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    FLUORINATED KETONE AND FLUORINATED ETHERS AS WORKING FLUIDS FOR THERMAL ENERGY CONVERSION
    2.
    发明申请
    FLUORINATED KETONE AND FLUORINATED ETHERS AS WORKING FLUIDS FOR THERMAL ENERGY CONVERSION 审中-公开
    氟化酮和氟化醚作为工作流体进行热能转换

    公开(公告)号：WO2005085398A2

    公开(公告)日：2005-09-15

    申请号：PCT/US2005/006555

    申请日：2005-03-01

    Applicant: HONEYWELL INTERNATIONAL INC. ,  ZYHOWSKI, Gary, J. ,  SINGH, Rajiv, R.

    Inventor： ZYHOWSKI, Gary, J. ,  SINGH, Rajiv, R.

    IPC: C10M

    CPC classification number: C09K5/045 ,  C09K2205/108 ,  C09K2205/112

    Abstract: Polyfluorinated ethers and polyfluorinated ketones and mixtures thereof, preferably polyfluorinated ethers such as methyl (trifluoroethyl) ether (CH3OCH2CF3), methyl (heptafluoropropyl) ether (CH 3 OCF 2 CHFCF 3 ), di(trifluoroethyl) ether (CF 3 CH 2 OCH 2 CF 3 ), methyl (hexafluoropropyl) ether (CH 3 OCF 2 CF 2 CHF 2 ), methyl (pentafluoropropyl) ether (CH 3 OCH 2 CF 2 CF 3 ), methyl (perfluorobutyl) ether (C 4 F 9 OCH 3 ), ethyl (perfluorobutyl) ether (C 4 F 9 OC 2 H 5 ), and polyfluorinated ketones such as methyl (perfluoromethyl) ketone (CF 3 COCH 3 ), perfluoromethyl (trifluoroethyl) ketone (CF 3 CH 2 COCF 3 ), methyl (perfluooroethyl) ketone (C 2 F 5 COCH 3 ), methyl (perfluoropropyl) ketone (F 3 CF 2 CF 2 COCH 3 ), perfluoroethyl (perfluoropropyl) ketone (CF 3 CF 2 CF 2 COC 2 F 5 ), methyl (octafluorobutyl) ketone (C 2 F 5 CFHCF 2 COCH 3 ), di(perfluoropropyl) ketone (CF 3 CF 2 CF 2 COCF 2 CF 2 CF 3 ), and mixtures thereof meet the requirement for not adversely affect atmospheric chemistry and would be a negligible contributor to ozone depletion and to green-house global warming in comparison to the fully halogenated hydrocarbons and are suitable for use as working fluids for u se i n thermal energy conversion systems such as an organic Rankine cycle system.

    Abstract translation: 多氟化醚和多氟化酮及其混合物，优选多氟化醚如甲基（三氟乙基）醚（CH 3 OCH 2 CF 3），甲基（七氟丙基）醚（CH 3 OCF 3） 2 CHFCF 3），二（三氟乙基）醚（CF 3 CH 2 OCH 2 CF 2 CF 3） ），甲基（六氟丙基）醚（CH 3）2 OCF 2 CF 2 CHF 2， ），甲基（五氟丙基）醚（CH 3 OCH 2 CF 2 CF 3），甲基（五氟丙基） 全氟丁基）醚（C 4 F 9 OCH 3），乙基（全氟丁基）醚（C 4 F 4） 例如甲基（全氟甲基）酮（CF 3 COCH 3），以及多氟化酮如甲基（全氟甲基）酮（CF 3 COCH 3） ，全氟甲基（三氟乙基）酮（CF 3 CH 2 COCF 3），甲基（全氟乙基）酮（C 3 H 5） （全氟丙基）酮（F 3），甲基（全氟丙基）酮（F 3） （全氟丙基）酮（CF 3 CF 3），全氟乙基（全氟丙基）酮（CF 3 CF 3） （二氟甲基）甲基（八氟丁基）酮（C 2 H 5） （全氟丙基）酮（CF3CF2CF2CF2CF2CF2CF2CF2CF2CF2CF2CF2CF2CF2CF2CF2CF2CF2CF2CF2CF2CF2CF2CF2CF2CF2CF2CF2CF2CF2CF2CF2CF2CF2CF2CF2CF2CF3） CF 2 CFCF 2 CF 2 CF 3）以及它们的混合物满足不会不利的要求 影响大气化学，与全卤代烃相比，对臭氧消耗和温室气体全球变暖的影响可以忽略不计，并且适合用作热能转化系统（如有机兰金循环系统）中的工作流体。

    FLUORINATED KETONE AND FLUORINATED ETHERS AS WORKING FLUIDS FOR THERMAL ENERGY CONVERSION
    4.
    发明申请
    FLUORINATED KETONE AND FLUORINATED ETHERS AS WORKING FLUIDS FOR THERMAL ENERGY CONVERSION 审中-公开
    氟化酮和氟化物作为热能转换的工作流体

