公开(公告)号：WO2006014834B1

公开(公告)日：2006-03-30

申请号：PCT/US2005026172

申请日：2005-07-21

Applicant: UNIV CALIFORNIA ,  BP CHEM INT LTD ,  ZERELLA MARK ,  MUKHOPADHYAY SUDIP ,  BELL ALEXIS T ,  SUNLEY JOHN GLENN ,  GAEMERS SANDER ,  HOWARD PHILIP ,  ELLIS BRIAN ,  LUCY ANDREW RICHARD

Inventor： ZERELLA MARK ,  MUKHOPADHYAY SUDIP ,  BELL ALEXIS T ,  SUNLEY JOHN GLENN ,  GAEMERS SANDER ,  HOWARD PHILIP ,  ELLIS BRIAN ,  LUCY ANDREW RICHARD

IPC: C07C51/14

CPC classification number: C07C51/305 ,  C07C53/08

Abstract: Acetic acid is produced by oxidation of methane with an oxygen-containing gas in the presence of an acid selected from an acid selected from concentrated sulfuric acid and fuming sulfuric acid, a palladium-containing catalyst and a promoter, preferably a copper or iron salt. The addition of a promoter and O 2 to a system that includes a palladium-containing catalyst such as PdCl 2 increases the rate of acetic acid formation from methane by more than an order of magnitude as compared with prior art and, in addition, inhibits the precipitation of Pd black.

Abstract translation: 在选自浓硫酸和发烟硫酸的酸，含钯催化剂和促进剂，优选铜或铁盐的酸存在下，用含氧气体氧化甲酸来生产乙酸。 将促进剂和O 2加入到包含含钯催化剂如PdCl 2 N的体系中增加了甲烷形成乙酸的速率超过一个量级 与现有技术相比，并且还抑制了Pd黑的沉淀。

公开(公告)号：WO2010055285A8

公开(公告)日：2010-07-08

申请号：PCT/GB2009002639

申请日：2009-11-10

Applicant: BP PLC ,  DITZEL EVERT JAN ,  GAEMERS SANDER ,  SUNLEY JOHN GLENN

Inventor： DITZEL EVERT JAN ,  GAEMERS SANDER ,  SUNLEY JOHN GLENN

IPC: C07C29/149 ,  C07C31/04 ,  C07C31/08 ,  C07C51/12 ,  C07C53/08

CPC classification number: C07C29/151 ,  C07C29/149 ,  C07C51/12 ,  Y02P20/582 ,  C07C31/08 ,  C07C31/04 ,  C07C53/08

Abstract: The present invention relates to a process for producing methanol and ethanol, wherein the methanol is produced from synthesis gas and the ethanol is produced via the hydrogenation of an ethanoic acid feed; characterised in that the hydrogenation of the ethanoic acid feed is carried out within the same alcohol synthesis unit and in the presence of the same catalyst(s) that is used to produce the methanol from the synthesis gas and wherein the feed introduced to the alcohol synthesis unit comprises synthesis gas and ethanoic acid.

Abstract translation: 本发明涉及一种生产甲醇和乙醇的方法，其中甲醇由合成气生产，乙醇通过乙酸进料的氢化生产; 其特征在于，所述乙酸进料的氢化在相同的醇合成单元内进行，并且在用于从合成气生产甲醇的相同催化剂的存在下进行，并且其中引入醇合成的进料 单元包括合成气和乙酸。

公开(公告)号：WO2006014834A1

公开(公告)日：2006-02-09

申请号：PCT/US2005/026172

申请日：2005-07-21

Applicant: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA ,  BP CHEMICALS LIMITED ,  ZERELLA, Mark ,  MUKHOPADHYAY, Sudip ,  BELL, Alexis, T. ,  SUNLEY, John Glenn ,  GAEMERS, Sander ,  HOWARD, Philip ,  ELLIS, Brian ,  LUCY, Andrew Richard

Inventor： ZERELLA, Mark ,  MUKHOPADHYAY, Sudip ,  BELL, Alexis, T. ,  SUNLEY, John Glenn ,  GAEMERS, Sander ,  HOWARD, Philip ,  ELLIS, Brian ,  LUCY, Andrew Richard

IPC: C07C51/14

CPC classification number: C07C51/305 ,  C07C53/08

Abstract: Acetic acid is produced by oxidation of methane with an oxygen-containing gas in the presence of an acid selected from an acid selected from concentrated sulfuric acid and fuming sulfuric acid, a palladium-containing catalyst and a promoter, preferably a copper or iron salt. The addition of a promoter and O 2 to a system that includes a palladium-containing catalyst such as PdCl 2 increases the rate of acetic acid formation from methane by more than an order of magnitude as compared with prior art and, in addition, inhibits the precipitation of Pd black.

