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    HIGH PERFORMANCE SOLUTION PROCESSABLE SEMINCONDUCTOR BASED ON DITHIENO [2,3-D:2',3'-D']BENZO[1,2-B:4,5-B'] DITHIOPHENE
    2.
    发明申请
    HIGH PERFORMANCE SOLUTION PROCESSABLE SEMINCONDUCTOR BASED ON DITHIENO [2,3-D:2',3'-D']BENZO[1,2-B:4,5-B'] DITHIOPHENE 审中-公开
    基于DITHIENO [2,3-D：2'，3'-D'] BENZO [1,2-B：4,5-B']二氢苯的高性能溶液可处理的SEMINCONUCTOR

    公开(公告)号：WO2010000670A1

    公开(公告)日：2010-01-07

    申请号：PCT/EP2009/057985

    申请日：2009-06-25

    申请人： BASF SE ,  MAX-PLANCK-GESELLSCHAFT ZUR FÖRDERUNG DER WISSENSCHAFTEN E.V. ,  KASTLER, Marcel ,  KOEHLER, Silke ,  MUELLEN, Klaus ,  GAO, Peng ,  BECKMANN, Dirk ,  FENG, Xinliang

    发明人： KASTLER, Marcel ,  KOEHLER, Silke ,  MUELLEN, Klaus ,  GAO, Peng ,  BECKMANN, Dirk ,  FENG, Xinliang

    IPC分类号： C07D495/12

    CPC分类号： H01L51/0074 ,  C07D495/22 ,  C09K11/06 ,  C09K2211/1011 ,  C09K2211/1092 ,  G02B2006/12069 ,  H01L51/0545 ,  H01L51/5048 ,  H05B33/10 ,  H05B33/14 ,  Y02E10/549

    摘要： Dithienobenzodithiophenes of general formula (I) in which R 1 to R 6 are each independently selected from a) H, b) halogen, c) -CN, d) -NO 2 , e) - OH, f) a C 1-20 alkyl group, g) a C 2-20 alkenyl group, h) a C 2-20 alkynyl group, i) a C 1-20 alkoxy group, j) a C 1-20 alkylthio group, k) a C 1-20 haloalkyl group, I) a -Y- C 3-10 cycloalkyl group, m) a -Y-C 6-14 aryl group, n) a -Y-3-12 membered cyclo- heteroalkyl group, or o) a -Y-5-14 membered heteroaryl group, wherein each of the C 1-20 alkyl group, the C 2-20 alkenyl group, the C 2-20 alkynyl group, the C 3-10 cycloalkyl group, the C 6-14 aryl group, the 3-12 membered cyc- loheteroalkyl group, and the 5-14 membered heteroaryl group is optionally substituted with 1 -4 R 7 groups, wherein R 1 and R 3 and R 2 and R 4 may also together form an aliphatic cyclic moiety, Y is independently selected from divalent a C 1-6 alkyl group, a divalent C 1 - 6 haloalkyl group, or a covalent bond; and m is independently selected from 0, 1, or 2. The invention also relates to the use of the dithienobenzodithiophenes according to any of claims 1 to 4 as semiconductors or charge transport materials, as thin-film transistors (TFTs), or in semiconductor components for organic light-emitting diodes (OLEDs), for photovoltaic components or in sensors, as an electrode material in batteries, as optical waveguides or for electrophotography applications.

    摘要翻译： 通式（I）的二噻吩并苯并二噻吩，其中R 1至R 6各自独立地选自a）H，b）卤素，c）-CN，d）-NO 2，e）-OH，f）C 1-20烷基， ）C2-20烯基，h）C2-20炔基，i）C1-20烷氧基，j）C1-20烷硫基，k）C1-20卤代烷基，I）a -Y- C3-10环烷基，m）a-Y-C6-14芳基，n）a -Y-3-12元环杂烷基，或o）-Y-5-14元杂芳基，其中各 C 1-20烷基，C 2-20烯基，C 2-20炔基，C 3-10环烷基，C 6-14芳基，3-12元环杂烷基，和5-14 任选被1-4个R 7基团取代，其中R 1和R 3以及R 2和R 4也可以一起形成脂族环状部分，Y独立地选自二价C 1-6烷基，二价C 1-6卤代烷基 ，或共价键; 并且m独立地选自0,1或2.本发明还涉及根据权利要求1至4中任一项所述的二噻吩并苯并噻吩作为半导体或电荷传输材料，作为薄膜晶体管（TFT）或半导体 用于有机发光二极管（OLED）的组件，用于光伏组件或传感器，作为电池中的电极材料，作为光波导或电子照相应用。

