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公开(公告)号:WO2010091047A1
公开(公告)日:2010-08-12
申请号:PCT/US2010/022991
申请日:2010-02-03
CPC分类号: C07F15/025 , C07F5/062 , C07F15/065
摘要: The present invention generally relates to a new process of making a trialkyl aluminum compound in which at least one alkyl group is a primary alkyl derived from an internal olefin or alpha-olefin. The process employs an isomerization/hydroalumination catalyst.
摘要翻译: 本发明一般涉及制备三烷基铝化合物的新方法,其中至少一个烷基是衍生自内烯烃或α-烯烃的伯烷基。 该方法采用异构化/水化铝催化剂。
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公开(公告)号:WO2007130305A3
公开(公告)日:2008-01-17
申请号:PCT/US2007010200
申请日:2007-04-26
申请人: DOW GLOBAL TECHNOLOGIES INC , BOONE HAROLD W , COALTER JOSEPH N III , FRAZIER KEVIN A , IVERSON CARL N , MUNRO IAN M , PEIL KEVIN P , VOSEJPKA PAUL C
发明人: BOONE HAROLD W , COALTER JOSEPH N III , FRAZIER KEVIN A , IVERSON CARL N , MUNRO IAN M , PEIL KEVIN P , VOSEJPKA PAUL C
IPC分类号: C07F7/00 , C08F4/659 , C08F10/00 , C08F210/00
CPC分类号: C07F7/00 , C07F7/006 , C08F10/00 , C08F110/06 , C08F4/64044
摘要: Hafnium complexes of carbazolyl substituted imidazol ligands and their use as components of olefin polymerization catalyst compositions are disclosed.
摘要翻译: 公开了咔唑基取代的咪唑配体的铪络合物及其作为烯烃聚合催化剂组合物的组分的用途。
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公开(公告)号:WO2007130307A2
公开(公告)日:2007-11-15
申请号:PCT/US2007/010225
申请日:2007-04-26
申请人: DOW GLOBAL TECHNOLOGIES INC. , BOONE, Harold, W. , COALTER, Joseph, N., III , FRAZIER, Kevin, A. , IVERSON, Carl, N. , MUNRO, Ian, M. , VOSEJPKA, Paul, C.
发明人: BOONE, Harold, W. , COALTER, Joseph, N., III , FRAZIER, Kevin, A. , IVERSON, Carl, N. , MUNRO, Ian, M. , VOSEJPKA, Paul, C.
IPC分类号: C07F7/00 , C08F10/00 , C08F210/00
CPC分类号: C07F7/00 , C07F7/006 , C08F10/00 , C08F110/14 , C08F4/64144 , C08F2500/20 , C08F2500/03
摘要: Hafnium complexes of heterocyclic organic ligands containing internal orthometallation and their use as components of olefin polymerization catalysts, especially for gas-phase olefin polymerizations, are disclosed.
摘要翻译: 公开了含有内部正金属化的杂环有机配体的铪络合物及其作为烯烃聚合催化剂的组分,特别是用于气相烯烃聚合的组分。
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公开(公告)号:WO2007130242A2
公开(公告)日:2007-11-15
申请号:PCT/US2007/007882
申请日:2007-03-29
申请人: DOW GLOBAL TECHNOLOGIES INC. , VOSEJPKA, Paul, C. , BOONE, Harold, W. , FRAZIER, Kevin, A. , IVERSON, Carl, N.
CPC分类号: C07D307/82 , C07D233/64 , C07D405/04 , C07F7/00 , C08F10/00 , C08F110/06 , C08F4/64044 , C08F2500/15 , C08F2500/03
摘要: Hafnium complexes of heterocyclic organic ligands having improved solubility in aliphatic hydrocarbon solvents and their use as components of olefin polymerization catalysts as well as novel syntheses of component parts thereof are disclosed.
摘要翻译: 公开了在脂族烃溶剂中具有改善的溶解度的杂环有机配体的铪络合物及其作为烯烃聚合催化剂的组分的用途以及其组分部分的新型合成。
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5.
