Abstract:
The present invention relates to metal complexes of formula I, compositions comprising the metal complexes, to recording media comprising the metal complexes or compositions and to the use of the compositions in the production of optical recording media: wherein the substituent are as defined in the description. Use of the metal complexes of formula (I) in combination with oxonol dyes results, surprisingly, in a comparatively weak tendency of the oxonol dyes to aggregate in the solid state so that the absorption curve remains advantageously narrow event in the solid state, as a result of which recording media having high reflectivity as well as high sensitivity and good playback characteristics in the desired spectral range are made available.
Abstract:
The invention relates to an optical recording medium comprising a substrate, a reflecting layer and a recording layer, wherein the recording layer comprises a compound of formula (I),(II),(III); wherein R1, to R13, may be hydrogen or a variety of substituents, but R1, and R11 are not simultaneously hydrogen;Y - is an inorganic, organic or organometallic anion, or a mixture thereof; Z is a proton or a metal, ammonium or phosphonium cation, or a mixture thereof; m, n and o are each independently of the others an integer from 1 to 3; and p and q are each a number from 0 to 4, the ratio of o, p and q to one another, depending on the charge of the associated sub-structures, being such that there is no excess positive or negative charge in formula (I), (II) or (III). Also claimed are the use of a xanthene perchlorate in the preparation of compounds of formula (I), (II) or (III) having organometallic anions, and the use of lactates in the application of layers of dye to grooved substrates by spin-coating.
Abstract translation:本发明涉及一种光学记录介质,其包含基底,反射层和记录层,其中所述记录层包含式(I),(II),(III)的化合物; 其中R 1至R 13可以是氢或多种取代基,但R 1和R 11不同时为氢; Y m - 为无机,有机或有机金属阴离子或其混合物; Z n +是质子或金属,铵或鏻阳离子或其混合物; m,n和o彼此独立地为1至3的整数; 并且p和q各自是从0到4的数字,取决于相关子结构的电荷,o,p和q彼此的比率使得在公式(1)中不存在过量的正电荷或负电荷 I),(II)或(III)。 还要求保护x吨高氯酸盐在制备具有有机金属阴离子的式(I),(II)或(III)化合物中的应用,以及乳酸酯在通过旋涂 。
Abstract:
The invention relates to an optical recording medium comprising a substrate, a reflecting layer and a recording layer, wherein the recording layer comprises a compound of formula (I),(II),(III); wherein R 1 , to R 13 , may be hydrogen or a variety of substituents, but R 1 , and R 11 are not simultaneously hydrogen;Y m - is an inorganic, organic or organometallic anion, or a mixture thereof; Z n+ is a proton or a metal, ammonium or phosphonium cation, or a mixture thereof; m, n and o are each independently of the others an integer from 1 to 3; and p and q are each a number from 0 to 4, the ratio of o, p and q to one another, depending on the charge of the associated sub-structures, being such that there is no excess positive or negative charge in formula (I), (II) or (III). Also claimed are the use of a xanthene perchlorate in the preparation of compounds of formula (I), (II) or (III) having organometallic anions, and the use of lactates in the application of layers of dye to grooved substrates by spin-coating.
Abstract:
The present invention relates to an electronic device, especially an electroluminescent devices, comprising a compound of Formula (I), especially as host for phosphorescent compounds. The hosts may function with phosphorescent materials to provide improved efficiency, stability, manufacturability, or spectral characteristics of electroluminescent devices.
Abstract:
The invention relates to an optical recording medium comprising a substrate, a reflecting layer and a recording layer, wherein the recording layer comprises a compound of formula [L1Mr-4L-2] o [A m ] p [Z n+ q (I), [L 1 M r-3 L- 3 ] 0 [A m ] P [Z n+ ] q (II) or [L 3 M r-2 L 4 ] 0 [A m ] p [Z n+ ] q (III), or where applicable a mesomeric or tautomeric form thereof, wherein L 1 and L 2 are each independently of the other and L 3 and L 4 are each independently of the other wherein Q 1 isCR 1 orN,Q 2 iSO,S,NR 10 orQ 5 =Q 8 ,Q 3 is CR 3 orN,Q 4 isO,S,NR 10 or Q 7 =Q 8 , Q 5 is CR 5 or N , Q 6 is CR 6 or N , Q 7 is CR 7 or N , Q 8 is CR 8 or N , and Q 9 is 0, S, NR 10 or Q 6 =Q 8 ; M r , A m- , Z n+ , R 2 , R 9 are as defined in the claims.
Abstract translation:本发明涉及一种包括基板,反射层和记录层的光记录介质,其中记录层包含式[L1Mr-4L-2] o [A] m [p] [Z n + q (I),[L1Mr-3L-3] 0 [Am] P [Z n +] q(II)或[L3M L4] 0 [A m] p [Z
Abstract:
The present invention relates to a process for the preparation of furopyrroles of the general formula (I), comprising (a) heating a compound of the formula (II) under microwave irradiation optionally in the presence of an inert solvent, wherein A and A are Cl-C18alkyl, C2-Cl8alkenyl, C2-Cl8alkynyl, C5-C8cycloalkyl, C5- C8cycloalkenyl, aryl or heteroaryl, A is hydrogen, C1-C18alkyl, cyanomethyl, Ar ,-CR R -(CH2 )m -Ar or Y- R , wherein R and R independently of each other stand for hydrogen or C1-C4alkyl, or phenyl which can be substituted up to three times with C1-C4alkyl, Ar stands for aryl, C5-C8 cloalkyl, C5-C8 cycloalkenyl or heteroaryl, which can be substituted one to three times with C1-C8alkyl, C1-C8alkoxy, halogen or phenyl, which can be substituted with C1-C8alkyI or C1-C8alkoxy one to three times, and m stands for 0, 1, 2, 3 or 4, R is C1-C18alkyl, in particular C1-C4alkyl, aryl, in particular phenyl, or aralkyl, in particular benzyl, which can be substituted one to three times with C1-C8alkyl, C1-C8alkoxy, or halogen, Y is -C(O)-, -C(O)O-, -C(O)NH-, -SO2NH- or -SO2- and R is C1-Cl8alkyl, Ar , or aralkyl. The furopyrroles of the general formula (I) can be obtained in high yield and high purity by the process of the present invention.
