公开(公告)号：WO2016133668A1

公开(公告)日：2016-08-25

申请号：PCT/US2016/015300

申请日：2016-01-28

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： MOSER, William, H. ,  FORNOF, Ann, R. ,  JOLY, Guy, D. ,  YURT, Serkan ,  KREPSKI, Larry, R. ,  ABUELYAMAN, Ahmed, S. ,  FALSAFI, Afshin ,  CRAIG, Bradley, D. ,  OXMAN, Joel, D. ,  GADDAM, Babu, N.

IPC: C09J4/06 ,  A61K6/08 ,  C08F222/10 ,  C08F292/00

CPC classification number: C08F22/105 ,  A61K6/0052 ,  A61K6/0073 ,  A61K6/083 ,  C07C69/602 ,  C07F7/1836 ,  C07F9/091 ,  C08F292/00 ,  C08K3/36 ,  C09D4/00 ,  C09D7/61 ,  C09J4/06 ,  C08F2222/102 ,  C08F220/20 ,  C08F230/02 ,  A61K6/0023 ,  C08L33/08

Abstract: Novel stress-reducing crosslinking oligomers that have application in dental restoratives, thin films, hardcoats, composites, adhesives, and other uses subject to stress reduction are described. The addition-fragmentation process of crosslinking results in a chain-transfer event that provides novel polymers that may be further functionalized. In addition, the addition-fragmentation oligomer comprises pendent functional groups that bond to a substrate by forming an ionic or covalent bond, or etch the substrate by chemically removing some material from the substrate.

Abstract translation: 描述了应用于牙科修复剂，薄膜，硬涂层，复合材料，粘合剂和其它应力降低用途的新型减压交联低聚物。 交联的加成 - 断裂过程导致链转移事件，其提供可进一步官能化的新型聚合物。 此外，加成 - 断裂低聚物包括通过形成离子或共价键与基底键合的侧基官能团，或通过从基底中化学去除一些材料来蚀刻基底。

公开(公告)号：WO2013151739A1

公开(公告)日：2013-10-10

申请号：PCT/US2013/031847

申请日：2013-03-15

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  FORNOF, Ann R. ,  CARUSO DAILEY, Mary M. ,  CLAPPER, Jason D. ,  YURT, Serkan ,  KREPSKI, Larry R. ,  GADDAM, Babu N.

Inventor： FORNOF, Ann R. ,  CARUSO DAILEY, Mary M. ,  CLAPPER, Jason D. ,  YURT, Serkan ,  KREPSKI, Larry R. ,  GADDAM, Babu N.

IPC: C09J4/00

CPC classification number: C08F220/68 ,  C08F220/28 ,  C08F220/36 ,  C09J4/00 ,  C09J7/20 ,  C09J133/14 ,  C09J2433/00

Abstract: The present disclosure provides an crosslinkable composition comprising a (meth)acrylate copolymer component having pendant photobase functional groups and a crosslinking agent that has amine-reactive functional groups. On exposure to light, the pendant photobase group photolyzes to provide a pendant amine group, that crosslinks the copolymer.

Abstract translation: 本公开提供了包含具有侧基光官能团的（甲基）丙烯酸酯共聚物组分和具有胺反应性官能团的交联剂的可交联组合物。 在曝光时，侧基基团光聚合以提供交联共聚物的侧基胺基。

公开(公告)号：WO2013028401A1

公开(公告)日：2013-02-28

申请号：PCT/US2012/050725

申请日：2012-08-14

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  JOLY, Guy D. ,  ABUELYAMAN, Ahmed S. ,  CRAIG, Bradley D. ,  FALSAFI, Afshin ,  OXMAN, Joel D. ,  KREPSKI, Larry R. ,  MOSER, William H. ,  YURT, Serkan ,  FORNOF, Ann R.

Inventor： JOLY, Guy D. ,  ABUELYAMAN, Ahmed S. ,  CRAIG, Bradley D. ,  FALSAFI, Afshin ,  OXMAN, Joel D. ,  KREPSKI, Larry R. ,  MOSER, William H. ,  YURT, Serkan ,  FORNOF, Ann R.

IPC: C08F2/38

CPC classification number: C09D133/08 ,  C08F2/38 ,  C08F22/10 ,  C08F30/02 ,  C08F30/08 ,  C08F222/10 ,  C08F2438/03 ,  C09D133/04 ,  C08F220/20 ,  C08F2222/102 ,  C08F230/02 ,  C08F265/06 ,  C08F220/34 ,  C08F2222/1013

Abstract: Addition-fragmentation agents of the formula are disclosed having the following functional groups: 1) a labile addition-fragmentation group that can cleave and reform to relieve strain, 2) a free-radically polymerizable group, and 3) a surface-modifying functional group that associates with the surface of a substrate.

