Abstract:
The present invention relates to an organic framework comprising a plurality of platy layers formed by successively connecting building blocks arranged in the vicinity of each other, wherein each of said building blocks is formed through a covalent bonding of two or three C6-C204 aromatic ring groups to a linear or annular boron-containing cluster; and a Lewis base which is coordinate covalent bonded to the boron-containing cluster in said platy layers.
Abstract:
The present invention relates to an organic framework comprising a plurality of platy layers formed by successively connecting building blocks arranged in the vicinity of each other, wherein each of said building blocks is formed through a covalent bonding of two or three C6-C204 aromatic ring groups to a linear or annular boron-containing cluster; and a Lewis base which is coordinate covalent bonded to the boron-containing cluster in said platy layers.
Abstract:
Disclosed is a coordination polymer crystal with porous metal-organic frameworks (MOFs), in which, while a crystal state of the coordination polymer crystal is maintained, an additional material selected from the group consisting of an organic compound, a metal cluster, and an organometallic compound is chemically bonded to the coordination polymer crystal. Therefore it is possible easily adsorb and store more guest molecules regardless of a change in an ambient temperature or pressure due to the chemically bonded additional material (such as an organic compound, a metal cluster, and an organometallic compound).