FLUORINATED POLYFUNCTIONAL (METH)ACRYLIC ESTERS, FLUOROMONOMER COMPOSITION, MATERIAL WITH LOW REFRACTIVE INDEX, AND LOWLY REFLECTIVE FILM
    1.
    发明申请
    FLUORINATED POLYFUNCTIONAL (METH)ACRYLIC ESTERS, FLUOROMONOMER COMPOSITION, MATERIAL WITH LOW REFRACTIVE INDEX, AND LOWLY REFLECTIVE FILM 审中-公开
    氟化多官能(甲基)丙烯酸酯,荧光体组合物,具有低折射率的材料和低反射膜

    公开(公告)号:WO1997030021A1

    公开(公告)日:1997-08-21

    申请号:PCT/JP1997000356

    申请日:1997-02-12

    Inventor: NOF CORPORATION

    Abstract: Fluorinated polyfunctional (meth)acrylic esters represented by general formula (1), a fluoromonomer composition containing the same, a material with a low refractive index obtained by curing the monomer composition, and a lowly reflective film comprising the material with a low refractive index wherein: R , R , R , and R are the same or different and each represents hydrogen, acryloyl, or methacryloyl, provided that at least either R or R and at least either R or R represent each acryloyl or methacryloyl; and R represents C2-12 fluoroalkylene having two or more fluorine atoms.

    Abstract translation: 由通式(1)表示的氟化多官能(甲基)丙烯酸酯,含有它们的含氟单体组合物,通过固化单体组合物获得的具有低折射率的材料,以及低折射率材料的低反射膜,其中 :R 1,R 2,R 3和R 4相同或不同,各自表示氢,丙烯酰基或甲基丙烯酰基,条件是R 1或R 2中的至少一个为 且R 3或R 4中的至少任一个表示每个丙烯酰基或甲基丙烯酰基; R表示具有2个以上氟原子的C2-12氟代亚烷基。

    PROCESS FOR PRODUCING AN AQUEOUS SOLUTION OF PHOSPHORYLCHOLINE GROUP BEARING POLYMER AND AQUEOUS SOLUTION OF PHOSPHORYLCHOLINE GROUP BEARING POLYMER
    2.
    发明申请
    PROCESS FOR PRODUCING AN AQUEOUS SOLUTION OF PHOSPHORYLCHOLINE GROUP BEARING POLYMER AND AQUEOUS SOLUTION OF PHOSPHORYLCHOLINE GROUP BEARING POLYMER 审中-公开
    生产聚合物基团聚合物的聚苯乙烯类聚合物的水溶液和磷酸酯基团聚合物的水溶液的方法

    公开(公告)号:WO1996031566A1

    公开(公告)日:1996-10-10

    申请号:PCT/JP1996000894

    申请日:1996-04-02

    CPC classification number: C08F6/06 C08F6/003 C08F30/02

    Abstract: A process for producing an aqueous solution of a phosphorylcholine group bearing polymer, comprising polymerizing a polymerizable composition containing a phosphorylcholine group bearing monomer of general formula (1) in the presence of a nonmetallic polymerization initiator soluble in a water-containing medium to obtain a crude aqueous solution of a polymer and purifying the solution by the use of a separation membrane; and an aqueous solution of a phosphorycholine group bearing polymer produced by this process and having an impurity content of 2000 ppm. or below (X: a divalent organic residue; Y: C1-C6 alkyleneoxy; Z: H or R -O-CO- (R : C1-C10 alkyl or C1-C10 hydroxyalkyl); R : H or CH3; R , R and R : H, C1-C6 hydrocarbyl or hydroxylated hydrocarbyl; and m: 0 or 1).

