公开(公告)号：WO2013154907A3

公开(公告)日：2014-01-03

申请号：PCT/US2013035274

申请日：2013-04-04

Applicant: CHEVRON PHILLIPS CHEMICAL CO ,  KUFELD SCOTT E ,  HOTTOVY JOHN D ,  CHANG AI-FU

Inventor： KUFELD SCOTT E ,  HOTTOVY JOHN D ,  CHANG AI-FU

IPC: B01D53/00 ,  C08F2/00 ,  C08F2/01 ,  C08F6/00 ,  C08F10/02 ,  C08J11/02

CPC classification number: C08F2/001 ,  C08F6/001 ,  C08F110/02 ,  C08J11/02 ,  C08J2323/06 ,  C08L23/04 ,  C08F10/02 ,  C08F2/14

Abstract: A process for component separation in a polymer production system, comprising separating a polymerization product stream into a gas stream and a polymer stream, wherein the gas stream comprises ethane and unreacted ethylene, distilling the gas stream into a light hydrocarbon stream, wherein the light hydrocarbon stream comprises ethane and unreacted ethylene, contacting the light hydrocarbon stream with an absorption solvent system, wherein at least a portion of the unreacted ethylene from the light hydrocarbon stream is absorbed by the absorption solvent system, and recovering a waste gas stream from the absorption solvent system, wherein the waste gas stream comprises ethane, hydrogen, or combinations thereof.

Abstract translation: 一种聚合物生产系统中组分分离的方法，包括将聚合产物流分离成气流和聚合物流，其中气流包括乙烷和未反应的乙烯，将气流蒸馏成轻质烃流，其中轻烃 流包含乙烷和未反应的乙烯，使轻质烃流与吸收溶剂体系接触，其中至少一部分来自轻烃流的未反应乙烯被吸收溶剂体系吸收，并从吸收溶剂中回收废气流 系统，其中废气流包括乙烷，氢气或其组合。

公开(公告)号：WO2005047355A3

公开(公告)日：2005-09-09

申请号：PCT/US2004037279

申请日：2004-11-05

Applicant: CHEVRON PHILLIPS CHEMICAL CO ,  STACY NATHAN E ,  NASH LARRY L ,  HOTTOVY JOHN D

Inventor： STACY NATHAN E ,  NASH LARRY L ,  HOTTOVY JOHN D

IPC: C08F297/04 ,  C08L53/02

CPC classification number: C08L53/02 ,  C08F297/04 ,  C08F297/046 ,  C08L53/00

Abstract: We disclose a monovinylarene/conjugated diene block copolymer, comprising: (i) a random (conjugated dieneX/monovinylareney)m block, wherein x is about 2.5 wt% to about 10 wt%, y is from about 90 wt% to about 97.5 wt%, and x + y is about 97.5 wt% to 100 wt%; and (ii) a (conjugated dime)n block; wherein n is from about 20 wt% to about 30 wt%, m is from about 70 wt% to about 80 wt%, and m + n is from about 90 wt% to 100 wt%. We also disclose a method of forming the block copolymer and a method for fabricating an article from the block copolymer. The block copolymer typically exhibits a Tg at least about 10°C less than the Tg of a reference polymer differing only in that x is about 0 wt% and y is about 100 wt%.

Abstract translation: 我们公开了单乙烯基芳烃/共轭二烯嵌段共聚物，其包含：（i）无规（共轭二烯X /单乙烯基芳烃）m嵌段，其中x为约2.5重量％至约10重量％，y为约90重量％至约97.5重量％ ％，x + y为约97.5wt％至100wt％; 和（ii）（共轭角质）n嵌段; 其中n为约20重量％至约30重量％，m为约70重量％至约80重量％，m + n为约90重量％至100重量％。 我们还公开了形成嵌段共聚物的方法和由嵌段共聚物制造制品的方法。 嵌段共聚物通常表现出比参考聚合物的Tg低至少约10℃的Tg，其仅在x为约0重量％且y为约100重量％时不同。

公开(公告)号：WO2013154882A1

公开(公告)日：2013-10-17

申请号：PCT/US2013/035103

申请日：2013-04-03

Applicant: CHEVRON PHILLIPS CHEMICAL COMPANY LP ,  HOTTOVY, John, D ,  CHANG, Ai-Fu

Inventor： HOTTOVY, John, D ,  CHANG, Ai-Fu

IPC: B01D53/00 ,  C08F6/00 ,  C08F10/02

CPC classification number: B01D53/1418 ,  B01D53/1493 ,  B01D2252/20421 ,  B01D2252/20468 ,  B01D2252/604 ,  B01D2256/24 ,  C08F6/001 ,  C08F110/02 ,  C08J11/02 ,  C08J2323/06 ,  C08L23/04

Abstract: A process for recovery of ethylene from a polymerization product stream of a polyethylene production system, comprising separating a light gas stream from the polymerization product stream, wherein the light gas stream comprises ethane and unreacted ethylene, contacting the light gas stream with an absorption solvent system, wherein the contacting the light gas stream with the absorption solvent system occurs at a temperature in a range of from about 40° F to about 110° F, wherein at least a portion of the unreacted ethylene from the light gas stream is absorbed by the absorption solvent system, and recovering unreacted ethylene from the absorption solvent system to yield recovered ethylene.

