DUAL CURE POLYTHIOETHER
    8.
    发明申请
    DUAL CURE POLYTHIOETHER 审中-公开
    双固化聚四氟乙烯

    公开(公告)号:WO2016106352A1

    公开(公告)日:2016-06-30

    申请号:PCT/US2015/067450

    申请日:2015-12-22

    Abstract: Compositions that are curable to polythioether polymers are provided, comprising: a) a dithiol monomer; b) a diene monomer; c) a radical cleaved photoinitiator; d) a peroxide; and e) an amine; where the peroxide and amine together are a peroxide-amine redox initiator. In some embodiments, the amine is a tertiary amine. In some embodiments, the amine is selected from the group consisting of dihydroxyethyl-p-toluidine, N,N-diisopropylethylamine, and N, N, N', N", N"-pentamethyl-diethylenetriamine. In some embodiments, the peroxide is selected from the group consisting of di-tert-butyl peroxide, methyl ethyl ketone peroxide, and benzoyl peroxide. In some embodiments, the composition may additionally comprise a polythiol monomer having three or more thiol groups.

    Abstract translation: 提供可固化到聚硫醚聚合物的组合物,其包含:a)二硫醇单体; b)二烯单体; c)自由基裂解光引发剂; d)过氧化物; 和e)胺; 其中过氧化物和胺一起是过氧化物 - 胺氧化还原引发剂。 在一些实施方案中,胺是叔胺。 在一些实施方案中,胺选自二羟乙基 - 对甲苯胺,N,N-二异丙基乙胺和N,N,N',N“,N” - 五甲基二亚乙基三胺。 在一些实施方案中,过氧化物选自二叔丁基过氧化物,甲基乙基酮过氧化物和过氧化苯甲酰。 在一些实施方案中,组合物可另外包含具有三个或更多个硫醇基团的多硫醇单体。

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