公开(公告)号：WO2017214115A1

公开(公告)日：2017-12-14

申请号：PCT/US2017/036112

申请日：2017-06-06

Applicant: ARKEMA INC.

Inventor： KOZEL, Thomas H. ,  RACHWAL, Lisa B.

IPC: B01F17/00 ,  B01F17/44 ,  B01F17/56 ,  C07C409/00 ,  C08F4/34 ,  C08K5/14

Abstract: Evaporation of water from an aqueous dispersion of a solid peroxide such as benzoyl peroxide is retarded by the incorporation of carboxylic acid salt. The carboxylic acid salt renders the aqueous dispersion less susceptible to explosive decomposition when exposed to external triggering events such as impact, heat, friction or contamination, yet does not interfere with the ability to achieve and maintain a stable, small particle size dispersion having desirable viscosity and flow properties.

Abstract translation: 通过引入羧酸盐来阻止水从固体过氧化物如过氧化苯甲酰的水分散体中蒸发。 当暴露于诸如冲击，热，摩擦或污染的外部触发事件时，羧酸盐使水分散体不易受爆炸分解的影响，但不影响实现和保持具有所需粘度的稳定的小粒度分散体的能力 和流动性。

公开(公告)号：WO2013187949A1

公开(公告)日：2013-12-19

申请号：PCT/US2013/028492

申请日：2013-03-01

Applicant: ARKEMA INC.

Inventor： KOZEL, Thomas H. ,  GRAVELLE, Joseph M. ,  BELFORD, Timothy ,  SALVADOR, Tomas

IPC: C09K3/00

CPC classification number: A61K47/34 ,  A23L5/49 ,  A23V2002/00 ,  A61K9/14 ,  A61K9/145 ,  A61K31/327 ,  A61K47/08 ,  C11C3/02

Abstract: The viscosity of aqueous dispersions of normally solid organic peroxides may be advantageously lowered through the use of surfactants which are polyglyceryl esters of C6-C12 fatty acids. The reduction in viscosity facilitates milling the peroxides to reduce particle size and also provides dispersions of small particle size peroxides which may be readily poured or pumped.

Abstract translation: 通过使用作为C6-C12脂肪酸的聚甘油酯的表面活性剂，可以有利地降低常规固体有机过氧化物水分散体的粘度。 粘度的降低有助于研磨过氧化物以减少粒度，并且还提供可容易地倾倒或泵送的小粒径过氧化物的分散体。

公开(公告)号：WO2019133335A1

公开(公告)日：2019-07-04

申请号：PCT/US2018/066204

申请日：2018-12-18

Applicant: ARKEMA INC. ,  PPG INDUSTRIES OHIO, INC.

Inventor： KOZEL, Thomas H. ,  PALYS, Leonard H. ,  VANHEMELRYCK, Bruno ,  HEROLD, Robert D. ,  HERRARA, Marco ,  SLEZAK, Brandy

IPC: C08G64/02 ,  C08F18/24

Abstract: The present invention is directed to a polymerizable composition comprising (A) a reaction product of: (a) diethyleneglycol bischloroformate, ethyleneglycol bischloroformate, or combinations thereof; (b) allyl alcohol; (c) optionally, a cyclic polyol selected from the group consisting of a cycloaliphatic polyol having at least one secondary hydroxyl group, a heterocyclic polyol having primary and/or secondary hydroxyl groups, and mixtures thereof; and (d) optionally, at least one linear or branched aliphatic polyol having two to six hydroxyl groups; and (B) an organic peroxide comprising at least three peroxide groups. A polymerizate and/or an optical article comprising the polymerizable compositions of the invention are also provided.

公开(公告)号：WO2015031558A1

公开(公告)日：2015-03-05

申请号：PCT/US2014/053049

申请日：2014-08-28

Applicant: ARKEMA INC.

Inventor： KOZEL, Thomas H. ,  GRAVELLE, Joseph M. ,  BELFORD, Timothy ,  SALVADOR, Tomas ,  DESPOTOPOULOU, Marina

IPC: A23L1/277

CPC classification number: A23L5/40 ,  A23L5/49 ,  A61K8/0241 ,  A61K8/044 ,  A61K8/38 ,  A61K8/39 ,  A61K9/14 ,  A61K9/145 ,  A61K47/08 ,  A61K2800/412 ,  A61K2800/652 ,  A61Q5/08 ,  A61Q11/00 ,  C11D1/74 ,  C11D3/3947 ,  C11D3/3951 ,  C11D3/3955 ,  C11D3/3956 ,  C11D17/0013

Abstract: The viscosity of aqueous dispersions of normally solid organic peroxides may be advantageously lowered through the use of surfactants which are polyglyceryl esters of C6-C12 fatty acids. The reduction in viscosity facilitates milling the peroxides to reduce particle size and also provides dispersions of small particle size peroxides which may be readily poured or pumped. The aqueous dispersions are useful as components of pharmaceutical, personal care, and cleaning products and the like and are effective decolorizing agents for food products, industrial products and the like.