Abstract translation: 一种从聚乙烯生产系统的聚合产物流中回收乙烯的方法，包括从聚合产物流中分离轻质气体流，其中轻质气体流包含乙烷和未反应的乙烯，使轻质气体物流与吸收溶剂体系接触 其中轻质气体流与吸收溶剂体系的接触在约40°F至约110°F的温度范围内发生，其中至少一部分来自轻质气体流的未反应的乙烯被 吸收溶剂体系，并从吸收溶剂系统回收未反应的乙烯以产生回收的乙烯。

公开(公告)号：WO2011146334A1

公开(公告)日：2011-11-24

申请号：PCT/US2011/036434

申请日：2011-05-13

Applicant: CHEVRON PHILLIPS CHEMICAL COMPANY LP ,  HOTTOVY, John, D.

Inventor： HOTTOVY, John, D.

IPC: C08F10/00 ,  C08F2/00

CPC classification number: B01J19/245 ,  B01J19/1837 ,  C08F10/00 ,  C08F2400/02 ,  C08F2/002 ,  C08F2/01 ,  C08F2/001

Abstract: Techniques and systems for producing a polyolefin using reactors in series are described. Described embodiments include techniques and systems for polymerizing a monomer in a first polymerization reactor to form a first polyolefin, discharging a first slurry continuously from the first polymerization reactor to a second polymerization reactor, and discharging a second slurry continuously from the second polymerization reactor. Using continuous take-off devices disposed on either or both reactors, pressure control may be attained such that the rate of transfer between and withdrawal from both reactors are within a desired range.

Abstract translation: 描述了使用串联反应器生产聚烯烃的技术和系统。 描述的实施方案包括用于在第一聚合反应器中聚合单体以形成第一聚烯烃的技术和系统，将第一浆料从第一聚合反应器连续排出到第二聚合反应器，并从第二聚合反应器连续排出第二浆料。 使用设置在任一个或两个反应器上的连续取出装置，可以实现压力控制，使得两个反应器之间的转移速率和从两个反应器中回收的速率在期望的范围内。

公开(公告)号：WO2011097119A1

公开(公告)日：2011-08-11

申请号：PCT/US2011/022812

申请日：2011-01-28

Applicant: CHEVRON PHILLIPS CHEMICAL COMPANY LP ,  HOTTOVY, John, D. ,  MUTCHLER, Joel, A

Inventor： HOTTOVY, John, D. ,  MUTCHLER, Joel, A

IPC: C08F10/00 ,  C08F2/14

CPC classification number: B01J8/005 ,  B01J19/0013 ,  B01J19/1837 ,  B01J2219/00094 ,  B01J2219/00162 ,  B01J2219/00272 ,  C08F10/00 ,  C08F2/14

Abstract: Embodiments of the present application provide a method for manufacturing a polyolefin and a system for implementing the method. The method comprises combining a catalyst with a diluent mixture containing a diluent and an olefin monomer in a polymerization reactor. The diluent may comprise propane, butane, or isobutane, or a combination thereof. The polymerization reactor is operated at a pressure above a critical pressure of the diluent, but below the critical temperature of the diluent.

Abstract translation: 本发明的实施方案提供了制造聚烯烃的方法和用于实施该方法的系统。 该方法包括在聚合反应器中将催化剂与含有稀释剂和烯烃单体的稀释剂混合物组合。 稀释剂可以包括丙烷，丁烷或异丁烷，或其组合。 聚合反应器在高于稀释剂的临界压力但低于稀释剂的临界温度的压力下操作。

公开(公告)号：WO2013003133A1

公开(公告)日：2013-01-03

申请号：PCT/US2012/043215

申请日：2012-06-20

Applicant: CHEVRON PHILLIPS CHEMICAL COMPANY LP ,  HOTTOVY, John, D ,  KUFELD, Scott, E