Abstract translation: 公开了具有以下官能团的式的加成裂解剂：1）可以切割和改性以减轻应变的不稳定加成断裂基团，2）可自由基聚合的基团，和3）表面改性官能团 其与基底的表面相关联。

公开(公告)号：WO2016209916A1

公开(公告)日：2016-12-29

申请号：PCT/US2016/038695

申请日：2016-06-22

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： YURT, Serkan ,  EL-HEDOK, Ibrahim A. ,  SAKIZADEH, Kumars ,  SETH, Jayshree

IPC: C09J133/06

CPC classification number: C09J133/06 ,  C09J4/00 ,  C09J133/14 ,  C09J133/26

Abstract: A pressure sensitive adhesive composition is described that comprises a (meth)acrylic polymer comprising polymerized units of (meth)acrylic ester monomer having a Tg less than 0C and ethylenically unsaturated monomer comprising a pendent functional group crosslinked with an amine or carboxylic acid group of at least one amino acid. Also described are aqueous pressure sensitive adhesive compositions, adhesive-coated articles, and methods.

Abstract translation: 描述了一种压敏粘合剂组合物，其包含（甲基）丙烯酸类聚合物，其包含Tg小于0℃的（甲基）丙烯酸酯单体的聚合单元和包含与胺或羧酸基团交联的侧链官能团的烯键式不饱和单体， 至少一个氨基酸。 还描述了水性压敏粘合剂组合物，粘合剂涂覆的制品和方法。

公开(公告)号：WO2015077161A1

公开(公告)日：2015-05-28

申请号：PCT/US2014/065861

申请日：2014-11-17

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： CLAPPER, Jason D. ,  YURT, Serkan ,  CAMPBELL, Christopher J.

IPC: C08F220/18 ,  C09J133/08 ,  C09J4/00

CPC classification number: B32B27/308 ,  B32B27/08 ,  B32B27/365 ,  B32B2250/24 ,  B32B2551/00 ,  C08F220/18 ,  C08F220/26 ,  C08G18/6229 ,  C08G18/8116 ,  C09J4/00 ,  C09J133/066 ,  C09J133/08 ,  C08F2220/1891 ,  C08F220/20

Abstract: The disclosure describes a curable composition comprising a) a solute (meth)acryloyl oligomer having a plurality of pendent, ethylenically unsaturated, free-radically polymerizable functional groups and nucleophilic, hydrophilic groups, a M w of 5k to 30k, a T g

Abstract translation: 本公开内容描述了可固化组合物，其包含a）具有多个侧链，不饱和的，可自由基聚合的官能团和亲核亲水基团的溶质（甲基）丙烯酰基低聚物，Mw为5k至30k，Tg <20℃ ; b）溶剂单体组分; 链转移剂和光引发剂。 可固化组合物可用作光学应用中的粘合剂。

公开(公告)号：WO2014074373A1

公开(公告)日：2014-05-15

申请号：PCT/US2013/067638

申请日：2013-10-31

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： JOLY, Guy, D. ,  ABUELYAMAN, Ahmed, S. ,  FORNOF, Ann, R. ,  CRAIG, Bradley, D. ,  KREPSKI, Larry, R. ,  MOSER, William, H. ,  YURT, Serkan ,  OXMAN, Joel, D.

IPC: A61K6/083 ,  A61K6/00

CPC classification number: A61K6/083 ,  A61K6/0023 ,  A61K6/0088 ,  A61K6/0835 ,  C09J133/14 ,  C08L33/10

Abstract: A curable dental composition comprising an addition-fragmentation agent and a curable dental resin is disclosed.

Abstract translation: 公开了一种包含加成碎裂剂和可固化牙科用树脂的可固化牙科用组合物。

公开(公告)号：WO2013181030A1

公开(公告)日：2013-12-05

申请号：PCT/US2013/042140

申请日：2013-05-22

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  YURT, Serkan ,  CLAPPER, Jason D. ,  BEHLING, Ross E. ,  CAMPBELL, Christopher J. ,  ELLIS, Mark F.

Inventor： YURT, Serkan ,  CLAPPER, Jason D. ,  BEHLING, Ross E. ,  CAMPBELL, Christopher J. ,  ELLIS, Mark F.

IPC: C08F8/30 ,  C09J4/06 ,  C08F220/18

CPC classification number: C09J4/00 ,  B05D1/02 ,  B05D1/28 ,  B05D1/305 ,  B05D3/06 ,  B05D3/12 ,  B05D5/00 ,  B32B7/12 ,  B32B2250/03 ,  B32B2255/26 ,  B32B2307/412 ,  B32B2457/20 ,  C08F2220/1883 ,  C09J4/06 ,  G02B1/04 ,  Y10T428/269 ,  Y10T428/31507 ,  Y10T428/31612 ,  Y10T428/31663 ,  C08F2220/1891 ,  C08F220/20 ,  C08F2220/1858 ,  C08F2220/281