    Abstract translation: 一种含磷酰胆碱基聚合物的水溶液的制造方法,其特征在于,在可溶于含水介质的非金属聚合引发剂的存在下,使含有磷酸胆碱基的单体通式(1)的聚合性组合物聚合,得到粗品 聚合物的水溶液,并通过使用分离膜纯化溶液; 和通过该方法制造并具有2000ppm杂质含量的含磷酸基团的聚合物的水溶液。 或以下(X:二价有机残基; Y:C1-C6亚烷基氧基; Z:H或R 5 -O-CO-(R 5:C 1 -C 10烷基或C 1 -C 10羟基烷基); R 1 :H或CH 3; R 2,R 3和R 4:H,C 1 -C 6烃基或羟基化烃基; m:0或1)。

    WATER-DISPERSIBLE ACRYLIC GRAFT COPOLYMER, METHOD FOR MAKING IT AND WATER-BASED PAINT
    3.
    发明申请
    WATER-DISPERSIBLE ACRYLIC GRAFT COPOLYMER, METHOD FOR MAKING IT AND WATER-BASED PAINT 审中-公开
    水分散丙烯酸共聚物,其制备方法和水性涂料

    公开(公告)号:WO1996005260A1

    公开(公告)日:1996-02-22

    申请号:PCT/EP1995003145

    申请日:1995-08-08

    CPC classification number: C09D151/003 C08F265/04

    Abstract: To obtain paint films with outstanding paint film performance traits such as water resistance and chemical resistance, etc., and outstanding finished appearance, and to obtain water-based paints which are easy to apply and have outstanding storage stability. An acrylic copolymer of acid number 35-120 mg KOH/g, hydroxyl group number 50-150 mg KOH/g, glass transition temperature -20 to +50 DEG C and number average molecular mass 4500-9000, comprising a copolymer of alpha , beta -ethylenic unsaturated monomers (a), and a monomer combination including an alpha , beta -ethylenic unsaturated monomer containing a glycidal group and an alpha , beta -etylenic unsaturated monomer containing a hydroxyl group to give an acid number of

    Abstract translation: 为了获得具有优异的漆膜性能特征如耐水性和耐化学性等的漆膜,并且具有优异的成品外观,并且获得易于涂覆并且具有优异的储存稳定性的水性涂料。 酸值35-120mg KOH / g,羟基数50-150mg KOH / g,玻璃化转变温度-20至+50℃,数均分子量4500-9000的丙烯酸共聚物,包含α, β-烯属不饱和单体(a),以及包含含有缩水甘油基的α,β-亚乙烯基不饱和单体和含有羟基的α,β-亚乙烯基不饱和单体以产生酸值为15mg的单体组合 KOH / g,羟基数为50〜150mg KOH / g(b),在一个阶段中以规定的比例反应,制成水分散性丙烯酸接枝共聚物,其酸值为10〜30mgKOH / g,羟基数为50-150mg KOH / g,玻璃化转变温度为-20至+50℃,数均分子量为10,000-100,000,通过将由上述(b)形成的侧链接枝至 来自上述(a)的主链,该接枝共聚物分散在水性药物中 ium获得水性油漆。

    THERMOSET PAINT COMPOSITIONS
    4.
    发明申请
    THERMOSET PAINT COMPOSITIONS 审中-公开
    热固性涂料组合物

    公开(公告)号:WO1996000756A1

    公开(公告)日:1996-01-11

    申请号:PCT/EP1995002384

    申请日:1995-06-20

    CPC classification number: C08G18/6254 C08G18/6258

    Abstract: To obtain thermoset paint compositions with which paint films which have superior acid resistance, abrasion resistance and durability can be formed, and which have superior storage stability. Constitution: Thermoset paint compositions which contain a low polarity acrylic resin of hexane tolerance at least 100, being an esterification and polymerization reaction product of a monomer mixture comprising 10 - 70 % by weight of epoxy compound which has one epoxy group and which has no polymerizable unsaturated bond, 5 - 70 % by weight of vinyl monomer which has carboxyl groups and 5 - 85 % by weight of vinyl monomer which has no carboxylic acid group, and a hardening agent which reacts with hydroxy groups.

