公开(公告)号：WO2008002889A3

公开(公告)日：2008-03-27

申请号：PCT/US2007072071

申请日：2007-06-26

Applicant: GEN ELECTRIC ,  CHAN KWOK PONG ,  HAGBERG ERIK ,  MULLEN TARA J ,  ODLE ROY RAY ,  WHITE JAMES MITCHELL ,  YAMAGUCHI NORIMITSU

Inventor： CHAN KWOK PONG ,  HAGBERG ERIK ,  MULLEN TARA J ,  ODLE ROY RAY ,  WHITE JAMES MITCHELL ,  YAMAGUCHI NORIMITSU

IPC: C08K9/04 ,  C08J5/10 ,  C08J5/18 ,  C08K3/34 ,  C08K5/18 ,  C08K5/19 ,  C08K5/3432 ,  C08K5/50 ,  C08L71/00 ,  C08L79/08 ,  C08L81/04 ,  C08L81/06

CPC classification number: C08J3/201 ,  B82Y30/00 ,  C01B33/44 ,  C08J5/005 ,  C08K3/346 ,  C08K5/50 ,  C08K9/04

Abstract: This invention relates to organic salt compositions useful in the preparation of organoclay compositions, polymer-organoclay composite compositions, and methods for the preparation of polymer nanocomposites. In one embodiment, the present invention provides a method of making a polymer-organoclay composite composition, said method comprising melt mixing a quaternary organoclay composition comprising alternating inorganic silicate layers and organic layers, said organic layers comprising a quaternary organic cation with a polymeric resin comprising at least one polymer selected from the group consisting of polyamides, polyesters, polyarylene sulfides, polyarylene ethers, polyether sulfones, polyether ketones, polyether ether ketones, polyphenylenes, and polyphenylenes said polymeric resin being substantially free of polyetherimides; said melt mixing being carried out at a temperature in a range between about 300 °C and about 450 °C to provide a polymer-organoclay composite composition, said polymer-organoclay composite composition being characterized by a percent exfoliation of at least 10 percent.

Abstract translation: 本发明涉及可用于制备有机粘土组合物，聚合物 - 有机粘土复合材料组合物和制备聚合物纳米复合材料的方法的有机盐组合物。 在一个实施方案中，本发明提供了制备聚合物 - 有机粘土复合材料组合物的方法，所述方法包括熔融混合包含交替的无机硅酸盐层和有机层的季有机粘土组合物，所述有机层包含季铵有机阳离子与聚合树脂， 选自聚酰胺，聚酯，聚亚芳基硫醚，聚亚芳基醚，聚醚砜，聚醚酮，聚醚醚酮，聚苯和聚苯的至少一种聚合物，所述聚合物树脂基本上不含聚醚酰亚胺; 所述熔体混合在约300℃至约450℃之间的温度下进行，以提供聚合物 - 有机粘土复合材料组合物，所述聚合物 - 有机粘土复合组合物的特征在于至少10％的剥离百分比。

公开(公告)号：WO2008002870A3

公开(公告)日：2008-02-28

申请号：PCT/US2007072019

申请日：2007-06-25

Applicant: GEN ELECTRIC ,  CHAN KWOK PONG ,  ODLE ROY RAY ,  HALL DAVID BRUCE ,  MAXAM JOHN LESTER ,  STELLA ALBERT SANTO ,  GENOVESE SARAH ELIZABETH ,  MULLEN TARA J ,  WHITE JAMES MITCHELL ,  HAGBERG ERIK

Inventor： CHAN KWOK PONG ,  ODLE ROY RAY ,  HALL DAVID BRUCE ,  MAXAM JOHN LESTER ,  STELLA ALBERT SANTO ,  GENOVESE SARAH ELIZABETH ,  MULLEN TARA J ,  WHITE JAMES MITCHELL ,  HAGBERG ERIK