Inventor： HOTTOVY, John, D ,  KUFELD, Scott, E

IPC: B01J19/18 ,  B01J8/00 ,  C08F10/00 ,  B01D3/06

CPC classification number: C08F110/02 ,  B01D1/04 ,  B01D1/24 ,  B01J8/005 ,  B01J19/06 ,  B01J19/1837 ,  B01J2219/00006 ,  C08F6/003 ,  C08F10/00 ,  C08F2/00 ,  C08F2/14 ,  C08L23/00

Abstract: The present embodiments provide a system and method for separation within a polymer production process. Specifically, a flashline heater configured according to present embodiments may provide more time than is required for complete vaporization of liquid hydrocarbons that are not entrained within a polymer fluff produced within a polymerization reactor. Such extra time may allow for liquid hydrocarbons that are entrained within the polymer fluff to be vaporized.

Abstract translation: 本实施例提供了聚合物生产过程中的分离系统和方法。 具体而言，根据本实施例构造的闪蒸加热器可以提供比在聚合反应器内产生的聚合物绒毛内不夹带的液体烃完全蒸发所需的时间更长的时间。 这种额外的时间可以允许夹带在聚合物绒毛内的液体烃被汽化。

公开(公告)号：WO2010027912A1

公开(公告)日：2010-03-11

申请号：PCT/US2009/055324

申请日：2009-08-28

Applicant: CHEVRON PHILLIPS CHEMICAL COMPANY LP ,  HOTTOVY, John, D. ,  TAIT, John, H. ,  BURNS, David, H. ,  VERSER, Donald, W. ,  HEIN, James, E.

Inventor： HOTTOVY, John, D. ,  TAIT, John, H. ,  BURNS, David, H. ,  VERSER, Donald, W. ,  HEIN, James, E.

IPC: B01J19/18 ,  B01J19/24 ,  C08F10/00

CPC classification number: B01J4/008 ,  B01J19/1837 ,  B01J2204/005 ,  B01J2219/00094 ,  B01J2219/00159 ,  C08F10/00 ,  C08F2/14 ,  C08F2/01

Abstract: A flash chamber sized to receive the effluent discharged from a polyolefin reactor during normal operation of the reactor and during a reactor dump, advantageously eliminating a reactor dump tank or alternate flash tank from the equipment outlay of a polyolefin manufacturing process. The flash chamber is sized to hold at least the polyolefin solids discharged from the reactor. A condenser fluidically coupled to an overhead portion of the flash chamber is sized to condense the flow rate of vaporized hydrocarbon (e.g., diluent, monomer, etc.) discharged overhead from the flash chamber during normal operation and during the reactor dump.

Abstract translation: 闪蒸室的尺寸适于接收在反应堆的正常操作期间和反应器堆放期间从聚烯烃反应器排出的流出物，有利地从聚烯烃制造过程的设备消耗中消除反应堆倾倒罐或替代闪蒸罐。 闪蒸室的尺寸至少保持从反应器排出的聚烯烃固体。 流体耦合到闪蒸室的顶部部分的冷凝器的尺寸被设定为在正常操作期间和在反应堆堆放期间冷凝从闪蒸室排出的汽化烃（例如稀释剂，单体等）的流速。

公开(公告)号：WO2004024780A1

公开(公告)日：2004-03-25

申请号：PCT/US2003/029071

申请日：2003-09-16

Applicant: CHEVRON PHILLIPS CHEMICAL COMPANY LP ,  KUFELD, Scott, E. ,  REID, Thomas, A. ,  TAIT, John, H. ,  BURNS, David, H. ,  VERSER, DONALD, W. ,  HOTTOVY, John, D. ,  HENSLEY, Harvey, D. ,  PRZELOMSKI, David, J. ,  CYMBALUK, Teddy, H. ,  FRANKLIN, Robert, K. ,  PEREZ, Ethelwoldo, P.

Inventor： KUFELD, Scott, E. ,  REID, Thomas, A. ,  TAIT, John, H. ,  BURNS, David, H. ,  VERSER, DONALD, W. ,  HOTTOVY, John, D. ,  HENSLEY, Harvey, D. ,  PRZELOMSKI, David, J. ,  CYMBALUK, Teddy, H. ,  FRANKLIN, Robert, K. ,  PEREZ, Ethelwoldo, P.