    DITHIENOBENZO-THIENO[3,2-B]THIOPHENE-COPOLYMER AND ITS USE AS HIGH PERFORMANCE SOLUTION PROCESSABLE SEMICONDUCTING POLYMER
    4.
    发明申请
    DITHIENOBENZO-THIENO[3,2-B]THIOPHENE-COPOLYMER AND ITS USE AS HIGH PERFORMANCE SOLUTION PROCESSABLE SEMICONDUCTING POLYMER 审中-公开
    二氢苯并噻喃[3,2-B]噻吩共聚物及其作为高性能溶液可加工的半导体聚合物

    公开(公告)号：WO2011067192A2

    公开(公告)日：2011-06-09

    申请号：PCT/EP2010/068365

    申请日：2010-11-29

    申请人： BASF SE ,  MAX-PLANCK-GESELLSCHAFT ZUR FOERDERUNG DER WISSENSCHAFTEN E.V. ,  KASTLER, Marcel ,  KOEHLER, Silke ,  MUELLEN, Klaus ,  RIEGER, Ralph

    发明人： KASTLER, Marcel ,  KOEHLER, Silke ,  MUELLEN, Klaus ,  RIEGER, Ralph

    IPC分类号： C08G61/12

    CPC分类号： H01L51/0043 ,  C08G61/126 ,  C08G2261/124 ,  C08G2261/3223 ,  C08G2261/3243 ,  C08G2261/414 ,  C08G2261/92 ,  H01L51/0036 ,  H01L51/0558 ,  Y02E10/549

    摘要： Dithienobenzo-thieno[3,2-b]thiophene-copolymers of the formula (I) wherein: pi is a monocyclic or polycyclic moiety optionally substituted with 1-4 Ra groups, wherein R a , at each occurrence, is independently hydrogen or a) a halogen, b) -CN, c) -NO 2 , d) oxo, e) -OH, f) =C(R b ) 2 ; g) a C 1-20 alkyl group, h) a C 2-20 alkenyl group, i) a C 2-20 alkynyl group, j) a C 1-20 alkoxy group, k) a C 1-20 alkylthio group, I) a C 1-20 haloalkyl group, m) a -Y- C 3-10 cycloalkyl group, n) a -Y- C 6-14 aryl group, o) a -Y-3-12 membered cycloheteroalkyl group, or p) a -Y-5-14 membered heteroaryl group, wherein each of the C 1-20 alkyl group, the C 2-20 alkenyl group, the C 2-20 alkynyl group, the C 3-10 cycloalkyl group, the C 6-14 aryl or haloaryl group, the 3-12 membered cycloheteroalkyl group, and the 5- 14 membered heteroaryl group is optionally substituted with 1 -4 R b groups; Y, at each occurrence, is independently a divalent C 1-6 alkyl group, a divalent C 1-6 haloalkyl group, or a covalent bond; and R 1 , R 2 , R 3 , at each occurrence, are independently H, a halogen, CN, a C 1-30 alkyl group, a C 2-30 alkenyl group, a C 1-30 haloalkyl group, a C 2-30 alkynyl group, a C 1-30 alkoxy group, a C(O)-C 1-20 alkyl group, a C(O)-OC 1-20 alkyl group, a Y-C 3-10 cycloalkyl group, a -Y-3- 12 membered cycloheteroalkyl group, each optionally substituted with 1-5 substituents selected from a halogen, -CN, a C 1-6 alkyl group, a C 1-6 alkoxy group, and a C 1-6 haloalkyl group, -L-Ar 1 , -L-Ar 1 -Ar 1 , -L-Ar 1 -R 4 , or -L-Ar 1 -Ar 1 -R 4 and Y, at each occurrence, is independently a divalent C 1-6 alkyl group, a divalent C 1-6 haloalkyl group, or a covalent bond; n = 0, 1, 2; and o = 1 - 1000.

