INK JET INK AND RECORDING MATERIAL
    1.
    发明申请
    INK JET INK AND RECORDING MATERIAL 审中-公开
    墨水喷墨和记录材料

    公开(公告)号:WO2006122888A1

    公开(公告)日:2006-11-23

    申请号:PCT/EP2006/062108

    申请日:2006-05-08

    Abstract: The present invention relates to an ink-jet ink, an ink-jet recording material or an ink- jet system containing at least one water-soluble hindered amine compound of the general formula (I): wherein G 1 and G 2 are independently alkyl of 1 to 4 carbon atoms or are together pentamethylene; Z 1 and Z 2 are each methyl, or Z 1 and Z 2 together form an unsubstituted linking moiety or a linking moiety substituted by one or more groups selected from an ester, ether, hydroxy, oxo, cyanohydrin, amide, amino, carboxy or an urethane group; E is alkoxy of 1 to 18 carbon atoms, cycloalkoxy of 5 to 12 carbon atoms or aralkoxy of 7 to 15 carbon atoms, or E is -O-T-(OH) b ; T is a straight or branched chain alkylene of 1 to 18 carbon atoms, cycloalkylene of 5 to 18 carbon atoms, cycloalkenylene of 5 to 18 carbon atoms, a straight or branched chain alkylene of 1 to 4 carbon atoms substituted by phenyl or by phenyl substituted by one or two alkyl groups of 1 to 4 carbon atoms; b is 1, 2 or 3 with the proviso that b cannot exceed the number of carbon atoms in T, and when b is 2 or 3, each hydroxyl group is attached to a different carbon atoms of T; BM is a basic material selected from the group consisting of alkali metal hydroxides, alkaline earth metal hydroxides, and amines; and, HY is an inorganic or organic acid; and, wherein the total charge of cations is equal to the total charge of anions.

    Abstract translation: 本发明涉及含有至少一种通式(I)的水溶性受阻胺化合物的喷墨油墨,喷墨记录材料或喷墨系统:其中G 1 和G 2独立地是1至4个碳原子的烷基或者是五亚甲基; Z 1和Z 2各自为甲基,或Z 1和Z 2 2一起形成未取代的连接部分或 由一个或多个选自酯,醚,羟基,氧代,羟腈,酰胺,氨基,羧基或氨基甲酸酯基团的基团取代的连接部分; E为1至18个碳原子的烷氧基,5至12个碳原子的环烷氧基或7至15个碳原子的芳烷氧基,或E为-O-T(OH)b。 T是1至18个碳原子的直链或支链亚烷基,5至18个碳原子的亚环烷基,5至18个碳原子的亚环烯基,1至4个碳原子被苯基或苯基取代的直链或支链亚烷基 由一个或两个具有1至4个碳原子的烷基; b为1,2或3,条件是b不能超过T中的碳原子数,当b为2或3时,每个羟基与T的不同碳原子相连; BM是选自碱金属氢氧化物,碱土金属氢氧化物和胺的基本材料; HY是无机酸或有机酸; 并且其中阳离子的总电荷等于阴离子的总电荷。

    INK JET INK AND RECORDING MATERIAL
    2.
    发明申请
    INK JET INK AND RECORDING MATERIAL 审中-公开
    墨水喷墨和记录材料

    公开(公告)号:WO2005092992A1

    公开(公告)日:2005-10-06

    申请号:PCT/EP2005/051182

    申请日:2005-03-16

    CPC classification number: B41M5/5227 C09D11/38

    Abstract: The present invention relates to an ink-jet ink, an ink-jet recording material or an ink-jet system containing at least one water-soluble hindered amine compound of the general formula (I): wherein G 1 and G 2 are independently alkyl of 1 to 4 carbon atoms or are together pentamethylene; Z 1 and Z 2 are each methyl, or Z 1 and Z 2 together form an unsubstituted linking moiety or a linking moiety substituted by one or more groups selected from an ester, ether, hydroxy, oxo, cyanohydrin, amide, amino, carboxy or an urethane group; E is alkoxy of 1 to 18 carbon atoms, cycloalkoxy of 5 to 12 carbon atoms or aralkoxy of 7 to 15 carbon atoms, or E is -O-T-(OH) b ; T is a straight or branched chain alkylene of 1 to 18 carbon atoms, cycloalkylene of 5 to 18 carbon atoms, cycloalkenylene of 5 to 18 carbon atoms, a straight or branched chain alkylene of 1 to 4 carbon atoms substituted by phenyl or by phenyl substituted by one or two alkyl groups of 1 to 4 carbon atoms; b is 1, 2 or 3 with the proviso that b cannot exceed the number of carbon atoms in T, and when b is 2 or 3, each hydroxyl group is attached to a different carbon atoms of T; and, HY is an inorganic or organic acid; and, wherein the total charge of cations is equal to the total charge of anions.

