficient strength to form structural components of an aerospace vehicle, while also having sufficient electrical conductivity to dissipate electrostatic charge. As such, a composite material comprises an imide oligomer having thermally reactive endcaps and carbon nanofillers. The imide oligomer may comprise a phenyl ethynyl terminated imide. The phenylethynyl terminated imide may have a molecular weight of less than about 5000, or may have a molecular weight in the range of about 250 to about 5000. In particular, the phenylethynyl terminated imide may have a molecular weight of about 1500. The carbon nanofillers may be selected from the group consisting of carbon nanotubes, carbon nanofibcrs, expanded graphite, exfoliated graphite and combinations thereof. The carbon nanotubes may be selected from the group consisting of single-walled carbon nanotubes, double-walled carbon nanotubes, multi-walled carbon nanotubes and combinations thereof.

    Abstract translation: 本发明的实施例提供了具有足够的强度以形成航空航天车辆的结构部件的复合材料，同时还具有足够的导电性以消散静电电荷。 因此，复合材料包括具有热反应性端帽和碳纳米填料的酰亚胺低聚物。 酰亚胺低聚物可以包含苯基乙炔基封端的酰亚胺。 苯基乙炔基封端的酰亚胺可以具有小于约5000的分子量，或者可以具有约250至约5000的分子量。特别地，苯基乙炔基封端的酰亚胺可以具有约1500的分子量。碳纳米填料 可以选自碳纳米管，碳纳米纤维，膨胀石墨，剥离石墨及其组合。 碳纳米管可以选自单壁碳纳米管，双壁碳纳米管，多壁碳纳米管及其组合。

    TAILORABLE DIELECTRIC MATERIAL WITH COMPLEX PERMITTIVITY CHARACTERISTICS
    5.
    发明申请
    TAILORABLE DIELECTRIC MATERIAL WITH COMPLEX PERMITTIVITY CHARACTERISTICS 审中-公开
    具有复合电阻特性的可定量电介质材料

    公开(公告)号：WO2009014959A2

    公开(公告)日：2009-01-29

    申请号：PCT/US2008070189

    申请日：2008-07-16

    Applicant: NASA ,  DUDLEY KENNETH L ,  ELLIOTT HOLLY A ,  CONNELL JOHN W ,  SMITH JOSEPH G JR ,  GHOSE SAYATA ,  DELOZIER DONAVON MARK ,  WATSON KENT A

    Inventor： DUDLEY KENNETH L ,  ELLIOTT HOLLY A ,  CONNELL JOHN W ,  SMITH JOSEPH G JR ,  GHOSE SAYATA ,  DELOZIER DONAVON MARK ,  WATSON KENT A

    IPC: B32B5/16 ,  C08K3/08

    CPC classification number: C08K3/08 ,  B82Y30/00 ,  C08K2201/011

    Abstract: A dielectric material includes a network of nanosubstrates, such as but not limited to nanotubes, nanosheets, or other nanomaterials or nanostructures, a polymer base material or matrix, and nanoparticles constructed at least partially of an elemental metal. The network has a predetermined nano substrate loading percentage by weight with respect to a total weight of the dielectric material, and a preferential or predetermined longitudinal alignment with respect to an orientation of an incident electrical field. A method of forming the dielectric material includes depositing the metal-based nanoparticles onto the nanosubstrates and subsequently mixing these with a polymer matrix. Once mixed, alignment can be achieved by melt extrusion or a similar mechanical shearing process. Alignment of the nanosubstrate may be in horizontal or vertica! direction with respect to the orientation of an incident electrical field.

    Abstract translation: 介电材料包括纳米基底的网络，纳米基底例如但不限于纳米管，纳米片或其他纳米材料或纳米结构，聚合物基底材料或基质，以及至少部分由元素金属构造的纳米颗粒。 网络相对于介电材料的总重量具有预定的纳米基底负载重量百分比，并且相对于入射电场的取向具有优先的或预定的纵向对齐。 形成介电材料的方法包括将金属基纳米颗粒沉积到纳米基底上，并随后将这些与聚合物基质混合。 一旦混合，对准可以通过熔融挤出或类似的机械剪切过程来实现。 纳米基底的对齐可以是水平或垂直的。 方向相对于入射电场的取向。

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