    摘要翻译： 式（I）的二噻吩并噻吩并[3,2-b]噻吩 - 共聚物，其中：pi是任选被1-4个R a基团取代的单环或多环部分，其中R a在每次出现时独立地是氢或a） 卤素，b）-CN，c）-NO 2，d）氧代，e）-OH，f）= C（R b）2; g）C 1-20烷基，h）C 2-20烯基，i）C 2-20炔基，j）C 1-20烷氧基，k）C 1-20烷硫基，I）C1- 20个卤代烷基，m）a -Y-C 3-10环烷基，n）a -Y-C 6-14芳基，o）a -Y-3-12元环杂烷基，或p）a -Y-5- 14元杂芳基，其中C 1-20烷基，C 2-20烯基，C 2-20炔基，C 3-10环烷基，C 6-14芳基或卤代芳基中的每一个，3-12元 环杂烷基，5-14元杂芳基任选被1-4个Rb基团取代; Y在每次出现时独立地为二价C 1-6烷基，二价C 1-6卤代烷基或共价键; 并且R1，R2，R3各自独立地为H，卤素，CN，C1-30烷基，C2-30烯基，C1-30卤代烷基，C2-30炔基，C1 -30烷氧基，C（O）-C1-20烷基，C（O）-OC1-20烷基，Y-C3-10环烷基，-Y-3-12元环杂烷基，各自 任选被1-5个选自卤素，-CN，C 1-6烷基，C 1-6烷氧基和C 1-6卤代烷基的取代基取代，-L-Ar 1，-L-Ar 1 -Ar 1 - L-Ar1-R4或-L-Ar1-Ar1-R4和Y各自独立地为二价C 1-6烷基，二价C 1-6卤代烷基或共价键; n = 0,1,2; 并且o = 1-1000。

    DITHIENOBENZO-THIENO[3,2-B]THIOPHENE-COPOLYMER AND ITS USE AS HIGH PERFORMANCE SOLUTION PROCESSABLE SEMICONDUCTING POLYMER
    9.
    发明申请
    DITHIENOBENZO-THIENO[3,2-B]THIOPHENE-COPOLYMER AND ITS USE AS HIGH PERFORMANCE SOLUTION PROCESSABLE SEMICONDUCTING POLYMER 审中-公开
    二噻吩并噻吩并[3,2-B]噻吩共聚物及其用作高性能溶液处理半导体聚合物

    公开(公告)号：WO2011067192A3

    公开(公告)日：2011-09-15

    申请号：PCT/EP2010068365

    申请日：2010-11-29

    申请人： BASF SE ,  MAX PLANCK GESELLSCHAFT ,  KASTLER MARCEL ,  KOEHLER SILKE ,  MUELLEN KLAUS ,  RIEGER RALPH

    发明人： KASTLER MARCEL ,  KOEHLER SILKE ,  MUELLEN KLAUS ,  RIEGER RALPH

    IPC分类号： C08G61/12 ,  H01L51/00 ,  H01L51/05

    CPC分类号： H01L51/0043 ,  C08G61/126 ,  C08G2261/124 ,  C08G2261/3223 ,  C08G2261/3243 ,  C08G2261/414 ,  C08G2261/92 ,  H01L51/0036 ,  H01L51/0558 ,  Y02E10/549

