公开(公告)号：WO2012164054A1

公开(公告)日：2012-12-06

申请号：PCT/EP2012/060329

申请日：2012-06-01

Applicant: FÁBRICA NACIONAL DE MONEDA Y TIMBRE - REAL CASA DE LA MONEDA ,  CONSEJO SUPERIOR DE INVESTIGACIONES CIENTÍFICAS C.S.I.C. ,  ROMERO FANEGO, Juan José ,  GARCÍA JUEZ, Vicente ,  FERNÁNDEZ LOZANO, José Francisco ,  GAMO ARANDA, Javier ,  RODRÍGUEZ BARBERO, Miguel Ángel ,  RUIZ QUEVEDO, Andrés ,  LORITE VILLALBA, Israel

Inventor： ROMERO FANEGO, Juan José ,  GARCÍA JUEZ, Vicente ,  FERNÁNDEZ LOZANO, José Francisco ,  GAMO ARANDA, Javier ,  RODRÍGUEZ BARBERO, Miguel Ángel ,  RUIZ QUEVEDO, Andrés ,  LORITE VILLALBA, Israel

IPC: B42D15/00 ,  G07D7/12

CPC classification number: B42D25/405 ,  B42D25/29 ,  B42D25/378 ,  B42D2033/20 ,  B42D2035/34 ,  G01N21/65 ,  G07D7/1205

Abstract: The present invention relates to the use of non deactivable security markers comprising the combination of at least two types of nanoparticles of materials presenting Raman effect, wherein said nanoparticles are in a dispersed state or is forming agglomerates of between 2 and 500 nanoparticles. The invention also relates to security documents, articles or elements incorporating these markers, as well as to a method and system for the detection thereof.

Abstract translation: 本发明涉及使用不可失活的安全标记物，其包括呈现拉曼效应的材料的至少两种类型的纳米颗粒的组合，其中所述纳米颗粒处于分散状态或形成2至500个纳米颗粒的附聚物。 本发明还涉及包含这些标记的安全性文件，物品或元件，以及用于检测它们的方法和系统。

公开(公告)号：WO2014090867A2

公开(公告)日：2014-06-19

申请号：PCT/EP2013/076207

申请日：2013-12-11

Applicant: FÁBRICA NACIONAL DE MONEDA Y TIMBRE - REAL CASA DE LA MONEDA ,  NANOGAP SUB-NM-POWDER, SOCIEDAD ANONIMA

Inventor： LOPEZ QUINTELA, Manuel Arturo ,  GARCÍA JUEZ, Vicente

IPC: C09K11/58 ,  C09K11/02 ,  B42D15/00

CPC classification number: B41M3/144 ,  B42D25/29 ,  B42D25/36 ,  C09D11/037 ,  C09D11/50 ,  C09K11/02 ,  C09K11/58 ,  C22C5/02 ,  C22C5/06 ,  D21H21/42 ,  D21H21/44 ,  G01N21/64 ,  G01N21/6408 ,  G07D7/1205

Abstract: The present invention relates to the use of nanocompounds as non deactivable security markers comprising a charge-transfer complex of at least two different size metal atomic quantum clusters (AQCs). These nanocompounds are luminescent, particularly fluorescent after external excitation. The invention also relates to security documents, articles or elements incorporating these markers as well as to a method and a system for detecting the same.

Abstract translation: 本发明涉及纳米化合物作为包括至少两种不同尺寸的金属原子量子簇（AQC）的电荷转移复合物的非不可转化安全标记物的用途。 这些纳米化合物是发光的，特别是外部激发后的荧光。 本发明还涉及包含这些标记的安全性文件，物品或元件以及用于检测它们的方法和系统。

公开(公告)号：WO2012131045A1

公开(公告)日：2012-10-04

申请号：PCT/EP2012/055806

申请日：2012-03-30

Applicant: FÁBRICA NACIONAL DE MONEDA Y TIMBRE - REAL CASA DE LA MONEDA ,  CONSEJO SUPERIOR DE INVESTIGACIONES CIENTÍFICAS C.S.I.C. ,  ROMERO FANEGO, Juan José ,  GARCÍA JUEZ, Vicente ,  FERNÁNDEZ LOZANO, José Francisco ,  GAMO ARANDA, Javier ,  RODRÍGUEZ BARBERO, Miguel Ángel

Inventor： ROMERO FANEGO, Juan José ,  GARCÍA JUEZ, Vicente ,  FERNÁNDEZ LOZANO, José Francisco ,  GAMO ARANDA, Javier ,  RODRÍGUEZ BARBERO, Miguel Ángel

