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公开(公告)号:WO2023064917A1
公开(公告)日:2023-04-20
申请号:PCT/US2022/078139
申请日:2022-10-14
发明人: LUGO, Elva L. , LIU, Bo , LI, Mengmeng , MURE, Cliff R. , CRAMMER, Taylor L. , ALEXANDRE, Francois
IPC分类号: C08F210/16
摘要: According to one embodiment, a process for producing a unimodal ethylene/α-olefin copolymer, the process comprising contacting ethylene and one or more (C3−C12) α-olefin comonomers with a chromium-based catalyst system in a gas-phase polymerization reactor to produce the unimodal ethylene/α-olefin copolymer; wherein the unimodal ethylene/α-olefin copolymer comprises: a density from 0.952 g/cm3 to 0.957 g/cm3; a flow index (I21) from 4.0 to 6.2 dg/min; a melt viscosity ratio (V0.1/V100) at 190 °C of 55 to 75; a molecular weight distribution (MWD) as calculated by the weight average molecular weight (Mw) divided by the number-average molecular weight (Mn) (Mw/Mn); and a peak molecular weight (Mp), all as measured by gel permeation chromatography.
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公开(公告)号:WO2023009430A1
公开(公告)日:2023-02-02
申请号:PCT/US2022/038170
申请日:2022-07-25
摘要: Disclosed herein is a method for polymerizing a compound in a gas phase reactor. The method includes at least passing a liquid catalyst to a catalyst inlet of a manifold assembly, passing a carrier gas to a carrier gas inlet of the manifold assembly, combining the liquid catalyst and the carrier gas in the main channel of the manifold assembly, and passing the combination of the liquid catalyst and the carrier gas to the reaction chamber. The present disclosure is also directed to manifold assemblies for communication with reaction chambers.
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公开(公告)号:WO2021061597A1
公开(公告)日:2021-04-01
申请号:PCT/US2020/051907
申请日:2020-09-22
发明人: BORSE, Nitin , CHANDAK, Swapnil, B. , BAFNA, Ayush, A. , KUHLMAN, Roger, L. , WIELICZKO, Joel, D. , SZUL, John, F. , HE, Chuan, C. , LESTER, Charles, D.
摘要: A nucleating agent-free and LLDPE-free polyolefin composition for making films with enhanced barrier properties against water vapor and oxygen gas. Related aspects include formulations, manufactured articles, films, and methods.
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公开(公告)号:WO2020251764A1
公开(公告)日:2020-12-17
申请号:PCT/US2020/034803
申请日:2020-05-28
发明人: BORSE, Nitin , CHANDAK, Swapnil B.
摘要: A polyethylene blend that has an improved stretch break property and is useful for stretch wrap film applications. The polyethylene blend consists essentially of approximately 98 weight percent (wt%) of a linear low-density polyethylene (LLDPE) component and approximately 2 wt% of a higher molecular weight high-density polyethylene polymer (HMW HDPE) component, based on the combined weight of the LLDPE and HMW HDPE components. Also, a method of making the polyethylene blend, a formulation comprising the polyethylene blend and at least one additive that is different than the polyethylene blend, a method of making a manufactured article from the polyethylene blend or formulation; the manufactured article made thereby, and use of the polyethylene blend for stretch wrapping object(s) in need thereof.
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公开(公告)号:WO2020046663A1
公开(公告)日:2020-03-05
申请号:PCT/US2019/047424
申请日:2019-08-21
发明人: LIU, Bo , HE, Chuan , ABE, Daudi A. , KUHLMAN, Roger L. , BAFNA, Ayush A. , LYNN, Timothy R.
IPC分类号: C08F4/659 , C08F210/16
摘要: A bimodal ethylene- co -1-butene copolymer consisting essentially of a higher molecular weight component and a lower molecular weight component and, when in melted form at 190 degrees Celsius, is characterized by a unique melt property space defined by a combination of high-load melt index, melt flow ratio, and melt elasticity properties. A (blown) film consisting essentially of the bimodal ethylene- co -1-butene copolymer and having improved properties. Methods of synthesizing the bimodal ethylene- co -1-butene copolymer and making the blown film. A manufactured article comprising the bimodal ethylene- co -1- butene copolymer.