IPC: C08F2/00

CPC classification number: B01J19/1837 ,  B01J8/003 ,  B01J8/008 ,  C08F10/00 ,  C08F210/16 ,  C08F2/01 ,  C08F2/14 ,  C08F210/14

Abstract: A polymerization loop reactor including a loop reaction zone, a continuous takeoff, and a fluid slurry disposed in the reaction zone. A generally cylindrical wall defines the loop reaction zone. The length of the loop reaction zone and the nominal outside diameter of the generally cylindrical wall define a length / diameter ratio greater than 250. The reactor can be charged with a fluid slurry including an olefin monomer reactant, solid olefin polymer particles, and a liquid diluent. The concentration of the solid olefin polymer particles in the slurry can be greater than 40 weight percent based on the weight of polymer particles and the weight of liquid diluent. Also disclosed is a polymerization process carried out by polymerizing, in the loop reaction zone of a reactor as defined above, at least one olefin monomer in a liquid diluent to produce a fluid slurry as defined above.

Abstract translation: 一种包括环路反应区，连续起飞和设置在反应区中的流体淤浆的聚合反应器反应器。 大致圆柱形的壁限定了环路反应区域。 环路反应区的长度和大致圆柱形壁的标称外径确定了大于250的长度/直径比。反应器可以装有包含烯烃单体反应物，固体烯烃聚合物颗粒和液体的流体浆料 冲淡。 基于聚合物颗粒的重量和液体稀释剂的重量，浆料中固体烯烃聚合物颗粒的浓度可以大于40重量％。 还公开了聚合方法，其通过在液体稀释剂中的至少一种烯烃单体在如上定义的反应器的环路反应区域中聚合以产生如上所定义的流体浆料而进行。

公开(公告)号：WO2014070608A1

公开(公告)日：2014-05-08

申请号：PCT/US2013/066842

申请日：2013-10-25

Applicant: CHEVRON PHILLIPS CHEMICAL COMPANY LP ,  KUFELD, Scott E. ,  KREISCHER, Bruce E. ,  HOTTOVY, John D.

Inventor： KUFELD, Scott E. ,  KREISCHER, Bruce E. ,  HOTTOVY, John D.

IPC: C08F2/14 ,  C08F10/02

CPC classification number: C08F2/01 ,  B01J19/1837 ,  B01J2219/00162 ,  C08F2/14 ,  C08F6/00 ,  C08F6/003 ,  C08J11/02 ,  C08F10/02 ,  C08F2/00 ,  C08F210/16 ,  C08F210/14 ,  C08L23/06

Abstract: Processes and systems for the production for pressure management of a polymerization product flowing from a loop polymerization reactor to a separation vessel in a slurry polymerization system are disclosed herein. For example, a process comprises withdrawing the polymerization product from a loop polymerization reactor, and conveying the withdrawn polymerization product to a separation vessel via a first pressure differential and a second pressure differential. The withdrawn polymerization product may flow through the first pressure differential before flowing through the second pressure differential, and the first pressure differential may be less than the second pressure differential.

Abstract translation: 在本文中公开了用于从淤浆聚合系统中的环状聚合反应器流到分离容器的聚合产物的压力管理生产的方法和系统。 例如，一种方法包括从环路聚合反应器中取出聚合产物，并通过第一压力差和第二压差将抽出的聚合产物输送到分离容器。 撤回的聚合产物可能在流过第二压力差之前流过第一压力差，并且第一压力差可小于第二压力差。

公开(公告)号：WO2011162961A1

公开(公告)日：2011-12-29

申请号：PCT/US2011/039697

申请日：2011-06-09

Applicant: CHEVRON PHILLIPS CHEMICAL COMPANY LP ,  HOTTOVY, John, D ,  PEACOCK, Richard

Inventor： HOTTOVY, John, D ,  PEACOCK, Richard

IPC: B01J19/18 ,  C08F2/00

CPC classification number: C08L23/06 ,  B01J19/0006 ,  B01J19/002 ,  B01J19/1837 ,  B01J19/2455 ,  B01J2219/00162 ,  B01J2219/0027 ,  B01J2219/24 ,  C08F2/01 ,  C08F10/00 ,  C08F210/16 ,  C08F2/14 ,  C08F210/14

Abstract: A reactor system including an enclosed pressure relief system and/or a control system. The enclosed pressure relief system including a slurry separation system communicatively coupled with a pressure relief valve coupled to a loop reactor such that activation of the pressure relief valve results in discharge of a slurry from the loop reactor to the slurry separation system, wherein the slurry separation system is capable of separating solid and liquid components from gas components of the slurry and transmitting the gas components to a flare via a flare header.

Abstract translation: 包括封闭的压力释放系统和/或控制系统的反应堆系统。 封闭的压力释放系统包括浆料分离系统，其与连接到回路反应器的压力释放阀通信地联接，使得压力释放阀的激活导致浆料从环管反应器排放到浆料分离系统，其中浆料分离 系统能够将固体和液体组分与浆料的气体组分分离，并通过火炬头将气体组分传输到耀斑。