Abstract translation: 在选自浓硫酸和发烟硫酸的酸，含钯催化剂和助催化剂的酸存在下，通过用含氧气体氧化甲烷来生产乙酸 ，优选铜盐或铁盐。 向包括含钯催化剂例如PdCl 2的体系添加助催化剂和O 2 2使甲烷的乙酸形成速率增加多于一个数量级 与现有技术相比，并且此外还抑制Pd黑的沉淀。

公开(公告)号：WO2012151386A1

公开(公告)日：2012-11-08

申请号：PCT/US2012/036299

申请日：2012-05-03

Applicant: CALIFORNIA INSTITUTE OF TECHNOLOGY ,  BP CHEMICALS LIMITED ,  OBLAD, Paul ,  WINSTON, Matthew, S. ,  LABINGER, Jay, A. ,  BERCAW, John, E. ,  GAEMERS, Sander

Inventor： OBLAD, Paul ,  WINSTON, Matthew, S. ,  LABINGER, Jay, A. ,  BERCAW, John, E. ,  GAEMERS, Sander

IPC: B01J31/18 ,  B01J31/22

CPC classification number: B01J31/2226 ,  B01J31/1805 ,  B01J2231/12 ,  B01J2531/0216 ,  B01J2531/824

Abstract: A catalyst and/or precatalyst for olefin oligomerization comprising one or more coordination complexes having one or more central palladium metal atoms. Each palladium atom is bonded to four ligand donor atoms. Two of the donor atoms are group 16 elements and two of the donor atoms are group 15 elements. Also provided are neutral or cationic coordination complex dimers, so that the two palladium atoms are both bonded to one or two donor atoms from group 16, and each palladium atom is bonded to two donor atoms from group 15. In some instances, each of the two group 16 donor atoms are oxygen and each of the four group 15 donor atoms are nitrogen.

Abstract translation: 一种用于烯烃低聚的催化剂和/或预催化剂，其包含一种或多种具有一个或多个中心钯金属原子的配位络合物。 每个钯原子键合到四个配体供体原子。 两个供体原子是16族元素，两个供体原子是15族元素。 还提供了中性或阳离子配位络合物二聚体，使得两个钯原子都与第16族的一个或两个供体原子键合，并且每个钯原子与第15族键合到两个供体原子。在一些情况下， 两个16族供体原子是氧，四个15族供体原子中的每一个是氮。

公开(公告)号：WO2007071903A1

公开(公告)日：2007-06-28

申请号：PCT/GB2006/004359

申请日：2006-11-22

Applicant: BP EXPLORATION OPERATING COMPANY LIMITED ,  GAEMERS, Sander

Inventor： GAEMERS, Sander

IPC: C10G2/00 ,  B01J8/04 ,  B01J23/75

CPC classification number: C10G2/341 ,  B01J8/04 ,  B01J8/067 ,  B01J19/2485 ,  B01J23/24 ,  B01J23/462 ,  B01J23/74 ,  B01J23/75 ,  B01J23/80 ,  B01J2208/00663 ,  B01J2208/00884 ,  B01J2219/0004 ,  C10G2/332 ,  Y02P20/582

Abstract: A process for producing at least one condensed-phase product from one or more gas- phase reactants in the presence of a solid catalyst having one or more catalyst components, wherein the solid catalyst has two or more regions in which the contact time of the one or more gas-phase reactants with the one or more catalyst components is different.

