公开(公告)号：WO2008017663A2

公开(公告)日：2008-02-14

申请号：PCT/EP2007/058146

申请日：2007-08-06

Applicant: ESSILOR INTERNATIONAL (COMPAGNIE GENERALE D'OPTIQUE) ,  DE LEUZE-JALLOULI, Agnès ,  FOURNAND, Gérald ,  STANCZYK, Susan M.

Inventor： DE LEUZE-JALLOULI, Agnès ,  FOURNAND, Gérald ,  STANCZYK, Susan M.

CPC classification number: C09C3/006 ,  B82Y30/00 ,  C01P2004/64 ,  C09C1/00 ,  C09C1/3009 ,  C09C1/3054 ,  C09C1/3063 ,  C09C1/3081 ,  C09C1/309 ,  C09C3/048 ,  C09C3/063 ,  C09C3/08 ,  C09C3/12

Abstract: The present invention relates to a process for modifying the surface of nanoparticles, comprising providing nanoparticles, activating the surface of said nanoparticles by treatment with energetic species, and treating said nanoparticles with at least one gaseous phosphorus-containing compound having at least one functional group selected from a phosphoric acid group, a phosphonic acid group, a phosphinic acid group, a phosphinous acid group, salts thereof and derivatives thereof, a phosphine group and derivatives thereof, a phosphine oxide group and derivatives thereof, a phosphite group and a phosphonium group, resulting in chemical grafting of said phosphorus-containing compound on the surface of the nanoparticles. The invention also relates to a method of preparation of a stabilized dispersion of nanoparticles using the above prepared nanoparticles.

Abstract translation: 本发明涉及一种修饰纳米颗粒表面的方法，包括提供纳米颗粒，通过用能量物质处理活化所述纳米颗粒的表面，并用至少一种选自至少一个官能团的气态含磷化合物处理所述纳米颗粒 磷酸基，膦酸基，次膦酸基，膦酸基，其盐及其衍生物，膦基及其衍生物，氧化膦基及其衍生物，亚磷酸酯基和鏻基， 导致所述含磷化合物在纳米颗粒的表面上的化学接枝。 本发明还涉及使用上述制备的纳米颗粒制备稳定的纳米颗粒分散体的方法。

公开(公告)号：WO2008017663A3

公开(公告)日：2008-03-27

申请号：PCT/EP2007058146

申请日：2007-08-06

Applicant: ESSILOR INT ,  DE LEUZE-JALLOULI AGNES ,  FOURNAND GERALD ,  STANCZYK SUSAN M

Inventor： DE LEUZE-JALLOULI AGNES ,  FOURNAND GERALD ,  STANCZYK SUSAN M

IPC: C09C1/00 ,  C09C1/30 ,  C09C3/00 ,  C09C3/04 ,  C09C3/06 ,  C09C3/08 ,  C09C3/12

CPC classification number: C09C3/006 ,  B82Y30/00 ,  C01P2004/64 ,  C09C1/00 ,  C09C1/3009 ,  C09C1/3054 ,  C09C1/3063 ,  C09C1/3081 ,  C09C1/309 ,  C09C3/048 ,  C09C3/063 ,  C09C3/08 ,  C09C3/12

Abstract: The present invention relates to a process for modifying the surface of nanoparticles, comprising providing nanoparticles, activating the surface of said nanoparticles by treatment with energetic species, and treating said nanoparticles with at least one gaseous phosphorus-containing compound having at least one functional group selected from a phosphoric acid group, a phosphonic acid group, a phosphinic acid group, a phosphinous acid group, salts thereof and derivatives thereof, a phosphine group and derivatives thereof, a phosphine oxide group and derivatives thereof, a phosphite group and a phosphonium group, resulting in chemical grafting of said phosphorus-containing compound on the surface of the nanoparticles. The invention also relates to a method of preparation of a stabilized dispersion of nanoparticles using the above prepared nanoparticles.

Abstract translation: 本发明涉及修饰纳米颗粒表面的方法，包括提供纳米颗粒，通过用高能物质处理活化所述纳米颗粒的表面，并用至少一种选择至少一种官能团的气态含磷化合物处理所述纳米颗粒 膦酸基团，次膦酸基团，亚膦酸基团，其盐及其衍生物，膦基及其衍生物，氧化膦基团及其衍生物，亚磷酸酯基团和鏻基团， 导致所述含磷化合物在纳米颗粒表面上的化学接枝。 本发明还涉及使用上述制备的纳米粒子制备纳米粒子的稳定分散体的方法。