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    PROCESS FOR THE PREPARATION OF PHENOL AND CYCLOHEXANONE
    6.
    发明申请
    PROCESS FOR THE PREPARATION OF PHENOL AND CYCLOHEXANONE 审中-公开
    制备苯酚和环己酮的方法

    公开(公告)号：WO2011001244A1

    公开(公告)日：2011-01-06

    申请号：PCT/IB2010/001540

    申请日：2010-06-23

    申请人： POLIMERI EUROPA S.P.A. ,  BENCINI, Elena ,  GAMBAROTTI, Cristian ,  MELONE, Lucio ,  PASTORI, Nadia ,  PROSPERINI, Simona ,  PUNTA, Carlo ,  RECUPERO, Francesco

    发明人： BENCINI, Elena ,  GAMBAROTTI, Cristian ,  MELONE, Lucio ,  PASTORI, Nadia ,  PROSPERINI, Simona ,  PUNTA, Carlo ,  RECUPERO, Francesco

    IPC分类号： C07C2/66 ,  C07C2/74 ,  C07C37/08 ,  C07C39/04 ,  C07C13/28 ,  C07C49/403 ,  C07C45/53 ,  C07C409/16

    CPC分类号： C07C2/66 ,  C07C2/74 ,  C07C37/08 ,  C07C45/53 ,  C07C2529/08 ,  C07C2601/14 ,  C07C13/28 ,  C07C39/04 ,  C07C49/403

    摘要： Process for the preparation of phenol and cyclohexanone which comprises : a. the synthesis of cyclohexylbenzene by the hydro- alkylation of benzene by contact with hydrogen or the alkylation of benzene with cyclohexene using Y zeolites; b. the selective aerobic oxidation of cyclohexylbenzene to the corresponding hydroperoxide catalyzed by N- hydroxy-derivatives in the presence of polar solvents; and c. the scission of the hydroperoxide of cyclohexylbenzene to phenol and cyclohexanone by homogeneous or heterogeneous acid catalysts; characterized in that the synthesis of cyclohexylbenzene takes place in the presence of a catalytic system comprising a Y zeolite and an inorganic ligand wherein the Y zeolite has a crystalline structure with openings consisting of (12) tetrahedra and the inorganic ligand is γ-alumina, and wherein said catalytic composition is characterized by a pore volume, obtained by adding the mesoporosity and macroporosity fractions, greater than or equal to 0.7 cm /g, wherein at least 30% of said volume consists of pores with a diameter greater than 100 nanometers.

    摘要翻译： 苯酚和环己酮的制备方法，其包括：a。 通过与氢接触而使苯进行氢化烷基化或使用Y沸石将苯与环己烯烷基化合成环己基苯; 湾 在极性溶剂存在下，由N-羟基衍生物催化环己基苯与相应的氢过氧化物的选择性好氧氧化; 和c。 通过均相或多相酸催化剂将环己基苯的氢过氧化物分解成苯酚和环己酮; 其特征在于环己基苯的合成是在包含Y沸石和无机配体的催化体系存在下进行的，其中Y沸石具有由（12）四面体构成的开口的结晶结构，无机配体是α-氧化铝，以及 其中所述催化组合物的特征在于孔容积，其通过加入大于或等于0.7cm 3 / g的中孔隙度和大孔隙度分数而获得，其中至少30％的所述体积由直径大于100纳米的孔组成。