Abstract:
The present invention relates to metal complexes of formula I, compositions comprising the metal complexes, to recording media comprising the metal complexes or compositions and to the use of the compositions in the production of optical recording media: wherein the substituent are as defined in the description. Use of the metal complexes of formula (I) in combination with oxonol dyes results, surprisingly, in a comparatively weak tendency of the oxonol dyes to aggregate in the solid state so that the absorption curve remains advantageously narrow event in the solid state, as a result of which recording media having high reflectivity as well as high sensitivity and good playback characteristics in the desired spectral range are made available.
Abstract:
The present invention relates to a process for the preparation of furopyrroles of the general formula (I), comprising (a) heating a compound of the formula (II) under microwave irradiation optionally in the presence of an inert solvent, wherein A 1 and A 2 are C l -C 18 alkyl, C 2 -C l8 alkenyl, C 2 -C l8 alkynyl, C 5 -C 8 cycloalkyl, C 5- C 8 cycloalkenyl, aryl or heteroaryl, A 3 is hydrogen, C 1 -C 18 alkyl, cyanomethyl, Ar 3 ,-CR 30 R 31 -(CH 2 ) m -Ar 3 or Y- R 32 , wherein R 30 and R 31 independently of each other stand for hydrogen or C 1 -C 4 alkyl, or phenyl which can be substituted up to three times with C 1 -C 4 alkyl, Ar 3 stands for aryl, C 5 -C 8 cloalkyl, C 5 -C 8 cycloalkenyl or heteroaryl, which can be substituted one to three times with C 1 -C 8 alkyl, C 1 -C 8 alkoxy, halogen or phenyl, which can be substituted with C 1 -C 8 alkyI or C 1 -C 8 alkoxy one to three times, and m stands for 0, 1, 2, 3 or 4, R is C 1 -C 18 alkyl, in particular C 1 -C 4 alkyl, aryl, in particular phenyl, or aralkyl, in particular benzyl, which can be substituted one to three times with C 1 -C 8 alkyl, C 1 -C 8 alkoxy, or halogen, Y is -C(O)-, -C(O)O-, -C(O)NH-, -SO 2 NH- or -SO 2 - and R 32 is C 1 -C l8 alkyl, Ar 3 , or aralkyl. The furopyrroles of the general formula (I) can be obtained in high yield and high purity by the process of the present invention.
Abstract:
The invention relates to an optical recording medium comprising a substrate, a reflecting layer and a recording layer, wherein the recording layer comprises a compound of formula [L1Mr-4L-2]o [A ]p [Z q(I), [L1Mr-3L-3]0 [Am] [Z ]q(II) or [L3M L4]0 [A ]p[Z ]q (III), or where applicable a mesomeric or tautomeric form thereof, wherein L1 and L2 are each independently of the other and L3 and L4 are each independently of the other wherein Q1 isCR1orN,Q2iSO,S,NR10orQ5=Q8,Q3 is CR3orN,Q4 isO,S,NR10or Q7=Q8, Q5 is CR5 or N , Q6 is CR6 or N , Q7 is CR7 or N , Q8 is CR8 or N , and Q9 is 0, S, NR10 or Q6=Q8; M , A , Z , R2, R9 are as defined in the claims.
Abstract translation:本发明涉及一种包括基底,反射层和记录层的光学记录介质,其中该记录层包含式[L1Mr-4L-2] o [A m] p [Z n + q (I),[L1Mr-3L-3] 0 [Am] [Zn +] q(II)或[L3Mr-L4] 0 [Am] p [Z
Abstract:
The invention relates to an optical recording medium comprising a substrate, a reflecting layer and a recording layer, wherein the recording layer comprises a compound of formula (I),(II),(III); wherein R1, to R13, may be hydrogen or a variety of substituents, but R1, and R11 are not simultaneously hydrogen;Y - is an inorganic, organic or organometallic anion, or a mixture thereof; Z is a proton or a metal, ammonium or phosphonium cation, or a mixture thereof; m, n and o are each independently of the others an integer from 1 to 3; and p and q are each a number from 0 to 4, the ratio of o, p and q to one another, depending on the charge of the associated sub-structures, being such that there is no excess positive or negative charge in formula (I), (II) or (III). Also claimed are the use of a xanthene perchlorate in the preparation of compounds of formula (I), (II) or (III) having organometallic anions, and the use of lactates in the application of layers of dye to grooved substrates by spin-coating.
Abstract translation:本发明涉及一种包括基底,反射层和记录层的光学记录介质,其中记录层包括式(I),(II),(III)的化合物; 其中R 1至R 13可以是氢或各种取代基,但R 1和R 11不同时为氢; Y 1 - 为无机,有机或有机金属阴离子或其混合物; Z 是质子或金属,铵或鏻阳离子或其混合物; m,n和o各自独立地为1〜3的整数; 并且p和q各自为0至4的数,根据相关子结构的电荷,o,p和q彼此的比例使得在式(1)中不存在过量的正电荷或负电荷 I),(II)或(III)。 还要求的是使用高氯酸呫吨酯来制备具有有机金属阴离子的式(I),(II)或(III)化合物,以及使用乳酸盐通过旋涂将染料层施加到凹槽基材上 。