NEW METAL COMPLEXES
    1.
    发明申请
    NEW METAL COMPLEXES 审中-公开
    新金属复合材料

    公开(公告)号:WO2004102551A2

    公开(公告)日:2004-11-25

    申请号:PCT/EP2004/050706

    申请日:2004-05-05

    Abstract: The present invention relates to metal complexes of formula I, compositions comprising the metal complexes, to recording media comprising the metal complexes or compositions and to the use of the compositions in the production of optical recording media: wherein the substituent are as defined in the description. Use of the metal complexes of formula (I) in combination with oxonol dyes results, surprisingly, in a comparatively weak tendency of the oxonol dyes to aggregate in the solid state so that the absorption curve remains advantageously narrow event in the solid state, as a result of which recording media having high reflectivity as well as high sensitivity and good playback characteristics in the desired spectral range are made available.

    Abstract translation: 本发明涉及式I的金属络合物,包含金属络合物的组合物,包含金属络合物或组合物的记录介质以及组合物在制备光学记录介质中的用途:其中取代基如说明书中所定义 。 式(I)的金属络合物与氧杂醇染料的组合使用令人惊奇的是,氧固醇染料在固体状态下聚集的相对较弱的趋势,使得吸收曲线在固体状态下保持有利的是狭窄的事件,如 其结果是可以获得具有高反射率的记录介质以及在所需光谱范围内的高灵敏度和良好的回放特性。

    PROCESS FOR THE PREPARATION OF FUROPYRROLES
    6.
    发明申请
    PROCESS FOR THE PREPARATION OF FUROPYRROLES 审中-公开
    制备氟化物的方法

    公开(公告)号:WO2005005430A3

    公开(公告)日:2005-06-16

    申请号:PCT/EP2004051259

    申请日:2004-06-28

    CPC classification number: C07D487/04 C07D491/04

    Abstract: The present invention relates to a process for the preparation of furopyrroles of the general formula (I), comprising (a) heating a compound of the formula (II) under microwave irradiation optionally in the presence of an inert solvent, wherein A and A are Cl-C18alkyl, C2-Cl8alkenyl, C2-Cl8alkynyl, C5-C8cycloalkyl, C5- C8cycloalkenyl, aryl or heteroaryl, A is hydrogen, C1-C18alkyl, cyanomethyl, Ar ,-CR R -(CH2 )m -Ar or Y- R , wherein R and R independently of each other stand for hydrogen or C1-C4alkyl, or phenyl which can be substituted up to three times with C1-C4alkyl, Ar stands for aryl, C5-C8 cloalkyl, C5-C8 cycloalkenyl or heteroaryl, which can be substituted one to three times with C1-C8alkyl, C1-C8alkoxy, halogen or phenyl, which can be substituted with C1-C8alkyI or C1-C8alkoxy one to three times, and m stands for 0, 1, 2, 3 or 4, R is C1-C18alkyl, in particular C1-C4alkyl, aryl, in particular phenyl, or aralkyl, in particular benzyl, which can be substituted one to three times with C1-C8alkyl, C1-C8alkoxy, or halogen, Y is -C(O)-, -C(O)O-, -C(O)NH-, -SO2NH- or -SO2- and R is C1-Cl8alkyl, Ar , or aralkyl. The furopyrroles of the general formula (I) can be obtained in high yield and high purity by the process of the present invention.

    Abstract translation: 本发明涉及一种制备通式(I)的呋喃并吡咯的方法,其包括(a)在微波辐射下任选地在惰性溶剂存在下加热式(II)化合物,其中A 1, 和A 2是C 1 -C 18烷基,C 2 -C 18烯基,C 2 -C 18炔基,C 5 -C 8环烷基,C 5 -C 8环烯基,芳基或杂芳基,A 3是氢,C 1 -C 18烷基,氰甲基,Ar 3, R 31 - (CH 2)m -Ar 3或Y-R 32,其中R 30和R 31彼此独立地代表氢或C 1 -C 4烷基 或可以被C 1 -C 4烷基取代三次的苯基,Ar 3代表芳基,C 5 -C 8烷基,C 5 -C 8环烯基或杂芳基,其可以被C 1 -C 8烷基,C 1 -C 8烷基取代一至三次 C 1-8烷氧基,卤素或苯基,其可以被C 1 -C 8烷基或C 1 -C 8烷氧基取代一至三次,m代表0,1,2,3或4,R是C 1 -C 18烷基,特别是C 1 -C 4烷基, 芳基,特别是苯基或芳烷基,特别是苄基, 可以用C 1 -C 8烷基,C 1 -C 8烷氧基或卤素取代一至三次,Y是-C(O) - , - C(O)O-,-C(O)NH-,-SO 2 NH-或 - SO 2 - 和R 32是C 1 -C 8烷基,Ar 3或芳烷基。 通过本发明的方法可以高产率和高纯度获得通式(I)的呋喃并吡咯。