    Abstract translation: 为了获得具有优异的耐酸性,耐磨性和耐久性的涂膜的热固性涂料组合物,可以形成具有优异的储存稳定性的热固性涂料组合物。 结构:含有至少100个己烷耐受性的低极性丙烯酸树脂的热固性涂料组合物是包含10-70重量%的具有一个环氧基并且不具有可聚合的环氧基的环氧化合物的单体混合物的酯化和聚合反应产物 不饱和键,5-70重量%的具有羧基的乙烯基单体和5-85重量%的不含羧酸基的乙烯基单体,和与羟基反应的硬化剂。

    WATER-SOLUBLE CELLULOSE DERIVATIVE AND BIOCOMPATIBLE MATERIAL
    5.
    发明申请
    WATER-SOLUBLE CELLULOSE DERIVATIVE AND BIOCOMPATIBLE MATERIAL 审中-公开
    水溶性纤维素衍生物和生物成分材料

    公开(公告)号:WO1993016117A1

    公开(公告)日:1993-08-19

    申请号:PCT/JP1993000177

    申请日:1993-02-12

    Inventor: NOF CORPORATION

    CPC classification number: B01D67/0088 A61L33/08 C08F251/02 C08L1/02 C08F230/02

    Abstract: A water-soluble cellulose derivative which is produced by grafting 2-methacryloyloxyethylphosphorylcholine onto water-soluble cellulose and has a structural unit represented by formula (I); and a biocompatible material containing the same as the active ingredient, wherein n represents an integer of 1 to 100. The water-soluble cellulose derivative having such a specific structural unit is endowed with both biocompatibility and an affinity for cellulose, thus being utilizable as a biocompatible material for clarifying blood, and so forth.

    COLORED METALLIC PAINT COMPOSITIONS AND PAINTED OBJECTS
    7.
    发明申请
    COLORED METALLIC PAINT COMPOSITIONS AND PAINTED OBJECTS 审中-公开
    彩色金属涂料组合物和涂饰物品

    公开(公告)号:WO1997031983A1

    公开(公告)日:1997-09-04

    申请号:PCT/EP1997000608

    申请日:1997-02-10

    CPC classification number: C09D5/36

    Abstract: To obtain a colored metallic paint with which a colored metallic paint film which has excellent features and with which a change in color is produced according to differences in the viewing angle can be formed using the usual cheap pigments without compounding special glitter materials. A paint composition which contains, per 100 parts by weight of a film forming binder (A), from 0.1 to 15 parts by weight of metallic powder (B), from 0.1 to 10 parts by weight of a first colored pigment (C) of primary particle size from 0.01 to 0.2 mu m which is selected from among the group comprising the phthalocyanine, perylene, indanthrone, azomethine, benzimidazolone, quinacridone, anthraquinone, diketopyrolopyrrole and dioxazine based pigments, and from 0.5 to 50 parts by weight of a second colored pigment (D) of primary particle size from 0.1 to 2 mu m selected from among the group comprising the diketopyrolopyrrole, quinacridone, pyrazolone, naphthol AS, iron oxide and complex metal oxide based pigments, where the primary particle size of the pigment (C) is relatively smaller than that of the pigment (D), and there is a complementary color relationship between the pigments (C) and (D).

    Abstract translation: 为了获得具有优异特征并且根据视角的差异产生颜色变化的着色金属漆膜的彩色金属涂料,可以使用通常的廉价颜料形成,而不需要混合特殊的闪光材料。 一种涂料组合物,其包含相对于成膜粘合剂(A)每100重量份,0.1〜15重量份的金属粉末(B),0.1〜10重量份的第一着色颜料(C) 一次粒径为0.01〜0.2μm,选自酞菁,苝,阴丹酮,偶氮甲碱,苯并咪唑酮,喹吖啶酮,蒽醌,二酮咯吡咯和二恶嗪类颜料,以及0.5〜50重量份的第二有色 颜料(C)的一次粒径为0.1〜2μm的颜料(D),选自二酮基吡咯并吡咯,喹吖啶酮,吡唑啉酮,萘酚AS,氧化铁和复合金属氧化物系颜料, (D)相对较小,颜料(C)和(D)之间存在互补的颜色关系。

    METHOD FOR FORMING A PAINT FILM, AND PAINTED OBJECT
    8.
    发明申请
    METHOD FOR FORMING A PAINT FILM, AND PAINTED OBJECT 审中-公开
    形成涂膜的方法和涂漆对象

