公开(公告)号：WO2007057900A3

公开(公告)日：2009-04-09

申请号：PCT/IL2006001327

申请日：2006-11-16

Applicant: BROMINE COMPOUNDS LTD ,  OREN JAKOB ,  YASSIN NASIF ,  ZILBERMAN JOSEPH ,  CANFI DORIT ,  FRIM RON ,  BERUBEN DOV

Inventor： OREN JAKOB ,  YASSIN NASIF ,  ZILBERMAN JOSEPH ,  CANFI DORIT ,  FRIM RON ,  BERUBEN DOV

IPC: C08K5/03 ,  C08L25/06

CPC classification number: C08K5/06 ,  C07C17/12 ,  C07C17/14 ,  C07C25/18 ,  C07C43/225 ,  C07C43/29 ,  C08K5/03 ,  C07C22/04

Abstract: Polybrominated bisaryl compounds containing bromomethyl or bromomethylene groups are provided, as well as flameproof polymeric formulations comprising the compounds. The novel compounds exhibit a good thermal stability, and are particularly suitable for flame-retarding polystyrene thermoplastic foams. A process for making the polybrominated bisaryl compounds is also provided.

Abstract translation: 提供了包含溴甲基或溴亚甲基的多溴二芳基化合物，以及包含该化合物的防火聚合物。 新型化合物表现出良好的热稳定性，特别适用于阻燃聚苯乙烯热塑性泡沫塑料。 还提供了制备多溴二芳基化合物的方法。

公开(公告)号：WO2007132463A1

公开(公告)日：2007-11-22

申请号：PCT/IL2007/000589

申请日：2007-05-14

Applicant: BROMINE COMPOUNDS LTD. ,  GELMONT, Mark ,  PELED, Michael ,  ALON, Dina ,  FRIM, Ron ,  BAR-YAAKOV, Yoav

Inventor： GELMONT, Mark ,  PELED, Michael ,  ALON, Dina ,  FRIM, Ron ,  BAR-YAAKOV, Yoav

IPC: C09K21/08 ,  C09K21/12 ,  C08K5/00 ,  C08L75/04

CPC classification number: C09K21/08 ,  C08G18/4045 ,  C08G18/4816 ,  C08G18/4829 ,  C08G18/582 ,  C08G18/6611 ,  C08G2101/0025 ,  C08G2105/02 ,  C08K5/053 ,  C08K5/06 ,  C08K5/521 ,  C08K2003/329 ,  C08L2201/02 ,  C09K21/12 ,  C08L75/04

Abstract: A liquid flame retardant composition which comprises one or more flame retarding agents, which are the epoxides obtainable by reacting tetrabromobisphenol A with epichlorohydrin and their end-capped derivatives represented by Formula (1) is provided. The liquid composition is especially useful in the preparation of rigid polyurethane foams.

Abstract translation: 提供一种液体阻燃剂组合物，其包含一种或多种阻燃剂，其是通过使四溴双酚A与表氯醇反应获得的环氧化物及其由式（1）表示的封端衍生物。 液体组合物特别适用于硬质聚氨酯泡沫的制备。

公开(公告)号：WO2010150266A3

公开(公告)日：2010-12-29

申请号：PCT/IL2010/000514

申请日：2010-06-27

Applicant: IMI TAMI Institute for Research and Development Ltd. ,  BONAN, Michael ,  GINZBERG, Eyal ,  MOZES, Akiva ,  BARNEA, Eyal ,  KESELMAN, Hugo ,  FRIEDMAN, Gideon ,  FRIM, Ron ,  LANGEVELD, Cornelis Petrus

Inventor： BONAN, Michael ,  GINZBERG, Eyal ,  MOZES, Akiva ,  BARNEA, Eyal ,  KESELMAN, Hugo ,  FRIEDMAN, Gideon ,  FRIM, Ron ,  LANGEVELD, Cornelis Petrus

