公开(公告)号：WO2013048752A1

公开(公告)日：2013-04-04

申请号：PCT/US2012/055070

申请日：2012-09-13

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  LAUFER, Caroline, H. ,  EATON, Robert, F. ,  GHOSH-DASTIDAR, Abhijit ,  MUNDRA, Manish ,  CHAUDHARY, Bharat, I. ,  COGEN, Jeffrey, M. ,  FU, Lin

Inventor： LAUFER, Caroline, H. ,  EATON, Robert, F. ,  GHOSH-DASTIDAR, Abhijit ,  MUNDRA, Manish ,  CHAUDHARY, Bharat, I. ,  COGEN, Jeffrey, M. ,  FU, Lin

IPC: C08K5/00 ,  C07D303/42

CPC classification number: C08K5/1515 ,  C08K5/0016 ,  C08K2201/014 ,  C09D127/06 ,  H01B3/443 ,  C08L27/06

Abstract: The present disclosure is directed to a plasticizer, polymeric compositions containing the plasticizer, and conductors coated with the polymeric composition. The plasticizer includes (i) an epoxidized fatty acid methyl ester, (ii) an epoxidized natural oil, and (iii) an epoxidized tallate ester. Polymeric compositions containing a polymeric resin and the plasticizer exhibit a weight loss less than 50 mg/cm 2 after exposure to 100°C for seven days. Conductors coated with the polymeric composition (containing the plasticizer) pass the low temperature unwind test of UL719 and exhibit a weight loss less than 50 mg/cm 2 after exposure to 100°C for seven days.

Abstract translation: 本公开涉及含增塑剂的增塑剂，聚合物组合物和涂覆有聚合物组合物的导体。 增塑剂包括（i）环氧化脂肪酸甲酯，（ii）环氧化天然油，和（iii）环氧化的酯酸酯。 含有聚合物树脂和增塑剂的聚合物组合物在暴露于100℃下七天后的重量损失小于50mg / cm 2。 涂覆有聚合物组合物（含增塑剂）的导体通过UL719的低温退火试验，并且在暴露于100℃7天后显示出小于50mg / cm 2的重量损失。

公开(公告)号：WO2012061606A1

公开(公告)日：2012-05-10

申请号：PCT/US2011/059166

申请日：2011-11-03

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  EATON, Robert F. ,  GHOSH-DASTIDAR, Abhijit ,  CHAUDHARY, Bharat I. ,  COGEN, Jeffrey M. ,  LAUFER, Caroline H.

Inventor： EATON, Robert F. ,  GHOSH-DASTIDAR, Abhijit ,  CHAUDHARY, Bharat I. ,  COGEN, Jeffrey M. ,  LAUFER, Caroline H.

IPC: C08K5/1515

CPC classification number: C08K5/1515 ,  C08K2201/014 ,  H01B3/308 ,  C08L27/06

Abstract: The disclosure is directed to a plasticizer system with improved electrical properties. The plasticizer system includes (a) a primary plasticizer consisting of an epoxidized vegetable oil and (b) a secondary plasticizer consisting of an epoxidized fatty acid ester, where the primary plasticizer is present in an amount greater than 50% by weight of the total plasticizer system weight.

Abstract translation: 本公开涉及具有改善的电性能的增塑剂体系。 增塑剂体系包括（a）由环氧化植物油组成的主要增塑剂和（b）由环氧化脂肪酸酯组成的二级增塑剂，其中主要增塑剂的存在量大于总增塑剂的50重量％ 系统重量。

公开(公告)号：WO2012044498A1

公开(公告)日：2012-04-05

申请号：PCT/US2011/052452

申请日：2011-09-21

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  CHEN, Buo ,  CHAUDHARY, Bharat, I. ,  KMIEC, Chester, J. ,  COGEN, Jeffrey, M.

Inventor： CHEN, Buo ,  CHAUDHARY, Bharat, I. ,  KMIEC, Chester, J. ,  COGEN, Jeffrey, M.