Abstract translation: 一种在具有一种或多种催化剂组分的固体催化剂存在下从一种或多种气相反应物制备至少一种冷凝相产物的方法，其中固体催化剂具有两个或更多个区域，其中一个 或更多的气相反应物与一种或多种催化剂组分不同。

公开(公告)号：WO2004101487A1

公开(公告)日：2004-11-25

申请号：PCT/GB2004/001900

申请日：2004-05-05

Applicant: BP CHEMICALS LIMITED ,  GAEMERS, Sander ,  SUNLEY, John, Glenn

Inventor： GAEMERS, Sander ,  SUNLEY, John, Glenn

IPC: C07C51/12

CPC classification number: C07C67/36 ,  C07C51/12 ,  C07C53/08 ,  C07C69/14

Abstract: A process for the liquid phase carbonylation of an alcohol and/or a reactive derivative thereof in the presence of hydrogen in which there is employed a catalyst comprising rhodium of iridium coordinated with a polydentate ligand.

Abstract translation: 在氢气存在下使醇和/或其活性衍生物液相羰基化的方法，其中使用包含与多齿配位体配位的铱铑的催化剂。

公开(公告)号：WO2014207235A1

公开(公告)日：2014-12-31

申请号：PCT/EP2014/063760

申请日：2014-06-27

Applicant: CASTROL LIMITED ,  CARRERA, Martin E. ,  DAVIES, John Philip ,  GAEMERS, Sander ,  SHABAKER, John William ,  WILLIAMS, Oliver

Inventor： CARRERA, Martin E. ,  DAVIES, John Philip ,  GAEMERS, Sander ,  SHABAKER, John William ,  WILLIAMS, Oliver

IPC: C10M105/08 ,  C10M105/18 ,  C10M105/32

CPC classification number: C10M105/36 ,  C10M105/08 ,  C10M105/18 ,  C10M105/32 ,  C10M105/34 ,  C10M2203/02 ,  C10M2203/0206 ,  C10M2203/1006 ,  C10M2203/1025 ,  C10M2205/0285 ,  C10M2207/028 ,  C10M2207/04 ,  C10M2207/0406 ,  C10M2207/281 ,  C10M2207/2815 ,  C10M2207/2825 ,  C10M2219/046 ,  C10N2220/02 ,  C10N2230/02 ,  C10N2230/04 ,  C10N2230/36 ,  C10N2230/64 ,  C10N2230/74 ,  C10N2240/10 ,  C10N2260/02 ,  C10N2220/022

Abstract: A lubricating composition comprising a base oil of lubricating viscosity and one or more lubricant additives, wherein the base oil comprises or consists of a base stock which comprises or consists of at least one isoprenoid compound comprising: (i) one or two oxygen-containing moieties independently selected from ether and ester moieties; (ii) a first acyclic isoprenoid moiety containing 1 to 5 isoprenyl units; and (iii) optionally, a second acyclic isoprenoid moiety containing 1 to 5 isoprenyl units with the proviso that at least one isoprenoid moiety contains 3 to 5 isoprenyl units where the isoprenoid compound contains a single ether moiety.

Abstract translation: 一种润滑组合物，其包含润滑粘度的基础油和一种或多种润滑剂添加剂，其中所述基础油包含或由基础油组成，所述基础油包含至少一种类异戊二烯化合物或由至少一种类异戊二烯化合物组成，所述类似物包含：（i）一个或两个含氧部分 独立地选自醚和酯部分; （ii）含有1至5个异戊二烯基单元的第一无环类异戊二烯部分; 和（iii）任选地，含有1至5个异戊二烯基单元的第二无环类异戊二烯部分，条件是至少一种类异戊二烯部分含有3至5个异戊二烯基，其中类异戊二烯化合物含有单醚部分。

公开(公告)号：WO2008075030A3

公开(公告)日：2008-08-07

申请号：PCT/GB2007004865

申请日：2007-12-18

Applicant: BP EXPLORATION OPERATING ,  GAEMERS SANDER

Inventor： GAEMERS SANDER

IPC: C10G2/00 ,  B01J23/80 ,  B01J23/89 ,  C07C1/04

CPC classification number: B01J37/0201 ,  B01J23/80 ,  B01J23/8953 ,  B01J37/0009 ,  B01J37/031 ,  B01J37/08 ,  C10G2/331 ,  C10G2/333

Abstract: A composition for use as a catalyst or catalyst precursor for the conversion of synthesis gas to hydrocarbons said composition comprises (i) cobalt either as the elemental metal, oxide or a compound thermally decomposable to the elemental metal or oxide and (ii) zinc in the form of the oxide or a compound thermally decomposable to the oxide and (iii) platinum in elemental form or in the form of a compound characterised in that the platinum metal is present in the composition in amount in the range 0.0001 to 1.50 % w/w. The compositions show improved activity over a wide temperature range than prior art compositions and also exhibit improved methane selectivity.