IPC: C05C5/02 ,  C22B26/00

Abstract: A process for producing KNO3 from polyhalite is disclosed. In a preferred embodiment, the process comprises steps of (a) contacting polyhalite with HNO3; (b) adding Ca(OH)2 to the solution, thereby precipitating as CaSO4 at least part of the sulfate present in said solution; (c) precipitating as Mg(OH)2 at least part of the Mg2+ remaining in said solution by further addition of Ca(OH)2 to the remaining solution; (d) concentrating the solution, thereby precipitating as a sulfate compound at least part of the sulfate remaining in solution; (e) separating at least part of the NaCl from the solution remaining; and (f) crystallizing as solid KNO3 at least part of the K+ and NO3- contained in the solution. The process enables direct conversion of polyhalite to KNO3 of purity exceeding 98.5% and that is essentially free of magnesium and sulfate impurities.

公开(公告)号：WO2008146277A1

公开(公告)日：2008-12-04

申请号：PCT/IL2008/000712

申请日：2008-05-26

Applicant: BROMINE COMPOUNDS LTD. ,  OREN, Jakob ,  YASSIN, Nasif ,  FRIM, Ron

Inventor： OREN, Jakob ,  YASSIN, Nasif ,  FRIM, Ron

IPC: C07C201/12 ,  C07C205/08

CPC classification number: C07C201/12 ,  C07C205/08

Abstract: A continuous process of preparing bromopicrin is disclosed. The process is effected by transferring a continuous flow of a first mixture and a continuous flow of a second mixture into a first reactor, the first mixture containing nitromethane and bromine and the second mixture containing an aqueous solution of an alkaline substance, to thereby obtain a reaction mixture which comprises bromopicrin in said first reactor; and collecting the bromopicrin from the reaction mixture. Highly pure bromopicrin obtained by this process is also disclosed.

Abstract translation: 公开了制备溴氰菊酯的连续方法。 该方法通过将第一混合物的连续流和第二混合物的连续流转移到第一反应器中，第一混合物含有硝基甲烷和溴，第二混合物含有碱性物质的水溶液，从而获得 在所述第一反应器中包含溴化苦素的反应混合物; 并从反应混合物中收集溴氰菊酯。 还公开了通过该方法获得的高纯度溴氰菊酯。

公开(公告)号：WO2010150267A1

公开(公告)日：2010-12-29

申请号：PCT/IL2010/000515

申请日：2010-06-27

Applicant: IMI TAMI Institute for Research and Development Ltd. ,  BONAN, Michael ,  GINZBERG, Eyal ,  MOZES, Akiva ,  BARNEA, Eyal ,  KESELMAN, Hugo ,  FRIEDMAN, Gideon ,  FRIM, Ron ,  LANGEVELD, Cornelis Petrus

Inventor： BONAN, Michael ,  GINZBERG, Eyal ,  MOZES, Akiva ,  BARNEA, Eyal ,  KESELMAN, Hugo ,  FRIEDMAN, Gideon ,  FRIM, Ron ,  LANGEVELD, Cornelis Petrus

IPC: C05C5/02 ,  C22B26/00

CPC classification number: C22B3/065 ,  C05C5/02 ,  C22B3/20 ,  C22B26/10 ,  Y02P10/234

Abstract: A method for the production of KNO 3 from polyhalite is provided. The method comprises steps of decomposing said polyhalite into syngenite, gypsum, and soluble components, treating the solid decomposition products sequentially with HNO 3 and Ca basic compound, precipitating the CaSO 4 thus formed, and crystallizing the KNO 3 from the solution remaining. The method recovers up to 75% of the potassium present in the raw polyhalite as KNO 3 and substantially all of the remainder as a potassium magnesium sulfate salt.