    公开(公告)号:WO1997022421A1

    公开(公告)日:1997-06-26

    申请号:PCT/EP1996005166

    申请日:1996-11-22

    CPC classification number: B05D7/532 B05D7/542

    Abstract: To offer a method for forming paint films of outstanding acid resistance, finished appearance, water resistance and adhesion, etc., even when a water-based base finishing coat and solvent-based top finishing coat are painted wet-on-wet. A method for forming a paint film by a method for forming a hardened paint film in which a water-based thermosetting base finishing coat is painted onto the surface of an object to be painted, a thermosetting top coat is painted on top of this wet-on-wet, and the paint films are hardened at the same time, in which the aforementioned top coat which contains as a primary resin a copolymer which is a copolymer of a vinyl monomer which has a ring structure and other vinyl monomer(s) in which the proportion of vinyl monomer having a ring structure in the total quantity of monomers is 20-50 wt.%, and the proportion of other vinyl monomer(s) is 80-50 wt.%, and which has a glass transition temperature of 0-60 DEG C, a solubility parameter of 9.0-11.0 and a weight-average molecular weight of 4000-30,000.

    Abstract translation: 为了提供一种形成具有优异的耐酸性,成品外观,耐水性和粘附性等的涂膜的方法,即使将水性基底涂层和溶剂型顶涂层涂在湿润湿润上。 通过用于形成硬化漆膜的方法来形成漆膜的方法,其中将水性热固性基底饰面涂布在待涂漆物体的表面上,将热固性顶涂层涂在该湿 - 并且涂膜同时硬化,其中上述顶涂层包含作为主要树脂的共聚物,该共聚物是具有环结构的乙烯基单体和其它乙烯基单体的共聚物 其中单体总量中具有环结构的乙烯基单体的比例为20-50重量%,其它乙烯基单体的比例为80-50重量%,玻璃化转变温度为 0-60℃,溶解度参数为9.0-11.0,重均分子量为4000-30,000。

    METHOD FOR FORMING A PAINT FILM, AND A PAINTED OBJECT
    9.
    发明申请
    METHOD FOR FORMING A PAINT FILM, AND A PAINTED OBJECT 审中-公开
    形成涂膜的方法和涂漆物体

    公开(公告)号:WO1997022420A1

    公开(公告)日:1997-06-26

    申请号:PCT/EP1996005159

    申请日:1996-11-22

    Abstract: To form paint films of outstanding acid resistance, finished appearance, water resistance, adhesion and bending resistance by coating a base finishing coat and top finishing coat wet-on-wet. A method for forming a paint film by a method for forming a thermosetting paint film in which a solvent-based thermosetting base finishing coat is painted onto the surface of an object to be painted, a thermosetting top finishing coat is painted on top of this wet-on-wet, and the paint films are hardened at the same time, in which the aforementioned top finishing coat which contains as a primary resin a copolymer which is a copolymer of a vinyl monomer which has a ring structure and other vinyl monomers in which the proportion of vinyl monomer having a ring structure in the total quantity of monomers is 20-50 wt.%, and the proportion of other vinyl monomer(s) is 80-50 wt.%, and which has a glass transition temperature of 0-60 DEG C, a solubility parameter of 9.0-11.0 and a weight-average molecular weight of 4000-30,000.

    Abstract translation: 通过涂布底漆和顶涂层湿润湿法,形成具有优异耐酸性,成品外观,耐水性,粘合性和耐弯曲性的漆膜。 通过用于形成热固性漆膜的方法来形成漆膜的方法,其中将溶剂型热固性基底涂层涂在待涂漆物体的表面上,将热固性顶部精整涂层涂在该湿的顶部 并且漆膜同时硬化,其中上述顶涂层包含作为主要树脂的共聚物,其是具有环结构的乙烯基单体和其它乙烯基单体的共聚物,其中其中 在单体总量中具有环结构的乙烯基单体的比例为20-50重量%,其它乙烯基单体的比例为80-50重量%,玻璃化转变温度为0 -60℃,溶解度参数为9.0-11.0,重均分子量为4000〜30000。

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