Abstract: The disclosure describes a curable composition comprising a) a solute (meth)acryloyl oligomer having a plurality of pendent, ethylenically unsaturated, free-radically polymerizable functional groups and nucleophilic, hydrophilic groups, a) M w of 5k to 30k, a T g

Abstract translation: 本公开描述了一种可固化组合物，其包含a）具有多个侧链，不饱和的，可自由基聚合的官能团和亲核亲水基团的溶质（甲基）丙烯酰基低聚物，a）5k至30km的Mw，Tg <20° C; b）溶剂单体组分; 和光引发剂。 可固化组合物可用作光学应用中的粘合剂。

公开(公告)号：WO2019005022A1

公开(公告)日：2019-01-03

申请号：PCT/US2017/039610

申请日：2017-06-28

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： FRANKE, Carsten ,  DINGELDEIN, Joseph C. ,  ESCH, Jay A. ,  SMITHSON, Robert L.W. ,  SETH, Jayshree ,  BENSON, Olester Jr. ,  CALVERLEY, Karen J. ,  HUFFMAN, Alexander J. ,  YURT, Serkan ,  NIKNEZHAD, Setareh ,  KROPP, Michael A. ,  BAETZOLD, John P.

IPC: B29C41/20 ,  B29C67/00 ,  B32B27/04 ,  C25D3/22 ,  C09J129/04

Abstract: A method of making an adhesive is provided, including obtaining an actinic radiation-polymerizable adhesive precursor composition disposed against a surface of an actinic radiation-transparent substrate and irradiating a first portion of the actinic radiation-polymerizable adhesive precursor composition through the actinic radiation-transparent substrate for a first irradiation dosage. The method further includes irradiating a second portion of the actinic radiation-polymerizable adhesive precursor composition through the actinic radiation-transparent substrate for a second irradiation dosage. The first portion and the second portion are adjacent to or overlapping with each other and the first irradiation dosage and the second irradiation dosage are not the same. The method forms an integral adhesive having a variable thickness in an axis normal to the surface of the actinic radiation-transparent substrate. Also, an adhesive article is provided, including a substrate having a major surface and an integral adhesive disposed on the major surface of the substrate. Further, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an article; and generating, with the manufacturing device by an additive manufacturing process, the article based on the digital object. A system is provided, including a display that displays a 3D model of an article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an article.

公开(公告)号：WO2015057413A1

公开(公告)日：2015-04-23

申请号：PCT/US2014/059236

申请日：2014-10-06

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： FORNOF, Ann R. ,  MOSER, William H. ,  ABUELYAMAN, Ahmed S. ,  JOLY, Guy D. ,  KREPSKI, Larry R. ,  YURT, Serkan

IPC: C08G75/00 ,  A61C5/04 ,  A61K6/083 ,  C07C323/54 ,  C09D4/00 ,  C08F230/08 ,  C08L51/00

CPC classification number: C07C323/54 ,  A61C5/50 ,  A61K6/0073 ,  A61K6/083 ,  C07C323/12 ,  C08F2/38 ,  C08F290/067 ,  C08F2220/1858 ,  C08F2222/102 ,  C08F2222/225 ,  C08F2230/085 ,  C08F2438/03 ,  C08G75/00 ,  C08L35/02 ,  C08L51/08 ,  C09D4/00 ,  C09D133/14 ,  C09D135/02 ,  A61K6/0023 ,  C08L33/10 ,  A61K6/0017

Abstract: A Addition-fragmentation oligomers containing allylic disulfide groups are described. The oligomers may be added to polymerizable compositions to provide labile crosslinks that can cleave and reform during the polymerization process.

Abstract translation: 描述了含有烯丙基二硫化物基团的加成 - 裂解低聚物。 可以将低聚物加入到可聚合组合物中以提供在聚合过程中可以切割和改性的不稳定交联。

公开(公告)号：WO2013028397A2

公开(公告)日：2013-02-28

申请号：PCT/US2012/050718

申请日：2012-08-14

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  JOLY, Guy D. ,  ABUELYAMAN, Ahmed S. ,  CRAIG, Bradley D. ,  FALSAFI, Afshin ,  OXMAN, Joel D. ,  KREPSKI, Larry R. ,  MOSER, William H. ,  YURT, Serkan

Inventor： JOLY, Guy D. ,  ABUELYAMAN, Ahmed S. ,  CRAIG, Bradley D. ,  FALSAFI, Afshin ,  OXMAN, Joel D. ,  KREPSKI, Larry R. ,  MOSER, William H. ,  YURT, Serkan

IPC: A61K6/083

CPC classification number: A61K6/083 ,  A61C19/003 ,  A61K6/0023 ,  A61K6/0835 ,  C08L33/08 ,  C08L33/10

Abstract: A curable dental composition comprising an addition-fragmentation agent and a curable dental resin is disclosed.

Abstract translation: 公开了包含加成 - 断裂剂和可固化牙科树脂的可固化牙科用组合物。