Abstract translation: 提供了一种从多卤化物生产KNO3的方法。 该方法包括将所述多卤化物分解成顺铂，石膏和可溶组分的步骤，依次用HNO 3和Ca碱性化合物处理固体分解产物，沉淀出由此形成的CaSO 4，并从剩余的溶液中结晶出KNO 3。 该方法回收高达75％的原始多卤代黄酮中的钾作为KNO 3，并且基本上剩余的所有钾作为硫酸镁钾盐回收。

公开(公告)号：WO2009098692A1

公开(公告)日：2009-08-13

申请号：PCT/IL2009/000139

申请日：2009-02-05

Applicant: IMI TAMI INSTITUTE FOR RESEARCH AND DEVELOPMENT LTD. ,  WEISSMAN, Aharon ,  GORELIK, Yelena ,  VULTZ, Eyal Yehihel ,  PERLE, Dorit ,  MASRI, Basam ,  SHIKOLSKY, Gideon ,  HANUKA, Ezrah ,  FRIM, Ron

Inventor： WEISSMAN, Aharon ,  GORELIK, Yelena ,  VULTZ, Eyal Yehihel ,  PERLE, Dorit ,  MASRI, Basam ,  SHIKOLSKY, Gideon ,  HANUKA, Ezrah ,  FRIM, Ron

IPC: C04B28/34

CPC classification number: C04B28/34 ,  C04B22/126 ,  C04B2103/14 ,  C04B2103/24 ,  Y02W30/92 ,  C04B14/043 ,  C04B14/06 ,  C04B14/304 ,  C04B18/08

Abstract: A method is provided for advantageously altering the rate of hardening of a magnesium silico-phosphate cement (MSPC). Addition of on the order of 1% of an [MF 6 ] n- salt or acid to an MSPC, obtained by adding the salt or acid either directly to the dry mix or to the water used to effect hydraulic hardening of the cement, significantly alters the hardening rate without adversely affecting the physical properties of the final set cement. In preferred embodiments, Na 2 TiF 6 and/or K 2 TiF 6 are used as retardants, while K 3 AlF 6 is used as an accelerant. Other embodiments use M' n MF 6 compounds wherein M' is an alkali metal, an alkaline earth metal, or H, and M is chosen from inter alia Ti (n = 2), Zr (n = 2), Si (n = 2), P (n = 1), Al (n = 3), and Sb (n = 1).

Abstract translation: 提供了一种有利地改变硅酸钙水泥（MSPC）的硬化速率的方法。 通过将盐或酸直接添加到干混合物或用于水泥硬化的水中而将[MF6] n-盐或酸的1％量级添加到MSPC中，显着改变 硬化速率不会对最终固定水泥的物理性能产生不利影响。 在优选的实施方案中，使用Na 2 TiF 6和/或K 2 TiF 6作为阻聚剂，而K 3 AlF 6用作促进剂。 其他实施方案使用M'nMF6化合物，其中M'为碱金属，碱土金属或H，M特别选自Ti（n = 2），Zr（n = 2），Si（n = 2） ，P（n = 1），Al（n = 3）和Sb（n = 1）。

公开(公告)号：WO2007086048A3

公开(公告)日：2009-02-12

申请号：PCT/IL2007000018

申请日：2007-01-08

Applicant: BROMINE COMPOUNDS LTD ,  ASSARAF MENACHEM ,  FRIM RON

Inventor： ASSARAF MENACHEM ,  FRIM RON

IPC: A01N59/26 ,  A01N47/28

CPC classification number: A01N59/26 ,  A01N37/44 ,  A01N37/46 ,  A01N59/06 ,  A01N59/16 ,  A01N59/20 ,  A01N2300/00

Abstract: Novel pesticide compositions and formulations, containing a phosphorous-containing compound and a nitrogen-releasing compound, are disclosed. These novel compositions exhibit a synergistic pesticidal activity and are particularly useful in treating pests such as nematodes (including root-not nematodes), fungi and bacteria. Methods utilizing these compositions for controlling pests, articles-of-manufacture containing same and processes of preparing same are further disclosed.