Abstract translation: 一种用作合成气转化为烃的催化剂或催化剂前体的组合物，所述组合物包含（ⅰ）作为元素金属，氧化物或可热分解成元素金属或氧化物的化合物的钴和（ⅱ） 氧化物或可热分解成氧化物的化合物的形式和（iii）铂以元素形式或以化合物的形式存在，其特征在于铂族金属以0.0001-1.50％w / w 。 该组合物在宽温度范围内比现有技术组合物显示改善的活性，并且还表现出改进的甲烷选择性。

公开(公告)号：WO2008075030A2

公开(公告)日：2008-06-26

申请号：PCT/GB2007/004865

申请日：2007-12-18

Applicant: BP EXPLORATION OPERATING COMPANY LIMITED ,  GAEMERS, Sander

Inventor： GAEMERS, Sander

IPC: C10G2/00 ,  B01J23/80 ,  B01J23/89 ,  C07C1/04

CPC classification number: B01J37/0201 ,  B01J23/80 ,  B01J23/8953 ,  B01J37/0009 ,  B01J37/031 ,  B01J37/08 ,  C10G2/331 ,  C10G2/333

Abstract: A composition for use as a catalyst or catalyst precursor for the conversion of synthesis gas to hydrocarbons said composition comprises (i) cobalt either as the elemental metal, oxide or a compound thermally decomposable to the elemental metal or oxide and (ii) zinc in the form of the oxide or a compound thermally decomposable to the oxide and (iii) platinum in elemental form or in the form of a compound characterised in that the platinum metal is present in the composition in amount in the range 0.0001 to 1.50 % w/w. The compositions show improved activity over a wide temperature range than prior art compositions and also exhibit improved methane selectivity.

Abstract translation: 用作催化剂或用于将合成气转化为烃的催化剂前体的组合物所述组合物包含（i）钴作为元素金属，氧化物或可分解成元素金属或氧化物的化合物和（ii） 形式的氧化物或可热分解成氧化物的化合物，（iii）元素形式或化合物形式的铂，其特征在于铂金属以0.0001至1.50％w / w的量存在于组合物中 。 组合物在比现有技术组合物宽的温度范围内显示出改进的活性，并且还表现出改进的甲烷选择性。

公开(公告)号：WO2008075023A1

公开(公告)日：2008-06-26

申请号：PCT/GB2007/004853

申请日：2007-12-18

Applicant: BP EXPLORATION OPERATING COMPANY LIMITED ,  GAEMERS, Sander

Inventor： GAEMERS, Sander

IPC: C10G2/00 ,  B01J23/80 ,  B01J23/889 ,  C07C1/04

CPC classification number: B01J37/0201 ,  B01J23/80 ,  B01J23/8896 ,  B01J37/0009 ,  B01J37/03 ,  B01J37/18 ,  C10G2/332

Abstract: A composition for use as a catalyst or catalyst precursor for the conversion of synthesis gas to hydrocarbons said composition comprises (i) cobalt either as the elemental metal, oxide or a compound thermally decomposable to the elemental metal or oxide and (ii) zinc in the form of the oxide or a compound thermally decomposable to the oxide and (iii) rhenium in elemental form or in the form of a compound characterised in that the rhenium metal is present in the composition in amount in the range 0.0001 to 2.00 % w/w. The compositions show improved activity over a wide temperature range than prior art compositions.

Abstract translation: 用作催化剂或用于将合成气转化为烃的催化剂前体的组合物所述组合物包含（i）钴作为元素金属，氧化物或可分解成元素金属或氧化物的化合物和（ii） 形式的氧化物或可热分解成氧化物的化合物和（iii）元素形式的铼或化合物的形式，其特征在于铼金属以0.0001-2.00％w / w的量存在于组合物中 。 该组合物在宽的温度范围内显示出比现有技术组合物更好的活性。