公开(公告)号:WO2007037944A3
公开(公告)日:2007-05-31
申请号:PCT/US2006035082
申请日:2006-09-08
申请人: DOW GLOBAL TECHNOLOGIES INC , BOONE HAROLD W , FRAZIER KEVIN A , VANDERLENDE DANIEL D , VOSEJPKA PAUL C
IPC分类号: C07F7/00 , C08F10/06 , C08F210/06
CPC分类号: C08F210/14 , C07F7/00 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/06 , C08F210/06 , C08F210/16 , C08F210/18 , Y10S526/905 , C08F4/659 , C08F2500/04 , C08F2500/03 , C08F2500/17 , C08F2500/08 , C08F2500/20 , C08F4/6411
摘要: Group 4 metal complexes comprising a polyvalent, heteroaryl donor ligand and their use as components of olefin polymerization catalysts, especially suited for preparing propylene/ethylene copolymer products having high isotacticity and low molecular weight, are disclosed.
摘要翻译: 公开了包含多价杂芳基供体配体的4族金属络合物及其作为烯烃聚合催化剂组分的用途,特别适用于制备具有高等规度和低分子量的丙烯/乙烯共聚物产物。
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公开(公告)号:WO2004099268A1
公开(公告)日:2004-11-18
申请号:PCT/US2004/008834
申请日:2004-03-23
申请人: DOW GLOBAL TECHNOLOGIES INC , FRAZIER, Kevin, A. , VOSEJPKA, Paul, A. , BOONE, Harold, W. , STEVENS, James, C.
IPC分类号: C08F10/06
CPC分类号: C08F10/02 , C07F7/00 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F10/06 , C08F110/06 , C08F210/06 , C08F4/6411 , C08F2/06 , C08F4/659 , C08F2500/03 , C08F210/16 , C08F2500/08 , C08F2500/12
摘要: Group 4 metal complexes useful as addition polymerization catalysts of the formula: (I) wherein G 1 is a group containing from 1 to 40 atoms not counting hydrogen; T is a divalent bridging group of from 10 to 30 atoms not counting hydrogen, selected from mono- or di- aryl- substituted methylene or silylene groups or mono- or di- heteroaryl-substituted methylene or silylene groups, wherein at least one such aryl- or heteroaryl-substituent is substituted in one or both ortho- positions with a secondary or tertiary alkyl-group, a secondary or tertiary heteroalkyl group, a cycloalkyl group, or a heterocycloalkyl group, G 2 is a C 6-20 heteroaryl group containing Lewis base functionality, M is the Group 4 metal, X’’’’ is an anionic, neutral or dianionic ligand group, x’’’’ is a number from 0 to 5, and bonds, optional bonds and electron donative interactions are represented by lines, dotted lines and arrows respectively.
摘要翻译: 可用作下式的加成聚合催化剂的第4族金属络合物:(I)其中G 1是含有1至40个不计氢的原子的基团; T是不计算氢的10至30个原子的二价桥连基团,选自单或二芳基取代的亚甲基或亚甲硅烷基或单 - 或二 - 杂芳基取代的亚甲基或亚甲硅基,其中至少一个这样的芳基 - 或杂芳基 - 取代基在一个或两个邻位与二级或三级烷基,仲或叔杂烷基,环烷基或杂环烷基取代,G 2是C 6-20杂芳基 含有路易斯碱官能团,M是第4族金属,X“是阴离子,中性或双阴离子配体基团,x”是0至5的数,并且键,任选键和给电子相互作用是 由线,虚线和箭头分别表示。
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7.
公开(公告)号:WO2012027448A1
公开(公告)日:2012-03-01
申请号:PCT/US2011/048927
申请日:2011-08-24
申请人: DOW GLOBAL TECHNOLOGIES LLC , KLOSIN, Jerzy , THOMAS, Pulikkottil J. , IVERSON, Carl N. , ABOELELLA, Nermeen W. , FRAZIER, Kevin A.