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公开(公告)号:WO2019241045A1
公开(公告)日:2019-12-19
申请号:PCT/US2019/035921
申请日:2019-06-07
发明人: LIU, Bo , WIELICZKO, Joel D. , SZUL, John F. , ABE, Daudi A. , KUHLMAN, Roger L. , BAFNA, Ayush A. , LYNN, Timothy R.
IPC分类号: C08F210/16 , C08F4/659 , C08F4/6592 , C08J5/18
摘要: A bimodal ethylene- co -1-hexene copolymer consisting essentially of a higher molecular weight component and a lower molecular weight component and, when in melted form at 190 degrees Celsius, is characterized by a unique melt property space defined by a combination of high-load melt index, melt flow ratio, and melt elasticity properties. A blown film consisting essentially of the bimodal ethylene- co -1-hexene copolymer. A method of synthesizing the bimodal ethylene- co -1-hexene copolymer. A method of making the blown film. A manufactured article comprising the bimodal ethylene- co -1-hexene copolymer.
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公开(公告)号:WO2019182746A2
公开(公告)日:2019-09-26
申请号:PCT/US2019/020479
申请日:2019-03-04
发明人: MARIOTT, Wesley R. , SZUL, John F. , PENG, Haiqing , FARLEY, James M. , SAVATSKY, Bruce J. , LOCKLEAR, Brandon C.
IPC分类号: C08F210/16 , C08F4/6592
摘要: Embodiments of the present disclosure are directed towards catalyst formulations including a metallocene and a stearic compound selected from bis 2-hydroxyethyl stearyl amine, aluminum distearate, and combinations thereof, where the metallocene is represented by the following formula: (Formula (I)) wherein each n-PR is n-propyl, and each X is independently CH 3 , Cl, or F.
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公开(公告)号:WO2018226787A1
公开(公告)日:2018-12-13
申请号:PCT/US2018/036202
申请日:2018-06-06
摘要: The present disclosure provides a method of maintaining a target value of a melt flow index of a polyethylene polymer product being synthesized with a metallocene catalyst in a fluidized bed gas phase reactor. The method includes producing the polyethylene polymer product at the target value of the melt flow index with a metallocene catalyst in a fluidized bed gas phase reactor at a steady state in which the fluidized bed gas phase reactor is at a first reactor temperature and receives feeds of hydrogen and ethylene at a hydrogen to ethylene feed ratio at a first ratio value. When a change in reactor temperature is detected, the hydrogen to ethylene feed ratio is changed from the first ratio value to a second ratio value so as to maintain the melt flow index value of the polyethylene polymer product at the target value.
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公开(公告)号:WO2018222571A1
公开(公告)日:2018-12-06
申请号:PCT/US2018/034845
申请日:2018-05-29
发明人: CHANDAK, Swapnil B. , BORSE, Nitin
IPC分类号: C08L23/08
摘要: A polyethylene blend comprising a uniform dispersion of constituents (A) and (B): (A) a Ziegler-Natta catalyst-made linear low density polyethylene and (B) a metallocene catalyst-made linear low density polyethylene, a composition comprising the polyethylene blend and at least one additive, methods of making and using same, and manufactured articles and films comprising or made from same.
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公开(公告)号:WO2018213395A1
公开(公告)日:2018-11-22
申请号:PCT/US2018/032893
申请日:2018-05-16
发明人: HARLAN, C.Jeff , LUE, Ching-Tai
IPC分类号: C07F17/00 , C08F210/00 , C08F2/00 , C08F4/64 , C08F4/659
摘要: Embodiments of the present disclosure are directed towards metal complexes that can be utilized to form polymers. As an example, the present disclosure provides a metal complex of Formula I: wherein each Me represents methyl.
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