IPC: C08F2/44 ,  C08K3/34 ,  C08K5/19 ,  C08K5/3432 ,  C08K5/50 ,  C08K9/04 ,  C08L79/08

CPC classification number: C08F2/44

Abstract: A method for preparing a polymer-organoclay composite composition comprises combining a solvent and an unexfoliated organoclay to provide a first mixture, wherein the unexfoliated organoclay comprises alternating inorganic silicate layers and organic layers, and has an initial spacing between the silicate layers; exposing the first mixture to an energized condition of a sufficient intensity and duration to increase the initial spacing of the inorganic silicate layers, to provide a second mixture; contacting the second mixture with a polymer composition so that the polymer composition fills at least one region located between at least one pair of silicate layers, wherein the polymer composition is at least partially soluble in the solvent; and removing at least a portion of the solvent from the second mixture, wherein the inorganic silicate layers remain separated by the polymer after removal of the solvent.

Abstract translation: 一种制备聚合物 - 有机粘土复合材料组合物的方法，包括将溶剂和未剥离的有机粘土组合以提供第一混合物，其中未剥离的有机粘土包含交替的无机硅酸盐层和有机层，并且在硅酸盐层之间具有初始间隔; 将第一混合物暴露于足够强度和持续时间的通电状态以增加无机硅酸盐层的初始间隔，以提供第二混合物; 使所述第二混合物与聚合物组合物接触，使得所述聚合物组合物填充位于至少一对硅酸盐层之间的至少一个区域，其中所述聚合物组合物至少部分地可溶于所述溶剂中; 以及从所述第二混合物中除去至少一部分所述溶剂，其中在去除所述溶剂之后，所述无机硅酸盐层保持被所述聚合物分离。

公开(公告)号：WO2008039577A3

公开(公告)日：2008-12-04

申请号：PCT/US2007071205

申请日：2007-06-14

Applicant: SABIC INNOVATIVE PLASTICS IP ,  CHAN KWOK PONG ,  HAGBERG ERIK ,  MULLEN TARA J ,  ODLE ROY RAY

Inventor： CHAN KWOK PONG ,  HAGBERG ERIK ,  MULLEN TARA J ,  ODLE ROY RAY

IPC: C08K3/08 ,  B32B5/18 ,  B32B27/32 ,  B44C5/04 ,  C08J5/18 ,  C08K5/134 ,  C08K13/02 ,  C08L79/08 ,  C23C18/54 ,  H05K9/00

CPC classification number: H05K1/0346 ,  B82Y30/00 ,  C08G73/1007 ,  C08J5/005 ,  C08J5/18 ,  C08J2379/08 ,  H05K1/0373 ,  H05K2201/0154 ,  H05K2201/0209 ,  H05K2201/0257 ,  H05K2201/068

Abstract: A solvent cast film comprises a polyimide comprising structural units derived from polymerization of a dianhydride component comprising a dianhydride selected from the group consisting of 3,4'-oxydiphthalic dianhydride, 3,3'-oxydiphthalic dianhydride, 4,4'-oxydiphthalic dianhydride, and combinations thereof, with a diamine component wherein the polyimide has a glass transition temperature of at least 190°C; wherein the film has a coefficient of thermal expansion of less than 60 ppm/°C, a thickness from 0.1 to 250 micrometers, and less than 5% residual solvent by weight; wherein the polyimide has less than 15 molar % of structural units derived from a member selected from the group consisting of biphenyltetracarboxylic acid, a dianhydride of biphenyltetracarboxylic acid, an ester of biphenyltetracarboxylic acid, and a combination thereof.