IPC: C09D7/12 ,  B41M3/14 ,  B42D15/00 ,  G07D7/06

CPC classification number: G01N23/06 ,  B41M3/144 ,  B42D25/00 ,  B42D25/23 ,  B42D25/29 ,  B42D25/328 ,  B42D25/333 ,  B42D25/355 ,  B42D25/378 ,  B42D2033/20 ,  B42D2033/32 ,  C09D5/32 ,  C09D7/61 ,  C09D7/70 ,  G01N22/00 ,  G06K7/10009 ,  G06K19/14 ,  G07D7/06 ,  G07D7/10 ,  G07D7/1205

Abstract: The present invention relates to the use of non-deactivatable security compositions comprising the combination of at least two types of particles of oxide materials, where said particles have a different size and/or morphology, and where the inorganic oxide materials have at least one transition metal or one lanthanide element, and radiofrequency wave absorption properties. The invention also relates to security articles, documents or elements incorporating these compositions, as well as to a method and to a system for detection thereof.

Abstract translation: 本发明涉及使用不可失活的安全性组合物，其包含至少两种类型的氧化物材料颗粒的组合，其中所述颗粒具有不同的尺寸和/或形态，并且其中无机氧化物材料具有至少一个转变 金属或一种镧系元素，以及射频波吸收特性。 本发明还涉及包含这些组合物的安全性物品，文件或元件，以及用于检测它们的方法和系统。

公开(公告)号：WO2012107558A1

公开(公告)日：2012-08-16

申请号：PCT/EP2012/052307

申请日：2012-02-10

Applicant: FÁBRICA NACIONAL DE MONEDA Y TIMBRE - REAL CASA DE LA MONEDA ,  ORELLANA MORALEDA, Guillermo ,  GARCÍA FRESNADILLO, David ,  VARELA GARCÍA DE OTEYZA, Paloma ,  GAMO ARANDA, Javier ,  SILVÁN POBES, José Miguel ,  ÁLVAREZ MARTÍNEZ, Fernando ,  RUIZ QUEVEDO, Andrés

Inventor： ORELLANA MORALEDA, Guillermo ,  GARCÍA FRESNADILLO, David ,  VARELA GARCÍA DE OTEYZA, Paloma ,  GAMO ARANDA, Javier ,  SILVÁN POBES, José Miguel ,  ÁLVAREZ MARTÍNEZ, Fernando ,  RUIZ QUEVEDO, Andrés

IPC: C09K11/06

CPC classification number: C07F15/0053 ,  B42D15/00 ,  B42D25/387 ,  C09D11/00 ,  C09D11/50 ,  C09K11/06 ,  C09K2211/185

Abstract: The present invention relates to a new family of luminescent pigments consisting of a salt of two ruthenium(II) complex ions of opposite sign charges comprising N- chelating heterocyclic ligands and to their use in security applications to prevent counterfeiting. The invention also refers to ink compositions and to the security documents or secured goods comprising said luminescent pigments.

Abstract translation: 本发明涉及由包含N-螯合杂环配体的相反符号电荷的两种钌（II）络合离子的盐组成的新的发光颜料系列，以及它们在安全应用中用于防止假冒的用途。 本发明还涉及油墨组合物和包括所述发光颜料的安全证件或担保物品。

公开(公告)号：WO2016202979A1

公开(公告)日：2016-12-22

申请号：PCT/EP2016/064004

申请日：2016-06-17

Applicant: FÁBRICA NACIONAL DE MONEDA Y TIMBRE - REAL CASA DE LA MONEDA ,  CONSEJO SUPERIOR DE INVESTIGACIONES CIENTÍFICAS

Inventor： FERNÁNDEZ LOZANO, José Francisco ,  ROJAS HERNÁNDEZ, Rocío Estefanía ,  ENRÍQUEZ PÉREZ, Esther ,  RUBIO MARCOS, Fernando ,  GARCÍA JUEZ, Vicente ,  ANTÓN IBÁÑEZ, Lara

IPC: C09K11/02 ,  C09K11/77 ,  C09D5/22

CPC classification number: C09K11/7792 ,  B42D25/29 ,  B42D25/378 ,  C09D5/22 ,  C09K11/02

Abstract: The present invention relates to a nanostructured phosphorescent pigment comprising an Al 2 O 3 substrate; MAl 2 O 4 :X nanocrystals, where M is a cation selected from Ca 2+ , Sr 2+ , Ba 2+ , Mg 2+ , Zn 2+ and combinations thereof and where X is a cation selected from Eu 2+ , Dy 3+ , Nd 3+ , Er 3+ , La 3+ , Lu 3+ , Ce 3+ , Y 3+ , Sm 3+ , Gd 3+ , Tb 3+ , Tm 3+ , Yb 3+ and combinations thereof, disposed on the Al 2 O 3 substrate; and nanocrystals of molten salt disposed on the MAl 2 O 4 :X nanocrystals. Additionally, the invention relates to a method for preparing the nanostructured phosphorescent pigment of the invention comprising the steps of i) mixing starting materials comprising a cation M precursor, a cation X precursor, Al 2 O 3 and a molten salt; ii) heating the mixture resulting from step (i) in reducing atmosphere. The invention also relates to the use of the nanostructured phosphorescent pigment of the invention for signaling, illumination, decoration or authentication and to a security article comprising the nanostructured phosphorescent pigment of the invention.