IPC: C08J5/04 ,  C08L23/10

CPC classification number: G02B6/4434 ,  B29C70/081 ,  B29C70/523 ,  C08J5/10 ,  C08J2323/10 ,  C08K7/14 ,  C08L23/0815 ,  C08L23/10 ,  C08L51/06 ,  C08L2205/03 ,  C08L2205/16 ,  G02B6/4429 ,  Y10T428/2918 ,  Y10T428/2933 ,  Y10T428/2967 ,  Y10T428/2969

Abstract: This invention relates to a fiber reinforced plastic material with improved flexibility and high tensile strength for use in optic cables. The strength member composition comprises a polypropylene based thermoplastic resin, a continuous fiber having a modulus greater than 80 PGa, and talc.

Abstract translation: 本发明涉及一种纤维增强塑料材料，其具有改进的柔性和用于光缆的高拉伸强度。 强度构件组合物包含聚丙烯基热塑性树脂，模量大于80Pg的连续纤维和滑石。

公开(公告)号：WO2011041396A1

公开(公告)日：2011-04-07

申请号：PCT/US2010/050699

申请日：2010-09-29

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  ROHM AND HAAS COMPANY ,  CHAUDHARY, Bharat, I. ,  WILLS, Scott ,  MUNDRA, Manish

Inventor： CHAUDHARY, Bharat, I. ,  WILLS, Scott ,  MUNDRA, Manish

IPC: C08K5/00 ,  C08K5/07 ,  H01B3/44 ,  C08K5/098

CPC classification number: C08K5/07 ,  C08K5/0016 ,  C08K5/0091 ,  C08K5/098 ,  C08K5/1515 ,  H01B3/443 ,  C08L27/06

Abstract: The present disclosure is directed to a polymeric composition containing a vinyl chloride resin and an epoxidized fatty acid ester. The polymeric composition also includes a heat stabilizing composition. The heat stabilizing composition includes a first metal salt, a second metal salt, and a β-diketone. The epoxidized fatty acid ester is the primary, or the sole, plasticizer in the polymeric composition. The present polymeric composition finds advantageous application as a coating for wire and cable.

Abstract translation: 本公开涉及含有氯乙烯树脂和环氧化脂肪酸酯的聚合物组合物。 聚合物组合物还包括热稳定组合物。 热稳定化组合物包括第一金属盐，第二金属盐和β-二酮。 环氧化脂肪酸酯是聚合物组合物中的主要或唯一的增塑剂。 本发明的聚合物组合物可用作电线和电缆的涂层。

公开(公告)号：WO2011005852A1

公开(公告)日：2011-01-13

申请号：PCT/US2010/041198

申请日：2010-07-07

Applicant: DOW GLOBAL TECHNOLOGIES INC. ,  QUEEN'S UNIVERSITY AT KINGSTON ,  CHAUDHARY, Bharat, I. ,  PARENT, John, Scott ,  FINLAYSON, Malcolm, F. ,  WEAVER, John, D. ,  CONG, Rongjuan ,  WANG, Jian

Inventor： CHAUDHARY, Bharat, I. ,  PARENT, John, Scott ,  FINLAYSON, Malcolm, F. ,  WEAVER, John, D. ,  CONG, Rongjuan ,  WANG, Jian

IPC: C08F10/06 ,  C08F8/00

CPC classification number: C08F255/02 ,  C08F8/00 ,  C08F2810/20 ,  C08F230/08

Abstract: The present disclosure provides propylene-based polymers which exhibit a strain hardening distribution factor that is less than zero and/or a strain hardening factor greater than 1.5. The propylene-based polymers are rheology-modified by way of silane coupling to improve melt strength.

Abstract translation: 本公开提供了表现出小于零的应变硬化分布因子和/或应变硬化因子大于1.5的基于丙烯的聚合物。 基于丙烯的聚合物通过硅烷偶联进行流变改性以改善熔体强度。

公开(公告)号：WO2010074920A1

公开(公告)日：2010-07-01

申请号：PCT/US2009/066695

申请日：2009-12-04

Applicant: DOW GLOBAL TECHNOLOGIES INC. ,  SENGUPTA, Saurav, S. ,  GHOSH-DASTIDAR, Abhijit ,  CHAUDHARY, Bharat, I.

Inventor： SENGUPTA, Saurav, S. ,  GHOSH-DASTIDAR, Abhijit ,  CHAUDHARY, Bharat, I.