Abstract translation: 溶剂流延膜包含聚酰亚胺，所述聚酰亚胺包含衍生自包含选自3,4'-氧二邻苯二甲酸二酐， 以及它们的组合，其中所述聚酰亚胺具有至少190℃的玻璃化转变温度; 其中所述膜具有小于60ppm /℃的热膨胀系数，0.1-250微米的厚度和小于5重量％的残留溶剂; 其中所述聚酰亚胺具有小于15摩尔％的衍生自选自联苯四羧酸，联苯四羧酸的二酐，联苯四羧酸的酯及其组合的成员的结构单元。

公开(公告)号：WO2008060712A2

公开(公告)日：2008-05-22

申请号：PCT/US2007/071217

申请日：2007-06-14

Applicant: GENERAL ELECTRIC COMPANY ,  CHAN, Kwok, Pong ,  HAGBERG, Erik ,  MULLEN, Tara, J. ,  ODLE, Roy, Ray

Inventor： CHAN, Kwok, Pong ,  HAGBERG, Erik ,  MULLEN, Tara, J. ,  ODLE, Roy, Ray

CPC classification number: H05K1/0346 ,  B29B17/0042 ,  B29B17/0404 ,  B29K2079/08 ,  B29L2007/008 ,  B32B15/08 ,  C08G73/1007 ,  C08J5/18 ,  C08J2379/08 ,  C08L79/08 ,  H05K1/0373 ,  H05K2201/0154 ,  H05K2201/0209 ,  H05K2201/0257 ,  H05K2201/068 ,  Y02W30/62 ,  Y02W30/625 ,  Y10T428/12569 ,  Y10T428/25 ,  Y10T428/2938 ,  Y10T428/31678 ,  Y10T428/31681 ,  Y10T428/31721 ,  Y10T428/31765

Abstract: A solvent cast film comprises a polyimide comprising structural units derived from polymerization of a dianhydride component comprising a dianhydride selected from the group consisting of 3,4'-oxydiphthalic dianhydride, 3,3'-oxydiphthalic dianhydride, 4,4'-oxydiphthalic dianhydride, and combinations thereof, with a diamine component comprising 4,4'-diaminodiphenylsulfone; wherein the polyimide has a glass transition temperature from 190°C to 400°C; and wherein the film has a coefficient of thermal expansion of less than 60 ppm/°C, a thickness from 0.1 to 250 micrometers, endless than 5% residual solvent by weight.

Abstract translation: 溶剂流延膜包括聚酰亚胺，其包含衍生自二酐组分的聚合的结构单元，所述二酐组分包含二酐，其选自3,4'-氧二邻苯二甲酸二酐，3,3'-氧联二邻苯二甲酸二酐，4,4'-氧联二邻苯二甲酸二酐， 和其组合与二胺组分包含4,4'-二氨基二苯砜; 其中所述聚酰亚胺的玻璃化转变温度为190℃至400℃; 并且其中所述膜具有小于60ppm /℃的热膨胀系数，0.1至250微米的厚度，不超过5重量％的残留溶剂。

公开(公告)号：WO2008060710A2

公开(公告)日：2008-05-22

申请号：PCT/US2007/071203

申请日：2007-06-14

Applicant: GENERAL ELECTRIC COMPANY ,  CHAN, Kwok, Pong ,  HAGBERG, Erik ,  MULLEN, Tara, J. ,  ODLE, Roy, Ray

Inventor： CHAN, Kwok, Pong ,  HAGBERG, Erik ,  MULLEN, Tara, J. ,  ODLE, Roy, Ray

CPC classification number: H05K1/0346 ,  B32B15/08 ,  C08G73/1007 ,  C08J5/18 ,  C08J2379/08 ,  C08K3/346 ,  C08L79/08 ,  H05K2201/0154 ,  H05K2201/068 ,  Y10T428/12569 ,  Y10T428/2938 ,  Y10T428/31765

Abstract: An article comprises a solvent cast film comprising a polyetherimide comprising structural units derived from a dianhydride component selected from the group consisting of 3,4'-oxydiphthalic anhydride, 3,3'-oxydiphthalic anhydride, 4,4'- oxydiphthalic anhydride, and combinations thereof, and a diamine component. The polyetherimide has a glass transition temperature that is at least 1900C. The film has a coefficient of thermal expansion of less than 60 ppm/°C, a thickness from 0.1 to 250 micrometers, and less than 5% residual solvent by weight. The film has less than 15 molar % of a member selected from the group consisting of biphenyltetracarboxylic acid, dianhydrides of biphenyltetracarboxylic acid, esters of biphenyltetracarboxylic acid, and combinations thereof.