Abstract translation: 公开了含有含磷化合物和释放氮的化合物的新型农药组合物和制剂。 这些新型组合物表现出协同的杀虫活性，特别可用于处理害虫如线虫（包括根 - 线虫），真菌和细菌。 进一步公开了利用这些组合物来控制害虫的方法，含有该物质的制品及其制备方法。

公开(公告)号：WO2007057900A2

公开(公告)日：2007-05-24

申请号：PCT/IL2006/001327

申请日：2006-11-16

Applicant: BROMINE COMPOUNDS LTD. ,  OREN, Jakob ,  YASSIN, Nasif ,  ZILBERMAN, Joseph ,  CANFI, Dorit ,  FRIM, Ron ,  BERUBEN, Dov

Inventor： OREN, Jakob ,  YASSIN, Nasif ,  ZILBERMAN, Joseph ,  CANFI, Dorit ,  FRIM, Ron ,  BERUBEN, Dov

IPC: C08K5/03

CPC classification number: C08K5/06 ,  C07C17/12 ,  C07C17/14 ,  C07C25/18 ,  C07C43/225 ,  C07C43/29 ,  C08K5/03 ,  C07C22/04

Abstract: Polybrominated bisaryl compounds containing bromomethyl or bromomethylene groups are provided, as well as flameproof polymeric formulations comprising the compounds. The novel compounds exhibit a good thermal stability, and are particularly suitable for flame-retarding polystyrene thermoplastic foams. A process for making the polybrominated bisaryl compounds is also provided.

Abstract translation: 提供了包含溴甲基或溴亚甲基的多溴二芳基化合物，以及包含该化合物的防火聚合物。 新型化合物表现出良好的热稳定性，特别适用于阻燃聚苯乙烯热塑性泡沫塑料。 还提供了制备多溴二芳基化合物的方法。

公开(公告)号：WO2004071192A3

公开(公告)日：2004-08-26

申请号：PCT/IL2004/000140

申请日：2004-02-12

Applicant: BROMINE COMPOUNDS LTD. ,  FRIM, Ron

Inventor： FRIM, Ron

IPC: A01N25/00

Abstract: The stabilization of 3BP throughout its life-cycle is achieved via the use of azeotropic mixtures for dilution and prevention of shock or temperature sensitivity.

公开(公告)号：WO2012153323A1

公开(公告)日：2012-11-15

申请号：PCT/IL2011/000912

申请日：2011-11-30

Applicant: IMI TAMI INSTITUTE FOR RESEARCH AND DEVELOPMENT LTD. ,  VULTZ, Eyal, Yehiel ,  WEISSMAN, Aharon ,  MASSRI, Bassam ,  GINZBERG, Eyal ,  FRIM, Ron

Inventor： VULTZ, Eyal, Yehiel ,  WEISSMAN, Aharon ,  MASSRI, Bassam ,  GINZBERG, Eyal ,  FRIM, Ron

IPC: C04B12/02

CPC classification number: C04B28/34 ,  C04B14/304 ,  C04B20/1055 ,  C04B20/107 ,  C04B22/126 ,  C04B2103/20 ,  C04B14/043 ,  C04B14/06 ,  C04B14/068

Abstract: A mixture suitable for use in forming a magnesium silico-phosphate cement is disclosed. The mixture comprises particles of MgO at least partially coated with an additive adapted to alter the setting time of said cement cast; a phosphate salt or acid chosen that will provide a binder product characterized by the empirical chemical formula MMgPO 4 ⋅6H 2 O; and an aggregate phase chosen from the group containing (a) CaSiO 3 , (b) MgSiO 3 , (c) SiO 2 , (d) fly ash, (e) sea sand, and (f) any combination thereof. Coating the MgO particles provides better control of the alteration of the setting time and better physical properties of the set cement. Methods for making the mixture and for preparing a cement cast based on the mixture are also disclosed.

Abstract translation: 公开了一种适合用于形成硅磷酸钙水泥的混合物。 混合物包括至少部分地涂覆有适于改变所述水泥铸件的凝固时间的添加剂的MgO颗粒; 选择的磷酸盐或酸，其将提供以经验化学式MMgPO4·6H2O为特征的粘合剂产品; 和（a）CaSiO 3，（b）MgSiO 3，（c）SiO 2，（d）飞灰，（e）海砂和（f）它们的任何组合的组中选择的聚集相。 涂覆MgO颗粒可以更好地控制凝固时间的改变和凝固水泥的更好的物理性能。 还公开了制备混合物和基于混合物制备水泥铸件的方法。