公开(公告)号：WO1986006392A1

公开(公告)日：1986-11-06

申请号：PCT/JP1986000199

申请日：1986-04-18

Applicant: NIPPON GOHSEI KAGAKU KOGYO KABUSHIKI KAISHA ,  HASEGAWA, Kenji ,  SATO, Tetsuo ,  IWANAMI, Teruo

Inventor： NIPPON GOHSEI KAGAKU KOGYO KABUSHIKI KAISHA

IPC: C08J07/04

CPC classification number: C08J7/047 ,  C08J2367/02 ,  C08J2429/04 ,  Y10T428/1379

Abstract: An anchor coat layer is formed on a polyester molding before coating it with a solution of a vinyl alcohol resin having excellent gas barrier properties, by coating the surface of said molding with a solution in a solvent of a polyester of the following formulation having a limiting viscosity of 0.4 or more: acid component: terephthalic and/or isophthalic acid 90 to 40 mol %; aliphatic dicarboxylic acid containing 2 to 12 carbon atoms 10 to 60 mol %; diol component: straight-chain or cyclic diol containing 2 to 8 carbon atoms 90 to 10 mol %; branched diol containing 3 to carbon atoms 10 to 90 mol %. Thus, a polyester molding with excellent gas barrier properties can be obtained.

Abstract translation: 在聚酯模塑件上形成锚固涂层之后，用具有优异阻气性的乙烯醇树脂的溶液涂覆所述模制品的表面，在具有限制性的以下配方的聚酯的溶剂中涂布溶液 粘度为0.4以上：酸成分：对苯二甲酸和/或间苯二甲酸90〜40摩尔％ 含有2〜12个碳原子的脂肪族二羧酸10〜60摩尔％ 二醇成分：含有2〜8个碳原子的直链或环状二醇90〜10摩尔％ 含有3〜碳原子的支链二醇10〜90摩尔％。 因此，可以获得具有优异阻气性的聚酯模制品。

公开(公告)号：WO1998044044A1

公开(公告)日：1998-10-08

申请号：PCT/JP1997001118

申请日：1997-04-01

Applicant: NIPPON GOHSEI KAGAKU KOGYO KABUSHIKI KAISHA ,  SHIBUTANI, Mitsuo

Inventor： NIPPON GOHSEI KAGAKU KOGYO KABUSHIKI KAISHA

IPC: C08L29/04

CPC classification number: C08L29/04 ,  C08F2/20 ,  C08F8/12 ,  C08F2800/10 ,  C08J5/18 ,  C08F218/08 ,  C08F2216/1433 ,  C08F222/10 ,  C08F220/58 ,  C08F228/04 ,  C08F222/02 ,  C08F228/02 ,  C08F226/06

Abstract: A highly stable aqueous solution of a partially saponified vinyl ester resin, which contains a partially saponified vinyl ester resin with a degree of saponification of 70 mol% or below in a concentration of 50 % by weight or below and has at a concentration of 30 % by weight a cloud point y ( DEG C) satisfying the formula: 1ny > 0.042x + 1.0 wherein x represents the degree of saponification (mol%). This solution is highly useful, in particular, as a dispersion auxiliary for use in a suspension polymerization of vinyl compounds.

Abstract translation: 一种高度稳定的部分皂化乙烯基酯树脂的水溶液，其含有浓度为50重量％以下，皂化度为70摩尔％以下，浓度为30重量％的部分皂化乙烯基酯树脂， 重量的满足以下公式的浊点y（℃）：1ny> 0.042x + 1.0其中x表示皂化度（mol％）。 该溶液是非常有用的，特别是作为用于乙烯基化合物的悬浮聚合的分散助剂。

公开(公告)号：WO1994024171A1

公开(公告)日：1994-10-27

申请号：PCT/JP1993001371

申请日：1993-09-24

Applicant: NIPPON GOHSEI KAGAKU KOGYO KABUSHIKI KAISHA ,  MIYAKE, Shinji ,  FUJITA, Junko ,  TAKIDA, Hiroshi