发明人: KLOSIN, Jerzy , THOMAS, Pulikkottil J. , IVERSON, Carl N. , ABOELELLA, Nermeen W. , FRAZIER, Kevin A.
IPC分类号: C08F4/64 , C08F210/16 , C07F7/00 , C07D209/86
CPC分类号: C08F4/65912 , C07D209/82 , C07F7/00 , C08F4/659 , C08F210/16 , C08F210/18 , C08F210/14 , C08F2500/03 , C08F210/08 , C08F210/06 , C08F236/06 , C08F4/64189 , C08F4/64193
摘要: The present invention generally relates to a process that copolymerizes two or more polymerizable olefins, and to cataclyst comprising a metal -ligand complex (precatalyst). The present invention also generally relates to ligands useful for preparing the metal -ligand complex.
摘要翻译: 本发明一般涉及使两种或更多种可聚合烯烃共聚的方法,以及包含金属配位体复合物(预催化剂)的崩解剂。 本发明还通常涉及可用于制备金属配体复合物的配体。
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公开(公告)号:WO2010077483A1
公开(公告)日:2010-07-08
申请号:PCT/US2009/065435
申请日:2009-11-23
IPC分类号: C07D301/12 , C07D303/04
CPC分类号: C07D301/12 , C07D303/04 , C08G59/027 , C08G59/22
摘要: A process for preparing a divinylarene dioxide comprising reacting a divinylarene, such as divinylbenzene, with hydrogen peroxide in the presence of a solvent and in the presence of a catalyst to from a divinylarene dioxide; wherein the hydrogen peroxide is present in the reaction mixture in an excess or an equivalent mole ratio per mole of divinylarene.
摘要翻译: 一种制备二乙烯基芳烃二氧化物的方法,包括使二乙烯基芳烃如二乙烯基苯与过氧化氢在溶剂存在下和在催化剂存在下与二乙烯基芳烃二氧化物反应; 其中过氧化氢以每摩尔二乙烯基芳烃过量或当量摩尔比存在于反应混合物中。
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公开(公告)号:WO2007130242A3
公开(公告)日:2008-01-31
申请号:PCT/US2007007882
申请日:2007-03-29
申请人: DOW GLOBAL TECHNOLOGIES INC , VOSEJPKA PAUL C , BOONE HAROLD W , FRAZIER KEVIN A , IVERSON CARL N
IPC分类号: C08F4/645 , C07D233/54
CPC分类号: C07D307/82 , C07D233/64 , C07D405/04 , C07F7/00 , C08F10/00 , C08F110/06 , C08F4/64044 , C08F2500/15 , C08F2500/03
摘要: Hafnium complexes of heterocyclic organic ligands having improved solubility in aliphatic hydrocarbon solvents and their use as components of olefin polymerization catalysts as well as novel syntheses of component parts thereof are disclosed.
摘要翻译: 公开了在脂族烃溶剂中具有改善的溶解度的杂环有机配体的铪络合物及其作为烯烃聚合催化剂的组分的用途以及其组分部分的新型合成。
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公开(公告)号:WO2011081650A1
公开(公告)日:2011-07-07
申请号:PCT/US2010/003160
申请日:2010-12-14
申请人: DOW GLOBAL TECHNOLOGIES LLC , CLARK, Thomas, P. , FRAZIER, Kevin, A. , TIMMERS, Francis, J. , KOLTHAMMER, Brian, W.
CPC分类号: C07C11/02 , C07C5/2587 , C07C6/04 , C07C2531/22
摘要: Methods for producing alpha-olefins. The methods include selectively isomerizing an alpha-olefin to a mixture of beta-olefins and ethenolyzing at least a portion of the mixture of beta-olefins to an alpha-olefin.
摘要翻译: α-烯烃的制备方法。 所述方法包括将α-烯烃选择性异构化为β-烯烃的混合物,并将至少一部分β-烯烃的混合物乙烯化至α-烯烃。
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