Abstract translation: 本发明涉及包含Al2O3底物的纳米结构磷光颜料; MAl 2 O 4：X纳米晶体，其中M是选自Ca2 +，Sr2 +，Ba2 +，Mg2 +，Zn2 +的阳离子及其组合，其中X是选自Eu2 +，Dy3 +，Nd3 +，Er3 +，La3 +，Lu3 +，Ce3 +，Y3 +，Sm3 + Gd3 +，Tb3 +，Tm3 +，Yb3 +及其组合; 和设置在MAl2O4：X纳米晶体上的熔融盐的纳米晶体。 另外，本发明涉及一种制备本发明的纳米结构磷光颜料的方法，包括以下步骤：i）将包含阳离子M前体，阳离子X前体，Al 2 O 3和熔融盐的原料混合; ii）在还原气氛中加热由步骤（i）产生的混合物。 本发明还涉及本发明的纳米结构磷光颜料用于信号，照明，装饰或认证以及包含本发明的纳米结构磷光颜料的安全制品的用途。

公开(公告)号：WO2012172018A1

公开(公告)日：2012-12-20

申请号：PCT/EP2012/061353

申请日：2012-06-14

Applicant: FÁBRICA NACIONAL DE MONEDA Y TIMBRE - REAL CASA DE LA MONEDA ,  NANOGAP SUB-NM-POWDER, SOCIEDAD ANONIMA ,  LOPEZ QUINTELA, Manuel, Arturo ,  GARCÍA JUEZ, Vicente

Inventor： LOPEZ QUINTELA, Manuel, Arturo ,  GARCÍA JUEZ, Vicente

IPC: G01N33/58 ,  B41M3/14 ,  B42D15/00 ,  C09D5/22 ,  D21H21/48 ,  G06K19/14 ,  G07D7/12 ,  B82Y15/00

CPC classification number: B42D25/373 ,  B41M3/144 ,  B42D25/21 ,  B42D25/23 ,  B42D25/29 ,  B42D25/328 ,  B42D25/333 ,  B42D25/355 ,  B42D25/378 ,  B42D25/382 ,  B42D25/387 ,  B42D2033/10 ,  B42D2033/32 ,  B42D2035/34 ,  B82Y15/00 ,  C09D5/22 ,  C09K11/02 ,  C09K11/025 ,  C09K11/58 ,  D21H19/02 ,  D21H21/48 ,  D21H21/52 ,  D21H21/54 ,  G01N21/64 ,  G06K19/14 ,  G07D7/12 ,  G07D7/1205 ,  G21K5/00

Abstract: The present invention relates to the use of nanosystems as non deactivable security markers comprising metal atomic quantum clusters (AQCs) of at least two different size distributions encapsulated in a cavity with an inner diameter less than or equal to approximately 10 nm. These nanosystems are luminescence, particularly fluorescence after external excitation. The invention also relates to security documents, articles or elements incorporating these markers as well as to a method and a system for detecting the same.

Abstract translation: 本发明涉及纳米系统作为非可去除安全标记的用途，其包括封装在具有小于或等于约10nm的内径的空腔中的至少两个不同尺寸分布的金属原子量子簇（AQC）。 这些纳米系统是发光的，特别是外部激发后的荧光。 本发明还涉及包含这些标记的安全性文件，物品或元件以及用于检测它们的方法和系统。

公开(公告)号：WO2020152160A1

公开(公告)日：2020-07-30

申请号：PCT/EP2020/051404

申请日：2020-01-21

Applicant: FÁBRICA NACIONAL DE MONEDA Y TIMBRE - REAL CASA DE LA MONEDA ,  CONSEJO SUPERIOR DE INVESTIGACIONES CIENTÍFICAS

Inventor： MOURE ARROYO, Alberto ,  FERNÁNDEZ LOZANO, José Francisco ,  FUERTES DE LA LLAVE, Víctor ,  ENRÍQUEZ PÉREZ, Esther ,  GARCÍA JUEZ, Vicente

IPC: A61L15/42 ,  C04B28/00 ,  C04B41/00 ,  G01N21/65 ,  G07D7/1205 ,  B82Y30/00

Abstract: The present invention relates to a security marker; a method of preparing same; the use of said security marker; a security article, document, or element comprising said marker; the use of said security article, document, or element; an object of value comprising said marker; a method of preparing said security article, document, or element or said object of value; a method for determining the authenticity of said security article, document, or element or said object of value; and a system for determining the authenticity of said security article, document, or element or said object of value.