    摘要： Dithienobenzo-thieno[3,2-b]thiophene-copolymers of the formula (I) wherein: pi is a monocyclic or polycyclic moiety optionally substituted with 1-4 Ra groups, wherein Ra, at each occurrence, is independently hydrogen or a) a halogen, b) -CN, c) -NO2, d) oxo, e) -OH, f) =C(Rb)2; g) a C1-20 alkyl group, h) a C2-20 alkenyl group, i) a C2-20 alkynyl group, j) a C1-20 alkoxy group, k) a C1-20 alkylthio group, I) a C1-20 haloalkyl group, m) a -Y- C3-10 cycloalkyl group, n) a -Y- C6-14 aryl group, o) a -Y-3-12 membered cycloheteroalkyl group, or p) a -Y-5-14 membered heteroaryl group, wherein each of the C1-20 alkyl group, the C2-20 alkenyl group, the C2-20 alkynyl group, the C3-10 cycloalkyl group, the C6-14 aryl or haloaryl group, the 3-12 membered cycloheteroalkyl group, and the 5- 14 membered heteroaryl group is optionally substituted with 1 -4 Rb groups; Y, at each occurrence, is independently a divalent C1-6 alkyl group, a divalent C1-6 haloalkyl group, or a covalent bond; and R1, R2, R3, at each occurrence, are independently H, a halogen, CN, a C1-30 alkyl group, a C2-30 alkenyl group, a C1-30 haloalkyl group, a C2-30 alkynyl group, a C1-30 alkoxy group, a C(O)-C1-20 alkyl group, a C(O)-OC1-20 alkyl group, a Y-C3-10 cycloalkyl group, a -Y-3- 12 membered cycloheteroalkyl group, each optionally substituted with 1-5 substituents selected from a halogen, -CN, a C1-6 alkyl group, a C1-6 alkoxy group, and a C1-6 haloalkyl group, -L-Ar1, -L-Ar1 -Ar1, -L-Ar1-R4, or -L-Ar1-Ar1-R4 and Y, at each occurrence, is independently a divalent C1-6 alkyl group, a divalent C1-6 haloalkyl group, or a covalent bond; n = 0, 1, 2; and o = 1 - 1000.

    摘要翻译： 式（I）的二噻吩并苯并噻吩并[3,2-b]噻吩共聚物其中：p1是任选被1-4个Ra基团取代的单环或多环部分，其中Ra在每次出现时独立地为氢或a） b）-CN，c）-NO 2，d）氧代，e）-OH，f）= C（R b）2; g）C1-20烷基，h）C2-20烯基，i）C2-20炔基，j）C1-20烷氧基，k）C1-20烷硫基，I）C1- 20）卤代烷基，m）-YC 3 -10环烷基，n）-YC 6-14芳基，o）-Y-3-12元环杂烷基，或p）-Y- 14元杂芳基，其中C1-20烷基，C2-20链烯基，C2-20炔基，C3-10环烷基，C6-14芳基或卤代芳基，3-12元 环杂烷基，且所述5-14元杂芳基任选被1-4个Rb基团取代; Y在每次出现时独立地为二价C 1-6烷基，二价C 1-6卤代烷基或共价键; 并且R 1，R 2，R 3每次出现时独立地为H，卤素，CN，C 1-30烷基，C 2-30烯基，C 1-30卤代烷基，C 2-30炔基，C 30的烷氧基，C（O）-C1-20烷基，C（O）-OC1-20烷基，Y-C3-10环烷基，-Y-3-12元环杂烷基 其任选被1-5个选自卤素，-CN，C1-6烷基，C1-6烷氧基和C1-6卤代烷基的取代基取代，-L-Ar1，-L-Ar1-Ar1， - L-Ar1-R4或-L-Ar1-Ar1-R4和Y在每次出现时独立地为二价C1-6烷基，二价C1-6卤代烷基或共价键; n = 0,1,2; 和o = 1 - 1000。

    POLY(5,5'BIS(THIOPHEN-2-YL)-BENZO[2,1-B;3,4-B']DITHIOPHENE) AND ITS USE AS HIGH PERFORMANCE SOLUTION PROCESSABLE SEMICONDUCTING POLYMER
    10.
    发明申请
    POLY(5,5'BIS(THIOPHEN-2-YL)-BENZO[2,1-B;3,4-B']DITHIOPHENE) AND ITS USE AS HIGH PERFORMANCE SOLUTION PROCESSABLE SEMICONDUCTING POLYMER 审中-公开
    POLY（5,5'BIS（THIOPHEN-2-YL）-BENZO [2,1-B; 3,4-B'] DITHIOPHENE）及其作为高性能溶液可处理的半导体聚合物