Abstract translation: 一种制品包括含有聚醚酰亚胺的溶剂流延薄膜，该聚醚酰亚胺包含衍生自二酐组分的结构单元，所述二酐组分选自3,4'-氧联二邻苯二甲酸酐，3,3'-氧联二邻苯二甲酸酐，4,4'-氧联二邻苯二甲酸酐和组合 和二胺组分。 聚醚酰亚胺的玻璃化转变温度至少为190℃。 该膜具有小于60ppm /℃的热膨胀系数，0.1至250微米的厚度和小于5重量％的残留溶剂。 该膜具有少于15摩尔％的选自联苯四羧酸，联苯四羧酸的二酐，联苯四羧酸的酯及其组合的成员。

公开(公告)号：WO2008002891A2

公开(公告)日：2008-01-03

申请号：PCT/US2007072073

申请日：2007-06-26

Applicant: GEN ELECTRIC ,  CAO FENG ,  CHAN KWOK PONG ,  HAGBERG ERIK ,  KHOURI FARID FOUAD ,  MULLEN TARA J ,  ODLE ROY RAY ,  WHITE JAMES MITCHELL ,  YAMAGUCHI NORIMITSU

Inventor： CAO FENG ,  CHAN KWOK PONG ,  HAGBERG ERIK ,  KHOURI FARID FOUAD ,  MULLEN TARA J ,  ODLE ROY RAY ,  WHITE JAMES MITCHELL ,  YAMAGUCHI NORIMITSU

IPC: C08F2/44 ,  C08K3/34 ,  C08K5/17 ,  C08K5/50 ,  C08K9/04 ,  C08L79/08

CPC classification number: C08F2/44

Abstract: In one embodiment, the present invention provides a method of making a polymer- organoclay composite composition comprising (a) contacting under condensation polymerization conditions a first monomer, a second monomer, a solvent, and an organoclay composition, said organoclay composition comprising alternating inorganic silicate layers and organic layers, to provide a first polymerization reaction mixture, wherein one of said first monomer and second monomers is a diamine and the the other is an dianhydride; (b) carrying out a stoichiometry verification step on the first polymerization reaction mixture; (c) optionally adding additional reactant (monomer 1, monomer 2, or chainstopper) to the first polymerization reaction mixture to provide a second polymerization reaction mixture; and (d) removing solvent from the first polymerization reaction mixture or the second polymerization reaction mixture to provide a first polymer-organoclay composite composition comprising a polymer component and an organoclay component wherein the organoclay component is at least 10% exfoliated.

Abstract translation: 在一个实施方案中，本发明提供制备聚合物 - 有机粘土复合组合物的方法，其包括（a）在缩聚条件下使第一单体，第二单体，溶剂和有机粘土组合物接触，所述有机粘土组合物包含交替的无机硅酸盐 层和有机层，以提供第一聚合反应混合物，其中所述第一单体和第二单体之一是二胺，另一个是二酐; （b）在第一聚合反应混合物上进行化学计量验证步骤; （c）任选地向第一聚合反应混合物中加入另外的反应物（单体1，单体2或链闭锁剂）以提供第二聚合反应混合物; （d）从第一聚合反应混合物或第二聚合反应混合物中除去溶剂，以提供包含聚合物组分和有机粘土组分的第一聚合物 - 有机粘土复合组合物，其中有机粘土组分至少10％剥离。

公开(公告)号：WO2008002890A2

公开(公告)日：2008-01-03

申请号：PCT/US2007/072072

申请日：2007-06-26

Applicant: GENERAL ELECTRIC COMPANY ,  CHAN, Kwok, Pong ,  CROLL, Joshua, McClellan ,  HAGBERG, Erik ,  MAXAM, John, Lester ,  MULLEN, Tara, J. ,  ODLE, Roy, Ray ,  SUFFIELD, Rachel, Marie ,  WHITE, James, Mitchell ,  YAMAGUCHI, Norimitsu

