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    PROCESS FOR MAKING CROSSLINKED INJECTION MOLDED ARTICLES
    1.
    发明申请
    PROCESS FOR MAKING CROSSLINKED INJECTION MOLDED ARTICLES 审中-公开
    制造交联注塑制品的工艺

    公开(公告)号：WO2011034833A3

    公开(公告)日：2011-05-05

    申请号：PCT/US2010048704

    申请日：2010-09-14

    Applicant: UNION CARBIDE CHEM PLASTIC ,  DOW GLOBAL TECHNOLOGIES LLC ,  ESSEGHIR MOHAMED ,  SENGUPTA SAURAV S

    Inventor： ESSEGHIR MOHAMED ,  SENGUPTA SAURAV S

    IPC: B29C45/40

    CPC classification number: C08J3/244 ,  C08J2351/06

    Abstract: An injection molding process for making a plastic article, the process comprising the steps of: A. Forming a moisture-curable composition comprising a 1. Silane-functionalized polyethylene, 2. Moisture source, e.g., a moisture-containing filler, wherein the moisture source excludes alcohols, and 3. Condensation catalyst; B. Injecting the composition into a mold; C. Subjecting the composition to conditions sufficient to 1. Release moisture from the moisture source, and 2. Partially cure the composition; D. Removing the partially cured composition from the mold; and E. Continuing the cure of the composition outside of the mold. The process is particularly well suited for the manufacture of thick parts, such as wire and cable elastomeric connectors.

    Abstract translation: 一种用于制造塑料制品的注射成型方法，该方法包括以下步骤：A.形成包含1.硅烷官能化聚乙烯的可湿固化组合物，2.湿气源，例如含水的填充剂，其中湿气 来源不包括醇，和3.缩合催化剂; B.将组合物注入模具; C.使组合物达到足以达到的条件1.释放水分源中的水分，和2.使组合物部分固化; D.从模具中取出部分固化的组合物; 和E.继续固化模具外的组合物。 该工艺特别适用于制造厚壁部件，如电线和电缆弹性连接器。

    PROCESS FOR MAKING CROSSLINKED INJECTION MOLDED ARTICLES
    2.
    发明申请
    PROCESS FOR MAKING CROSSLINKED INJECTION MOLDED ARTICLES 审中-公开
    制造交错注射成型品的方法

    公开(公告)号：WO2011034833A2

    公开(公告)日：2011-03-24

    申请号：PCT/US2010/048704

    申请日：2010-09-14

    Applicant: UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY LLC ,  DOW GLOBAL TECHNOLOGIES INC. ,  ESSEGHIR, Mohamed ,  SENGUPTA, Saurav, S.

    Inventor： ESSEGHIR, Mohamed ,  SENGUPTA, Saurav, S.

    IPC: B29C45/40

    CPC classification number: C08J3/244 ,  C08J2351/06

    Abstract: An injection molding process for making a plastic article, the process comprising the steps of: A. Forming a moisture-curable composition comprising a 1. Silane-functionalized polyethylene, 2. Moisture source, e.g., a moisture-containing filler, wherein the moisture source excludes alcohols, and 3. Condensation catalyst; B. Injecting the composition into a mold; C. Subjecting the composition to conditions sufficient to 1. Release moisture from the moisture source, and 2. Partially cure the composition; D. Removing the partially cured composition from the mold; and E. Continuing the cure of the composition outside of the mold. The process is particularly well suited for the manufacture of thick parts, such as wire and cable elastomeric connectors.

    Abstract translation: 一种用于制造塑料制品的注射成型方法，该方法包括以下步骤：A.形成包含1.硅烷官能化聚乙烯的湿气固化组合物，2.水分源，例如含水填料，其中水分 来源不包括醇类，和3.缩合催化剂; B.将组合物注入模具; C.使组合物达到足以从水分源释放水分的条件，和2.部分固化组合物; D.从模具中取出部分固化的组合物; 和E.继续固化组合物在模具外面。 该方法特别适用于制造厚部件，例如电线和电缆弹性连接器。

    IN SITU MOISTURE GENERATION AND USE OF POLYFUNCTIONAL ALCOHOLS FOR CROSSLINKING OF SILANE-FUNCTIONALIZED RESINS
    4.
    发明申请
    IN SITU MOISTURE GENERATION AND USE OF POLYFUNCTIONAL ALCOHOLS FOR CROSSLINKING OF SILANE-FUNCTIONALIZED RESINS 审中-公开
    在SITU水分产生和使用多官能醇用于硅烷官能化树脂的交联