Inventor： NIPPON GOHSEI KAGAKU KOGYO KABUSHIKI KAISHA

IPC: C08F08/06

CPC classification number: C08J7/04 ,  C08F8/06 ,  C08F2800/10 ,  C08F216/06

Abstract: An oxidized polymer solution is produced by oxidizing a saponified ethylene-vinyl acetate copolymer in solution in a solvent mixture comprising water and an alcohol in the presence of a salt of a multivalent metal. A laminate is produced by coating a base material such as a polymer film with the polymer solution.

Abstract translation: 通过在多价金属盐的存在下，在包含水和醇的溶剂混合物的溶液中氧化皂化的乙烯 - 乙酸乙烯酯共聚物来制备氧化聚合物溶液。 通过用聚合物溶液涂覆诸如聚合物膜的基材来制备层压体。

公开(公告)号：WO1992020739A1

公开(公告)日：1992-11-26

申请号：PCT/JP1992000633

申请日：1992-05-15

Applicant: NIPPON GOHSEI KAGAKU KOGYO KABUSHIKI KAISHA ,  UEMURA, Tomoyoshi ,  AKAMATSU, Yoshimi ,  YOSHIDA, Yuichi ,  MORIWAKI, Yoshikazu

Inventor： NIPPON GOHSEI KAGAKU KOGYO KABUSHIKI KAISHA

IPC: C08L03/00

CPC classification number: B32B27/08 ,  B32B25/08 ,  B32B25/12 ,  B32B27/22 ,  B32B27/30 ,  B32B27/306 ,  B32B27/32 ,  B32B2307/7163 ,  B32B2307/718 ,  C08L3/02 ,  C08L29/04 ,  C08L2201/06 ,  Y10T428/31692 ,  Y10T428/31855 ,  Y10T428/3188 ,  Y10T428/31895 ,  Y10T428/31906 ,  Y10T428/31909 ,  Y10T428/31913 ,  Y10T428/31928 ,  Y10T442/20 ,  Y10T442/2025 ,  C08L2666/02 ,  C08L2666/26

Abstract: A biodegradable resin composition comprising a saponified ethylene/vinyl acetate copolymer and a starch, wherein the copolymer has an ethylene content of 20 to 60 mole %, a degree of saponification of the vinyl acetate units of 90 mole % or above, a melt flow index of 1 to 100 g/10 min at 210 °C under a 2,160 g load, and an θ60 to θ5 ratio of 0.5 to 4, wherein θ60 is the melt viscosity of the sample kept at 250 °C for 60 min and θ5 is the one at 250 °C for 5 min. The layer of this composition can form a laminated structure with another material such as a photodegradable polymer.

公开(公告)号：WO1986005191A1

公开(公告)日：1986-09-12

申请号：PCT/JP1985000114

申请日：1985-03-06

Applicant: NIPPON GOHSEI KAGAKU KOGYO KABUSHIKI KAISHA ,  MARUHASHI, Motokazu ,  OHNISHI, Kizo

Inventor： NIPPON GOHSEI KAGAKU KOGYO KABUSHIKI KAISHA

IPC: C08F02/20

CPC classification number: C08F2/20 ,  C08L29/04 ,  C08L2205/02 ,  C08L2666/04

Abstract: A dispersion stabilizer comprising (A) a polyvinyl alcohol resin containing oxyalkylene groups and having a surface tension of 35 to 55 dyne/cm at 20oC as a 1 wt % aqueous solution and, if necessary, (B) a water-soluble polymer or a lowly saponified, lowly polymerized polyvinyl alcohol resin. This dispersion stabilizer can improve a void ratio of the polyvinyl resin particles and raise a bulk density thereof and, in addition, improve uniformity of the particle size distribution and void ratio.