Inventor： CHAN, Kwok, Pong ,  CROLL, Joshua, McClellan ,  HAGBERG, Erik ,  MAXAM, John, Lester ,  MULLEN, Tara, J. ,  ODLE, Roy, Ray ,  SUFFIELD, Rachel, Marie ,  WHITE, James, Mitchell ,  YAMAGUCHI, Norimitsu

CPC classification number: C08J5/18 ,  C08J3/201 ,  C08J5/10 ,  C08J2379/08 ,  C08K3/346 ,  C08K5/18 ,  C08K5/19 ,  C08K5/3432 ,  C08K5/50 ,  C08K9/04

Abstract: This invention relates to organic salt compositions useful in the preparation of organoclay compositions, polymer-organoclay composite compositions, and methods for the preparation of polymer nanocomposites. In one embodiment, the present invention provides a method of making a polymer-organoclay composite composition, said method comprising melt mixing a quaternary organoclay composition comprising alternating inorganic silicate layers and organic layers, said organic layers comprising a quaternary organic cation with a polyetherimide composition; said melt mixing being carried out at a temperature in a range between about 300°C and about 450°C to provide a polymer-organoclay composite composition, said polymer-organoclay composite composition being characterized by a percent exfoliation of at least 10 percent.

Abstract translation: 本发明涉及可用于制备有机粘土组合物，聚合物 - 有机粘土复合材料组合物和制备聚合物纳米复合材料的方法的有机盐组合物。 在一个实施方案中，本发明提供了制备聚合物 - 有机粘土复合材料组合物的方法，所述方法包括熔融混合包含交替的无机硅酸盐层和有机层的季有机粘土组合物，所述有机层包含季铵有机阳离子与聚醚酰亚胺组合物; 所述熔体混合在约300℃至约450℃之间的温度下进行，以提供聚合物 - 有机粘土复合材料组合物，所述聚合物 - 有机粘土复合组合物的特征在于至少10％的剥离百分比。

公开(公告)号：WO2008002888A3

公开(公告)日：2008-01-03

申请号：PCT/US2007/072070

申请日：2007-06-26

Applicant: GENERAL ELECTRIC COMPANY ,  CHAN, Kwok, Pong ,  CROLL, Joshua, McClellan ,  GANESAN, Balakrishnan ,  HAGBERG, Erik ,  HARRIGAN, Marcus ,  KHOURI, Farid, Fouad ,  KISHAN, Gurram ,  MATHUR, Ritesh ,  MAXAM, John, Lester ,  MULLEN, Tara, J. ,  ODLE, Roy, Ray ,  RANGANATHAN, Sathish, Kumar ,  SUFFIELD, Rachel, Marie ,  WANG, Wenhui ,  WHITE, James, Mitchell

Inventor： CHAN, Kwok, Pong ,  CROLL, Joshua, McClellan ,  GANESAN, Balakrishnan ,  HAGBERG, Erik ,  HARRIGAN, Marcus ,  KHOURI, Farid, Fouad ,  KISHAN, Gurram ,  MATHUR, Ritesh ,  MAXAM, John, Lester ,  MULLEN, Tara, J. ,  ODLE, Roy, Ray ,  RANGANATHAN, Sathish, Kumar ,  SUFFIELD, Rachel, Marie ,  WANG, Wenhui ,  WHITE, James, Mitchell

IPC: C08K3/34 ,  C08K5/50 ,  C08K9/04 ,  C08L79/08

Abstract: This invention relates to organic salt compositions useful in the preparation of organoclay compositions, polymer-organoclay composite compositions, and methods for the preparation of polymer nanocomposites. In one embodiment, the present invention provides a polymer-organoclay composite composition comprising (a) a polymeric resin; and (b) an organoclay composition comprising alternating inorganic silicate layers and organic layers, said organic layers comprising a quaternary phosphonium cation having structure X wherein Ar 1 , Ar 2 , and Ar 3 are independently C 2 -C 50 aromatic radicals; Ar 4 is a bond or a C 2 -C 50 aromatic radical; "a" is a number from 1 to about 200; "c" is a number from 0 to 3; R 1 is independently at each occurrence a halogen atom, a C 1 -C 20 aliphatic radical, a C 5 -C 20 cycloaliphatic radical, or a C 2 -C 20 aromatic radical; and R 2 is a halogen atom, a C 1 -C 20 aliphatic radical, a C 5 -C 20 cycloaliphatic radical, a C 2 -C 50 aromatic radical, or a polymer chain.