    公开(公告)号：WO2009058545A2

    公开(公告)日：2009-05-07

    申请号：PCT/US2008079724

    申请日：2008-10-13

    Applicant: DOW GLOBAL TECHNOLOGIES INC ,  CHAUDHARY BHARAT I ,  COGEN JEFFREY M ,  SENGUPTA SAURAV S

    Inventor： CHAUDHARY BHARAT I ,  COGEN JEFFREY M ,  SENGUPTA SAURAV S

    CPC classification number: C08K5/05 ,  C08K5/42 ,  Y10T428/1352 ,  Y10T428/139 ,  C08L43/04

    Abstract: Polymer compositions comprise a (i) silane-fknctionalized polymer, e.g., a polyethylene grafted with vinyl triethoxy silane, (H) polyfunctional alcohol e.g., a,a,a',a'~ tetramethyl-I,3-benzenediethanol and, optionally, (iii) acid, e.g., an alkylated aryl disulfonic acid. The use of polyfunctional alcohols in the absence of a strong acid yields a light- crosslinking of the silane-functionalized polymer and this, in turn, provides a polymer melt with improved extensional properties such as elongational viscosity and melt strength. The use of a polyfunctional alcohol in combination with a blocked strong acid provides a slow rate of crosslinking during melt processing and a high degree of ultimate crosslinking after the polymer composition has been shaped or molded.

    Abstract translation: 聚合物组合物包含（i）硅烷官能化聚合物，例如用乙烯基三乙氧基硅烷接枝的聚乙烯，（H）多官能醇，例如a，a，a'，a'〜四甲基-1,3-苯二甲醇， （iii）酸，例如烷基化芳基二磺酸。 在不存在强酸的情况下使用多官能醇产生硅烷官能化聚合物的轻交联，这又提供了具有改进的拉伸性能如伸长粘度和熔体强度的聚合物熔体。 使用多官能醇与封闭的强酸组合提供了在熔融加工过程中缓慢的交联速率，以及在聚合物组合物成型或模制之后的高度极限交联。

    FUNCTIONALISED POLYOLEFINS, MOISTURE CURABLE POLYOLEFIN RESINS AND PROCESSES OF MANUFACTURE THEREOF
    6.
    发明申请
    FUNCTIONALISED POLYOLEFINS, MOISTURE CURABLE POLYOLEFIN RESINS AND PROCESSES OF MANUFACTURE THEREOF 审中-公开
    功能性聚烯烃，水分可固化聚烯烃树脂及其制造方法

    公开(公告)号：WO2006047875A1

    公开(公告)日：2006-05-11

    申请号：PCT/CA2005/001683

    申请日：2005-11-04

    Applicant: QUEEN'S UNIVERSITY AT KINGSTON ,  PARENT, John, Scott ,  SENGUPTA, Saurav, Sankar

    Inventor： PARENT, John, Scott ,  SENGUPTA, Saurav, Sankar

    IPC: C08F8/34 ,  C08F10/00 ,  C08F8/08 ,  C08F8/00 ,  C07F7/18

    CPC classification number: C07F7/1836 ,  C08F8/34 ,  C08F8/42 ,  C08F255/02

    Abstract: A process for preparing a functionalized polyolefin is described. The process comprises the step of reacting: (i) a polyolefin, (ii) a compound containing a functional group, and (iii) a coagent compound having Formula (I): X n - Y -Z m wherein: Y is a core moiety; Z is a moiety containing a carbon-carbon double bond or a carbon-carbon triple bond; X is a moiety different than Z and the bond between X and Y may be a single bond or a double bond; n is a whole number greater than or equal to 0; m is a whole number greater than or equal to 2; and m+n equals a number up to the valence of Y; wherein: (a) when m is 2 and n is 0, the process comprises initially reacting the polyolefin and the coagent to form a product that is then reacted with the compound containing the functional group, and (b) the compound containing a functional group is substantially inert in free radical-mediated polymerization reactions and in free radical-mediated grafted reactions. The invention also relates to a functionalized polyolefin produced by such a process. The functionalized polyolefins have improved chemical and physical properties and are used in the preparation of composites ans blends applied, for example, in packaging and automotive industry.

    Abstract translation: 描述了制备官能化聚烯烃的方法。 该方法包括以下步骤：（i）聚烯烃，（ii）含有官能团的化合物，和（iii）具有式（I）的助剂化合物：X-n-Y-Z 其中：Y是核心部分; Z是含有碳 - 碳双键或碳 - 碳三键的部分; X是不同于Z的部分，X和Y之间的键可以是单键或双键; n是大于或等于0的整数; m是大于或等于2的整数; 并且m + n等于直到Y的价数; 其中：（a）当m为2且n为0时，该方法首先使聚烯烃和助剂反应形成一种产物，然后与含有该官能团的化合物反应，和（b）含有官能团的化合物 在自由基介导的聚合反应和自由基介导的接枝反应中基本上是惰性的。 本发明还涉及通过这种方法制备的官能化聚烯烃。 官能化聚烯烃具有改善的化学和物理性质，并且用于制备复合材料和混合物，例如在包装和汽车工业中应用。

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