    Abstract translation: 本发明涉及含有至少一种通式(I)的水溶性受阻胺化合物的喷墨油墨,喷墨记录材料或喷墨系统:其中G1和G2独立地为1的烷基 至4个碳原子或一起为五亚甲基; Z1和Z2各自为甲基,或Z 1和Z 2一起形成未取代的连接部分或被一个或多个选自酯,醚,羟基,氧代,羟腈,氨基,羧基或氨基甲酸酯基团的基团取代的连接部分。 E为1至18个碳原子的烷氧基,5至12个碳原子的环烷氧基或7至15个碳原子的芳烷氧基,或E为-O-T(OH)b; T是1至18个碳原子的直链或支链亚烷基,5至18个碳原子的亚环烷基,5至18个碳原子的亚环烯基,1至4个碳原子被苯基或苯基取代的直链或支链亚烷基 1个或2个碳原子数为1〜4的烷基; b为1,2或3,条件是b不能超过T中的碳原子数,当b为2或3时,每个羟基与T的不同碳原子相连; HY为无机酸或有机酸; 并且其中阳离子的总电荷等于阴离子的总电荷。

    WATER COMPATIBLE STERICALLY HINDERED ALKOXYAMINES AND HYDROXY SUBSTITUTED ALKOXYAMINES
    7.
    发明申请
    WATER COMPATIBLE STERICALLY HINDERED ALKOXYAMINES AND HYDROXY SUBSTITUTED ALKOXYAMINES 审中-公开
    水相容性常规羟烷基胺和羟基取代的烷氧基

    公开(公告)号:WO2004076419A1

    公开(公告)日:2004-09-10

    申请号:PCT/EP2004/050133

    申请日:2004-02-16

    CPC classification number: C07D401/14 C07D211/94

    Abstract: Sterically hindered alkoxyamine and hydroxy substituted alkoxyamine stabilizer compounds are made water compatible via certain backbones with affinity towards water. The sterically hindered amines are for example of the formula where for example E and E’ are 2-hydroxycydohexyloxy, 2-hydroxy-2-methylpropoxy, benzyloxy, methoxy, propoxy, hexyloxy, heptyloxy, oclyloxy or cyclohexyloxy, R x is for example -NH 2 +CH 2 CH 2 0H Cl - , -NH 3 + - OAc, =NOH, -NHCH(CH 3 )COO - K + ,- NHCH 2 CH 2 NH(CH 3 ) 2 + - OAC, -NHCH 2 CH 2 SO 3 - K + , -NHCH(COO - K + )CH 2 CH 2 SCH 3 , -NHCH 2 COO - K + , -OCH(CH 3 )COO - K + , -OCH 2 CH 2 NH(CH 3 ) 2 + - OAC, -OCH 2 CH 2 SO 3 - K + , -OCH(COO - K + )CH 2 CH 2 SCH 3 or -OCH 2 COO - K + , and where R 5 comprises repeating units of -(OCH 2 CH 2 )-, -(OCH 2 CH 2 (CH 3 ))-,-(CH 2 CHCOOH)-, -(CH 2 C(CH 3 )COOH)-, -(CH 2 CHCOOCH 3 )-, -(NHCH 2 CH 2 )-, -(CH 2 CHOH)-, -(CH 2 CHCONH 2 )-or -(CH 2 CH(NHCOH))-. These compounds are particularly effective in stabilizing aqueous polymer systems against the deleterious effects of oxidative, thermal and actinic radiation. The compounds are effective for example in stabilizing water borne coatings, aqueous inks, aqueous inkjet media and photocured aqueous systems.

    Abstract translation: 经受某些骨架使空间受阻的烷氧基胺和羟基取代的烷氧基胺稳定剂化合物与水具有亲水性。 空间位阻胺例如具有下式,其中例如E和E'为2-羟基二己基氧基,2-羟基-2-甲基丙氧基,苄氧基,甲氧基,丙氧基,己氧基,庚氧基,α-氧代或环己氧基,Rx为例如-NH 2 + CH 2 CH 2 OH Cl - , - NH 3 +,OAc,= NOH,-NHCH(CH 3)COO - , - NHCH 2 CH 2 NH(CH 3)2 + - OAC,-NHCH 2 CH 2 SO 3 - (CH 3)COO-K +,-OCH 2 CH 2 NH(CH 3)2 +, - CH 2 CH 2 CH 3,-NHCH 2 COO- OCH,-OCH 2 CH 2 SO 3 K +,-OCH(COO - )K +)CH 2 CH 2 SCH 3或-OCH 2 COO K +,其中R 5包含 - (OCH 2 CH 2) - , - (OCH 2 CH 2(CH 3)) - , - (CH 2 CHCOOH) - , - (CH 2 C(CH 3)COOH) - , - (CH 2 CHCOOCH 3) - , - (NHCH 2 CH 2) - , - (CH 2 CHOH) - , - (CH 2 CHCONH 2) CH2CH(NHCOH)) - 。 这些化合物在稳定水性聚合物体系中抵抗氧化,热和光化辐射的有害影响是特别有效的。 该化合物例如在稳定水性涂料,水性油墨,水性喷墨介质和光固化水性体系中是有效的。

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