Abstract translation: 通过使用作为C6-C12脂肪酸的聚甘油酯的表面活性剂，可以有利地降低常规固体有机过氧化物水分散体的粘度。 粘度的降低有助于研磨过氧化物以减少粒度，并且还提供可容易地倾倒或泵送的小粒径过氧化物的分散体。 水分散体可用作药物，个人护理和清洁产品等的组分，并且是用于食品，工业产品等的有效的脱色剂。

公开(公告)号：WO2017151584A1

公开(公告)日：2017-09-08

申请号：PCT/US2017/019894

申请日：2017-02-28

Applicant: ARKEMA, INC.

Inventor： DLUZNESKI, Peter R. ,  SALVADOR, Tomas ,  KOZEL, Thomas H.

IPC: A61K8/38 ,  A61K31/192 ,  A61K31/203 ,  A61K31/327

Abstract: Encapsulated peroxide particles inhibit skin inflammation. A method of encapsulating a solid peroxide comprises dispersing solid peroxide particles ( e.g. , benzoyl peroxide) in an aqueous dispersion of fatty acid salt to form a peroxide/fatty acid salt dispersion, wherein the peroxide particles have a mean particle size (D50) of 10 µm or less; and subsequently encapsulating the solid peroxide particles by reacting the one or more monovalent fatty acid salts with one or more multivalent salts of calcium, magnesium, aluminum, silver, and/or zinc, thereby forming encapsulated peroxide particles.

Abstract translation: 封装的过氧化物颗粒抑制皮肤炎症。 包封固体过氧化物的方法包括将固体过氧化物颗粒（例如过氧化苯甲酰）分散在脂肪酸盐的水分散体中以形成过氧化物/脂肪酸盐分散体，其中过氧化物颗粒具有平均值 粒径（D50）为10微米或更小; 并随后通过使一种或多种单价脂肪酸盐与一种或多种钙，镁，铝，银和/或锌的多价盐反应而包封固体过氧化物颗粒，从而形成包封的过氧化物颗粒。

公开(公告)号：WO2011019688A1

公开(公告)日：2011-02-17

申请号：PCT/US2010/044967

申请日：2010-08-10

Applicant: ARKEMA INC. ,  NETHERO, Crit E. ,  SESHADRI, Sri R. ,  MACPHERSON, Bert ,  KOZEL, Thomas H. ,  PALYS, Leonard H.

Inventor： NETHERO, Crit E. ,  SESHADRI, Sri R. ,  MACPHERSON, Bert ,  KOZEL, Thomas H. ,  PALYS, Leonard H.

IPC: C01B15/00

CPC classification number: C07C407/003 ,  C08K5/14 ,  C08K9/04

Abstract: A low dusting extended peroxide comprises 4 - 60% by weight peroxide and a filler where the peroxide is supported on the filler. The filler comprises 20 - 100% by weight calcium carbonate and optionally silica. The extended peroxide has an angle of repose of 50° or less. A method of making the low dusting extended peroxide comprises mixing the filler material(s) and spraying the peroxide onto the filler material while it is mixing to achieve a uniform distribution of the peroxide on the filler material. A method of using the low dusting extended peroxide may include dispersing the low dusting extended peroxide in water to form an aqueous dispersion and supplying the aqueous dispersion to a fracture fluid comprising a polymer to cause the polymer to decompose.

Abstract translation: 低粉尘的延长过氧化物包含4-60重量％的过氧化物和填料，其中过氧化物负载在填料上。 填料包含20-100重量％的碳酸钙和任选的二氧化硅。 延伸的过氧化物的休止角为50°以下。 制备低喷涂延长的过氧化物的方法包括混合填料并在混合过程中将过氧化物喷涂到填料上，以实现过氧化物在填料上的均匀分布。 使用低起尘的延长的过氧化物的方法可以包括将低粉尘的延长的过氧化物分散在水中以形成水分散体并将水分散体供应到包含聚合物的断裂流体以引起聚合物分解。