    PROCESS FOR THE PREPARATION OF FUROPYRROLES
    8.
    发明申请
    PROCESS FOR THE PREPARATION OF FUROPYRROLES 审中-公开
    制备呋喃甲醇的方法

    公开(公告)号:WO2005005430A2

    公开(公告)日:2005-01-20

    申请号:PCT/EP2004/051259

    申请日:2004-06-28

    CPC classification number: C07D487/04 C07D491/04

    Abstract: The present invention relates to a process for the preparation of furopyrroles of the general formula (I), comprising (a) heating a compound of the formula (II) under microwave irradiation optionally in the presence of an inert solvent, wherein A 1 and A 2 are C l -C 18 alkyl, C 2 -C l8 alkenyl, C 2 -C l8 alkynyl, C 5 -C 8 cycloalkyl, C 5- C 8 cycloalkenyl, aryl or heteroaryl, A 3 is hydrogen, C 1 -C 18 alkyl, cyanomethyl, Ar 3 ,-CR 30 R 31 -(CH 2 ) m -Ar 3 or Y- R 32 , wherein R 30 and R 31 independently of each other stand for hydrogen or C 1 -C 4 alkyl, or phenyl which can be substituted up to three times with C 1 -C 4 alkyl, Ar 3 stands for aryl, C 5 -C 8 cloalkyl, C 5 -C 8 cycloalkenyl or heteroaryl, which can be substituted one to three times with C 1 -C 8 alkyl, C 1 -C 8 alkoxy, halogen or phenyl, which can be substituted with C 1 -C 8 alkyI or C 1 -C 8 alkoxy one to three times, and m stands for 0, 1, 2, 3 or 4, R is C 1 -C 18 alkyl, in particular C 1 -C 4 alkyl, aryl, in particular phenyl, or aralkyl, in particular benzyl, which can be substituted one to three times with C 1 -C 8 alkyl, C 1 -C 8 alkoxy, or halogen, Y is -C(O)-, -C(O)O-, -C(O)NH-, -SO 2 NH- or -SO 2 - and R 32 is C 1 -C l8 alkyl, Ar 3 , or aralkyl. The furopyrroles of the general formula (I) can be obtained in high yield and high purity by the process of the present invention.

    Abstract translation: 本发明涉及制备通式(I)呋喃并呋喃的方法,其包括(a)在微波辐射下任选地在存在下式(II)的情况下加热式 惰性溶剂,其中A 1和A 2是C 1 -C 18烷基,C≡2 -C≡C8烯基,C≡C12炔基,C≡C-sub C8-C8环烯基,芳基或杂芳基,A 3是氢,C 1 -C 8环烷基,C 5 -C 8环烯基,芳基或杂芳基,A 3是氢,C≡1 C18烷基,氰甲基,Ar 3,-CR 30 R 31 - (CH 3) - , - CH 2),或者Y-R <32>,或者Y-R <32> 其中R 30和R 31彼此独立地代表氢或C 1 -C 4 - / - ,其中R 30和R 31彼此独立地代表氢或C 1 -C 4 - 烷基或可被C 1 -C 4烷基取代至多三次的苯基,Ar 3代表芳基,C 1 -C 4烷基, 低于5-C 8 cloa C 1 -C 8 - 环烯基或杂芳基,其可以被C 1 -C 8取代1-3次, C 1-8烷基,C 1 -C 8烷氧基,卤素或可被C 1 -C 8取代的苯基 烷基或C 1 -C 8烷氧基取代1-3次,m代表0,1,2,3或4,R是C

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