公开(公告)号：WO2014206977A1

公开(公告)日：2014-12-31

申请号：PCT/EP2014/063267

申请日：2014-06-24

Applicant: FÁBRICA NACIONAL DE MONEDA Y TIMBRE - REAL CASA DE LA MONEDA

Inventor： GARCÍA JUEZ, Vicente ,  GAMO ARANDA, Javier ,  BORRUEL NAVARRO, Luis

IPC: B42D25/00 ,  B42D25/346 ,  B42D25/435 ,  B42D25/44 ,  B42D25/445

CPC classification number: B42D25/351 ,  B41M3/14 ,  B41M5/24 ,  B42D25/00 ,  B42D25/346 ,  B42D25/36 ,  B42D25/373 ,  B42D25/378 ,  B42D25/435 ,  B42D25/44 ,  B42D25/445 ,  B42D25/45 ,  B42D2033/22 ,  G07D7/003

Abstract: Method of providing a security document with a security feature, comprising the step of providing a conductive layer (22), and the step of removing part of said conductive layer (22) so as to convert at least a portion of said conductive layer into a metamaterial (31, 32) selected to provide for authentication of the security document. The invention also relates to a security document obtained with this method, and to a method of authenticating such a security document.

Abstract translation: 提供具有安全特征的安全文件的方法，包括提供导电层（22）的步骤，以及去除所述导电层（22）的一部分以便将所述导电层的至少一部分转化为 超材料（31,32）被选择以提供安全文件的认证。 本发明还涉及使用该方法获得的安全文档以及认证这种安全文档的方法。

公开(公告)号：WO2014180885A1

公开(公告)日：2014-11-13

申请号：PCT/EP2014/059309

申请日：2014-05-07

Applicant: FÁBRICA NACIONAL DE MONEDA Y TIMBRE - REAL CASA DE LA MONEDA

Inventor： OLMOS, Antonio ,  LAZZERINI, Maurizio ,  GARCÍA JUEZ, Vicente

IPC: D21H21/40 ,  B41M3/14 ,  B24D15/00 ,  D21H21/42 ,  D21H21/48 ,  B41M5/24

CPC classification number: D21H21/48 ,  B41M3/14 ,  B41M5/24 ,  B42D25/346 ,  B42D25/355 ,  B42D25/36 ,  B42D25/369 ,  B42D25/373 ,  B42D25/41 ,  B42D25/435 ,  D21H21/40 ,  D21H21/42

Abstract: A security document (1) comprises a paper document substrate (11) and a security element (2) embedded in said document substrate (11). The security element comprises an element substrate (21) and a material (22) sensitive to laser light. The method comprises the step of directing laser light (41 ) onto the document substrate (11) so as to alter said material (22), so as to provide said security element (2) with a detectable marking (3).

Abstract translation: 安全文件（1）包括纸文件基板（11）和嵌入所述文件基板（11）中的安全元件（2）。 安全元件包括元件基板（21）和对激光敏感的材料（22）。 该方法包括将激光（41）引导到文件基板（11）上以便改变所述材料（22）的步骤，以便为所述安全元件（2）提供可检测标记（3）。

公开(公告)号：WO2013072449A1

公开(公告)日：2013-05-23

申请号：PCT/EP2012/072809

申请日：2012-11-16

Applicant: FÁBRICA NACIONAL DE MONEDA Y TIMBRE - REAL CASA DE LA MONEDA

Inventor： ZAMORANO DE BLAS, Julián

IPC: A44C21/00 ,  B21C51/00 ,  B23P15/00

CPC classification number: B42D25/29 ,  A44C21/00 ,  B23K26/361 ,  B23K26/362 ,  B23K26/40 ,  B23K2203/04 ,  B23K2203/50 ,  B42D25/00 ,  B42D25/324 ,  B42D25/425 ,  G02B5/124 ,  Y10T83/02

Abstract: The present invention relates to an object comprising a region of its surface suitable for showing a plurality of images. Each of these images is observable from a different direction such that upon observing one of the images the other images stop being observable and do not interfere in the viewing of the observed image. The configuration which allows generating the region of surfaces suitable for showing the plurality of images allows for mass production by means of stamping or minting techniques and complicates the reproduction by unauthorized manufacturers. A method which allows obtaining the object having a region suitable for showing a plurality of images is also an object of the present invention.

Abstract translation: 本发明涉及一种包括其表面的适于显示多个图像的区域的物体。 这些图像中的每一个可以从不同的方向观察，使得在观察其中一个图像时，其它图像停止可观察，并且不干扰观察到的图像的观看。 允许产生适于显示多个图像的表面区域的配置允许通过冲压或铸造技术进行批量生产，并使未经授权的制造商的再现变得复杂。 允许获得具有适于显示多个图像的区域的对象的方法也是本发明的目的。