IPC: C08K5/42 ,  C08K5/56

CPC classification number: C08K5/42 ,  C08K5/56 ,  C08L43/04

Abstract: Ethylene-vinylsilane copolymers are moisture-cured under ambient conditions using a synergistic combination of at least one Lewis acid and at least one Brønsted acid or at least one Lewis base and at least one Brønsted base. Preferably the catalyst system comprises a Lewis acid, e.g., dibutyltin dilaurate, in combination with a Brønsted acid, e.g., sulfonic acid. The Lewis acid or base and the Brønsted acid or base is present in the catalyst system at a molar ratio of Lewis acid/base to Brønsted acid/base of 1:10 to 10:1.

Abstract translation: 乙烯 - 乙烯基硅烷共聚物在环境条件下使用至少一种路易斯酸和至少一种布朗斯台德酸或至少一种路易斯碱和至少一种布朗斯台德碱的协同组合进行湿固化。 优选地，催化剂体系包含与布朗斯台德酸例如磺酸组合的路易斯酸，例如二月桂酸二丁基锡。 路易斯酸或碱和布朗斯台德酸或碱以路易斯酸/碱与布朗斯台德酸/碱的摩尔比1:10至10:1存在于催化剂体系中。

公开(公告)号：WO2009045744A2

公开(公告)日：2009-04-09

申请号：PCT/US2008/076861

申请日：2008-09-18

Applicant: DOW GLOBAL TECHNOLOGIES INC. ,  WASSERMAN, Eric, P. ,  CHAUDHARY, Bharat, I. ,  BISCOGLO, Michael, B.

Inventor： WASSERMAN, Eric, P. ,  CHAUDHARY, Bharat, I. ,  BISCOGLO, Michael, B.

IPC: C08L43/04 ,  C08K5/04 ,  C08K5/098 ,  C08K5/057

CPC classification number: C08F8/00 ,  C08J9/125 ,  C08J2343/04 ,  C08K5/057 ,  C08K5/098 ,  C08K5/57 ,  Y10T428/139 ,  C08L43/04

Abstract: Compositions comprising a polymer resin comprising at least one copolymer with hydrolysablε groups, a water-generating meial salt hydrate, and a catalyst that comprises a metal atom and at least two ligands taken from the set alkyjoxy and carboxylate are used to form articles that moisture-cure through in-situ generation of water via dehydration of the metal hydrate. The compositions are melt mixed to promote the dehydration and start the cure process during the mixing step. The curing compositions are formed and allowed to harden.

Abstract translation: 包含聚合物树脂的组合物，所述聚合物树脂包含至少一种具有可水解基团的共聚物，产生水的湄公河盐水合物和包含金属原子和至少两个取自所述烷氧基和羧酸酯基的配体的催化剂 用于形成通过金属水合物的脱水原位生成水而湿固化的制品。 将该组合物熔融混合以促进脱水并在混合步骤期间开始固化过程。 固化组合物形成并允许硬化。

公开(公告)号：WO2009012069A1

公开(公告)日：2009-01-22

申请号：PCT/US2008/069289

申请日：2008-07-07

Applicant: DOW GLOBAL TECHNOLOGIES INC. ,  WASSERMAN, Eric, P. ,  CHAUDHARY, Bharat, I.

Inventor： WASSERMAN, Eric, P. ,  CHAUDHARY, Bharat, I.

IPC: C08K5/092 ,  C08K5/17 ,  C08K5/20 ,  C08L43/04 ,  C09D143/04

CPC classification number: C08K5/092 ,  C08K5/175 ,  C08L23/0892 ,  C08L2312/08 ,  Y10T428/139 ,  C08L43/04

Abstract: Compositions comprising a polymer resin comprising at least one copolymer with hydrolysable groups, an amino acid or diearboxylic acid water-generating organic compound, and a catalyst that comprises a metal atom and at least two ligands taken from the set alkyloxy and earhcxylate are used to form articles that moisture-cure through in-situ generation of water via ring-closing dehydration reactions.