公开(公告)号：WO2012065114A3

公开(公告)日：2012-07-19

申请号：PCT/US2011060450

申请日：2011-11-11

Applicant: SEGETIS INC ,  MULLEN BRIAN D ,  SCHOLTEN MARC D ,  LEIBIG CORA M ,  MULLEN TARA J ,  BADARINARAYANA VIVEK

Inventor： MULLEN BRIAN D ,  SCHOLTEN MARC D ,  LEIBIG CORA M ,  MULLEN TARA J ,  BADARINARAYANA VIVEK

IPC: C08G63/42 ,  C07D407/04 ,  C07D493/10 ,  C08L59/00 ,  C08L67/02

CPC classification number: C07D407/12 ,  C08K5/1565 ,  C08L59/02 ,  C08L77/00 ,  C08L79/08 ,  Y02P20/582 ,  C08L27/06

Abstract: Disclosed herein is a polyketal adduct obtained by forming an ester between a hydrocarbon polyol and a ketocarboxylic acid to produce an intermediate polyketocarboxylic ester. The intermediate polyketocarboxylic ester can be purified via crystallization to achieve purities of greater than 99.0% and then ketalized to produce the polyketal adduct, which can be used in polymer compositions. The polyketal adduct I is obtained at high purity and at high yield.

Abstract translation: 本文公开了通过在烃多元醇与酮基羧酸之间形成酯以产生中间体聚酮羧酸酯而获得的聚缩酮加合物。 中间体聚酮羧酸酯可通过结晶纯化以达到大于99.0％的纯度，然后缩酮化以制备可用于聚合物组合物中的聚缩酮加合物。 以高纯度和高收率获得聚缩酮加合物I.

公开(公告)号：WO2012065114A2

公开(公告)日：2012-05-18

申请号：PCT/US2011/060450

申请日：2011-11-11

Applicant: SEGETIS, INC. ,  MULLEN, Brian, D. ,  SCHOLTEN, Marc, D. ,  LEIBIG, Cora, M. ,  MULLEN, Tara, J. ,  BADARINARAYANA, Vivek

Inventor： MULLEN, Brian, D. ,  SCHOLTEN, Marc, D. ,  LEIBIG, Cora, M. ,  MULLEN, Tara, J. ,  BADARINARAYANA, Vivek

IPC: C08G63/42 ,  C08L67/02 ,  C08L59/00 ,  C07D407/04 ,  C07D493/10

CPC classification number: C07D407/12 ,  C08K5/1565 ,  C08L59/02 ,  C08L77/00 ,  C08L79/08 ,  Y02P20/582 ,  C08L27/06

Abstract: Disclosed herein is a polyketal adduct obtained by forming an ester between a hydrocarbon polyol and a ketocarboxylic acid to produce an intermediate polyketocarboxylic ester. The intermediate polyketocarboxylic ester can be purified via crystallization to achieve purities of greater than 99.0% and then ketalized to produce the polyketal adduct, which can be used in polymer compositions. The polyketal adduct I is obtained at high purity and at high yield.

Abstract translation: 本文公开了通过在烃多元醇和酮羧酸之间形成酯以产生中间体多酮羧酸酯而获得的聚缩酮加成物。 可以通过结晶纯化中间体多酮羧酸酯以实现大于99.0％的纯度，然后缩醛化以产生可用于聚合物组合物中的聚缩酮加合物。 以高纯度和高收率获得聚缩酮加成物I.