    公开(公告)号：WO2010000669A1

    公开(公告)日：2010-01-07

    申请号：PCT/EP2009/057984

    申请日：2009-06-25

    申请人： BASF SE ,  MAX-PLANCK-GESELLSCHAFT ZUR FÖRDERUNG DER WISSENSCHAFTEN E.V. ,  KASTLER, Marcel ,  KOEHLER, Silke ,  MUELLEN, Klaus ,  LIU, Miaoyin ,  BECKMANN, Dirk ,  RIEGER, Ralph

    发明人： KASTLER, Marcel ,  KOEHLER, Silke ,  MUELLEN, Klaus ,  LIU, Miaoyin ,  BECKMANN, Dirk ,  RIEGER, Ralph

    IPC分类号： H01B1/12 ,  C08G61/12 ,  C07D495/02 ,  H01L51/30

    CPC分类号： H01L51/0036 ,  C07D495/04 ,  C08G61/126 ,  H01B1/127 ,  H01L51/0043 ,  H01L51/0074 ,  H01L51/0541 ,  H01L51/0545 ,  Y02E10/549

    摘要： Poly(5,5'-bis(thiophen-2-yl)-benzo[2,1 -b;3,4-b']dithiophene) comprising as repeating units the group of the formula (I) wherein R is independently selected from a) a C 1-2O alkyl group, b) a C 2-20 alkenyl group, c) a C 2-20 alkynyl group, d) a C 1-20 alkoxy group, e) a -Y-C 3-10 cycloalkyl group, f) a -Y-C 6-14 aryl group, g) a -Y-3-12 membered cycloheteroalkyl group, or h) a -Y-5-14 membered het- eroaryl group, wherein each of the C 1-20 alkyl group, the C 2-20 alkenyl group, the C 2-20 alkynyl group, the C 3-10 cycloalkyl group, the C 6-14 aryl group, the 3-12 membered cycloheteroalkyl group, and the 5-14 membered heteroaryl group is optionally substituted with 1 -4 R 1 groups, R 1 is independently selected from a) a S(O) m -C 1-20 alkyl group, b) a S(O) m -OC 1-20 alkyl group, c) a S(O) m -OC 6-14 aryl group, d) a C(O)-OC 1-20 alkyl group, e) a C(O)-OC 6-14 aryl group, f) a C 1-20 alkyl group, g) a C 2-20 alkenyl group, h) a C 2-20 alkynyl group, i) a C 1-20 alkoxy group, j) a C 3-10 cycloalkyl group, k) a C 6-14 aryl group, I) a 3-12 membered cycloheteroalkyl group, or m) a 5-14 membered heteroaryl group, Y is independently selected from a divalent C 1-6 alkyl group, or a covalent bond; and m is independently selected from 0, 1, or 2, and having a number average molecular weight M n in the range of from 5,000 to 200,000 g/mol.

    摘要翻译： 包含作为重复单元的式（I）基团（其中R独立地选择）的聚（5,5'-双（噻吩-2-基） - 苯并[2,1-b; 3,4-b']二噻吩） 从a）C1-2O烷基，b）C2-20烯基，c）C2-20炔基，d）C1-20烷氧基，e）-Y-C3-10环烷基，f ）a -Y-C 6-14芳基，g）a -Y-3-12元环杂烷基，或h）a -Y-5-14元环芳基，其中C 1-20烷基， C2-20烯基，C2-20炔基，C3-10环烷基，C6-14芳基，3-12元环杂烷基和5-14元杂芳基任选被1〜 4个R 1基团，R 1独立地选自a）S（O）m -C 1-20烷基，b）S（O）m OC1-20烷基，c）S（O）m -OC 6 - 14芳基，d）C（O）-OC1-20烷基，e）C（O）-OC6-14芳基，f）C1-20烷基，g）C2-20烯基， h）C 2-20炔基，i）C 1-20烷氧基，j）C 3-10环烷基，k）C6 -14芳基，I）3-12元环杂烷基，或m）5-14元杂芳基，Y独立地选自二价C 1-6烷基或共价键; m独立地选自0,1或2，数均分子量Mn在5,000至200,000g / mol的范围内。