Abstract translation: 包含包含至少一种具有可水解基团的共聚物的聚合物树脂，氨基酸或二羧酸产水有机化合物的组合物和包含金属原子和至少两个取自组合的烷氧基和己二酸酯的配体的催化剂被用于形成 通过闭环脱水反应原位产生水分固化的物品。

公开(公告)号：WO2008045718A2

公开(公告)日：2008-04-17

申请号：PCT/US2007/080143

申请日：2007-10-02

Applicant: DOW GLOBAL TECHNOLOGIES INC. ,  ESSEGHIR, Mohamed ,  EATON, Robert, F. ,  COGEN, Jeffrey, M. ,  KLIER, John ,  JOW, Jinder ,  GUERRA, Suzanne, M. ,  CHAUDHARY, Bharat, I.

Inventor： ESSEGHIR, Mohamed ,  EATON, Robert, F. ,  COGEN, Jeffrey, M. ,  KLIER, John ,  JOW, Jinder ,  GUERRA, Suzanne, M. ,  CHAUDHARY, Bharat, I.

IPC: C08K5/00 ,  C08K5/3435

CPC classification number: C08F2/38 ,  C08F4/00 ,  C08K5/0025 ,  C08K5/3435

Abstract: Scorch is inhibited during the free-radical crosslinking of a crosslinkable polymer, e.g., an EPDM, by incorporating into the polymer before melt processing and crosslinking a scorch inhibiting amount of a derivative, preferably an ether, ester or urethane derivative, of a TEMPO compound, e.g., 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl. The scorch inhibitors of this invention perform as well, if not better, than their 4-hydroxy- tetrahydrocarbylpiperidin-1-oxyl counterparts in similar polymer compositions and under similar conditions in terms of scorch inhibition and ultimate degree of crosslinking, but exhibit less volatility and less migration within the polymer composition.

Abstract translation: 在可交联聚合物（例如EPDM）的自由基交联过程中，通过在熔融加工和交联之前将防焦烧量的衍生物，优选醚，酯 或TEMPO化合物例如4-羟基 - 四氢化碳基哌啶-1-氧基的氨基甲酸酯衍生物。 本发明的焦化抑制剂如果不是更好，其性能与它们的4-羟基 - 四烃基哌啶-1-氧基对应物在类似的聚合物组合物中以及在类似的焦化抑制和最终交联度条件下相似，但表现出较小的挥发性和 聚合物组合物内迁移较少。

公开(公告)号：WO2006017391A2

公开(公告)日：2006-02-16

申请号：PCT/US2005/027008

申请日：2005-08-01

Applicant: DOW GLOBAL TECHNOLOGIES INC. ,  BISCOGLIO, Michael, B. ,  KLIER, John ,  CHAUDHARY, Bharat, I. ,  MULLINS, Michael, J. ,  TUCKER, Christopher, J.

Inventor： BISCOGLIO, Michael, B. ,  KLIER, John ,  CHAUDHARY, Bharat, I. ,  MULLINS, Michael, J. ,  TUCKER, Christopher, J.

IPC: C08L23/00 ,  C08L51/06

CPC classification number: C08K5/42 ,  C08F255/00 ,  C08F255/02 ,  C08L23/0892 ,  C08L2312/08 ,  C08F230/08 ,  C08L43/04

Abstract: Silane crosslinkable polymer compositions comprise (i) at least one silane crosslinkable polymer, e.g., ethylene-silane copolymer, and (ii) a catalytic amount of at least one polysubstituted aromatic sulfonic acid (PASA). The PASA catalysts are of the formula: HSO 3 Ar-R 1 (R x ) m Where: m is 0 to 3; R 1 is (CH 2 ) n CH 3 , and n is 0 to 3 or greater than 20; Each R x is the same or different than R 1 ; and Ar is an aromatic moiety.

Abstract translation: 硅烷交联聚合物组合物包含（i）至少一种硅烷可交联聚合物，例如乙烯 - 硅烷共聚物，和（ii）催化量的至少一种多取代芳族磺酸（PASA）。 PASA催化剂具有下式：HSO 3 Ar-R 1（R x x）m其中：m 是0到3; R 1是（CH 2 CH 2）n CH 3 CH 3，n是0至3或大于20; 每个R x X相同或不同于R 1; 并且Ar是芳族部分。