    公开(公告)号：WO2005085398A3

    公开(公告)日：2005-12-15

    申请号：PCT/US2005006555

    申请日：2005-03-01

    Applicant: HONEYWELL INT INC ,  ZYHOWSKI GARY J ,  SINGH RAJIV R

    Inventor： ZYHOWSKI GARY J ,  SINGH RAJIV R

    IPC: C09K5/04 ,  F01K25/08

    CPC classification number: C09K5/045 ,  C09K2205/108 ,  C09K2205/112

    Abstract: Polyfluorinated ethers and polyfluorinated ketones and mixtures thereof, preferably polyfluorinated ethers such as methyl (trifluoroethyl) ether (CH3OCH2CF3), methyl (heptafluoropropyl) ether (CH3OCF2CHFCF3), di(trifluoroethyl) ether (CF3CH2OCH2CF3), methyl (hexafluoropropyl) ether (CH3OCF2CF2CHF2), methyl (pentafluoropropyl) ether (CH3OCH2CF2CF3), methyl (perfluorobutyl) ether (C4F9OCH3), ethyl (perfluorobutyl) ether (C4F9OC2H5), and polyfluorinated ketones such as methyl (perfluoromethyl) ketone (CF3COCH3), perfluoromethyl (trifluoroethyl) ketone (CF3CH2COCF3), methyl (perfluooroethyl) ketone (C2F5COCH3), methyl (perfluoropropyl) ketone (F3CF2CF2COCH3), perfluoroethyl (perfluoropropyl) ketone (CF3CF2CF2COC2F5), methyl (octafluorobutyl) ketone (C2F5CFHCF2COCH3), di(perfluoropropyl) ketone (CF3CF2CF2COCF2CF2CF3), and mixtures thereof meet the requirement for not adversely affect atmospheric chemistry and would be a negligible contributor to ozone depletion and to green-house global warming in comparison to the fully halogenated hydrocarbons and are suitable for use as working fluids for u se i n thermal energy conversion systems such as an organic Rankine cycle system.

    Abstract translation: 多氟化醚和多氟酮及其混合物，优选多氟化醚如甲基（三氟乙基）醚（CH 3 OCH 2 CF 3），甲基（七氟丙基）醚（CH 3 OCF 2 CHFCF 3），二（三氟乙基）醚（CF 3 CH 2 OCH 2 CF 3），甲基（六氟丙基）醚（CH 3 OCF 2 CF 2 CHF 2） 甲基（五氟丙基）醚（CH3OCH2CF2CF3），甲基（全氟丁基）醚（C4F9OCH3），乙基（全氟丁基）醚（C4F9OC2H5）和多氟化酮如甲基（全氟甲基）酮（CF3COCH3），全氟甲基（三氟乙基）酮（CF3CH2COCF3） 甲基（全氟丙基）酮（C2F5COCH3），甲基（全氟丙基）酮（F3CF2CF2COCH3），全氟乙基（全氟丙基）酮（CF3CF2CF2COC2F5），甲基（八氟丁基）酮（C2F5CFHCF2COCH3），二（全氟丙基）酮（CF3CF2CF2COCF2CF2CF3） 要求不会对大气化学造成不利影响，对于臭氧消耗和温室气体全球战争的贡献将是微不足道的 与完全卤化的烃类相比，适用于您的热能转换系统（如有机兰金循环系统）的工作流体。

    CHLORO- AND BROMO-FLUORO OLEFIN COMPOUNDS USEFUL AS ORGANIC RANKINE CYCLE WORKING FLUIDS
    9.
    发明申请
    CHLORO- AND BROMO-FLUORO OLEFIN COMPOUNDS USEFUL AS ORGANIC RANKINE CYCLE WORKING FLUIDS 审中-公开
    氯氟烷和氟氯酚化合物有效地作为有机RANKINE循环工作流体

    公开(公告)号：WO2010065895A1

    公开(公告)日：2010-06-10

    申请号：PCT/US2009/066828

    申请日：2009-12-04

    Applicant: HONEYWELL INTERNATIONAL INC. ,  ZYHOWSKI, Gary ,  HULSE, Ryan ,  NAIR, Haridasan K. ,  NALEWAJEK, David ,  SINGH, Rajiv, R.

    Inventor： ZYHOWSKI, Gary ,  HULSE, Ryan ,  NAIR, Haridasan K. ,  NALEWAJEK, David ,  SINGH, Rajiv, R.

    IPC: C09K5/04

    CPC classification number: C09K5/048 ,  C07B2200/09 ,  C07C21/18 ,  C09K5/045 ,  C09K2205/126 ,  F01K25/06 ,  F01K25/08

    Abstract: Aspects of the present invention are directed to working fluids and their use in processes wherein the working fluids comprise compounds having the structure of formula (I): wherein R 1 , R 2 R 3 , and R 4 are each independently selected from the group consisting of: H, F, Cl, Br, and C 1 -C 6 alkyl, at least C 6 aryl, at least C 3 cycloalkyl, and C 6 -C1 5 alkylaryl optionally substituted with at least one F, Cl, or Br, wherein formula (I) contains at least one F and at least one Cl or Br, provided that if any R is Br, then the compound does not have hydrogen. The working fluids are useful in Rankine cycle systems for efficiently converting waste heat generated from industrial processes, such as electric power generation from fuel cells, into mechanical energy or further to electric power. The working fluids of the invention are also useful in equipment employing other thermal energy conversion processes and cycles.

    Abstract translation: 本发明的方面涉及工作流体及其在工作流体中的用途，其中工作流体包含具有式（I）结构的化合物：其中R 1，R 2，R 3和R 4各自独立地选自：H， F，Cl，Br和C 1 -C 6烷基，至少C 6芳基，至少C 3环烷基和任选被至少一个F，Cl或Br取代的C 6 -C 15烷基芳基，其中式（I）含有至少一个F 和至少一个Cl或Br，条件是如果任何R是Br，则化合物不具有氢。 工作流体在兰金循环系统中有用，用于将从燃料电池产生的工业过程产生的废热有效地转化为机械能或进一步电力。 本发明的工作流体也可用于采用其他热能转换过程和循环的设备中。

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