公开(公告)号：WO2013139851A1

公开(公告)日：2013-09-26

申请号：PCT/EP2013/055808

申请日：2013-03-20

Applicant: BASF SE ,  BASF SCHWEIZ AG

Inventor： SCHROF, Wolfgang ,  MEIER, Thomas ,  JUNG, Christian Michael ,  CARROY, Antoine ,  JUNG, Werner-Alfons ,  HOFFMANN, Peter ,  HINTERMANN, Tobias ,  LORDELOT, Caroline ,  WALLQUIST, Olof

IPC: B05B9/00 ,  B05B9/01 ,  B05B1/24 ,  B05B1/30 ,  B05B7/06 ,  B05B7/16 ,  B05B7/22 ,  C08F2/50

CPC classification number: B05B7/068 ,  B05B1/3046 ,  B05B7/067 ,  B05B7/2435 ,  B05D1/02 ,  B05D1/34 ,  B05D3/067

Abstract: Gegenstand der vorliegenden Erfindung ist eine mobile Sprühpistole, mit der eine Strahlungshärtung eingeleitet werden kann, ohne dass der Operateur vor Strahlung geschützt werden muss. Dies wird erreich durch eine mobile Sprühpistole, umfassend einen Zufuhrkanal 2 für eine strahlungshärtbare Beschichtungsmasse, eine in Längsrichtung bewegliche Nadel 1, mit der der Zufuhrkanal 2, der einen Ringspalt um die Nadel 1 bildet, gegen die Mündung 13 des Zufuhrkanals 2 abgedichtet werden kann, wobei die Nadel 1 so ausgestaltet ist, dass sie für elektromagnetische Strahlung durchlässig ist, mit der eine Härtung der strahlungshärtbaren Beschichtungsmasse eingeleitet werden kann und/oder die Zuleitung 12 transparent für elektromagnetische Strahlung ausgestaltet ist und eine Beleuchtungseinheit 10 an derZuleitung 12 angebracht ist.

Abstract translation: 本发明是一种移动喷枪，用辐射固化可以启动无外科医生必须对辐射进行保护。 这是由移动喷枪达到，其包括进料通道2中的可辐射固化涂料组合物的目标，一个可移动的针1的纵向方向其中供应管道2，其形成在针1的周围的环形间隙可以针对口腔中的供给通道2的13密封， 其中，所述针1被构造成使得它是可渗透的电磁辐射，具有可辐射固化涂料组合物的固化可以启动和/或供应管线12被透明配置用于电磁辐射和照明单元10被附接到derZuleitung十二

公开(公告)号：WO2012136606A1

公开(公告)日：2012-10-11

申请号：PCT/EP2012/055920

申请日：2012-04-02

Applicant: BASF SE ,  HINTERMANN, Tobias ,  CARROY, Antoine ,  LORDELOT, Caroline ,  BAUER, Didier ,  KOHLI STECK, Rachel ,  FALLER, Marc

Inventor： HINTERMANN, Tobias ,  CARROY, Antoine ,  LORDELOT, Caroline ,  BAUER, Didier ,  KOHLI STECK, Rachel ,  FALLER, Marc

IPC: B01J31/02 ,  B01J31/22 ,  C08G18/22

CPC classification number: C09D175/16 ,  B01J31/0208 ,  B01J31/2234 ,  B01J2231/14 ,  B01J2231/48 ,  B01J2531/46 ,  C08G18/222 ,  C08G18/6229 ,  C08G18/68 ,  C08G18/792 ,  C09J175/04 ,  Y02P20/52

Abstract: A titanium-oxo-chelate catalyst formulation, comprising: (i) at least one compound of the formula (I), wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 and R 12 independently of each other are for example hydrogen, halogen, C 1 -C 20 alkyl, C 6 -C 14 aryl which is unsubstituted or substituted; or R 1 , R 2 and R 3 and/or R 4 , R 5 and R 6 and/or R 7 , R 8 and R 9 and/or R 10 , R 11 and R 12 together with the C-atom to which they are attached each form a C 6 - C 14 aryl group which is unsubstituted or substituted; or R 1 and R 2 and/or R 4 and R 5 and/or R 7 and R 8 and/or R 10 and R 11 together with the C-atom to which they are attached form a 5- to 7-membered carbocyclic ring; at least one chelate ligand compound of the formula (lla), (lIb) or (lIc), wherein R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are defined as above for formula (I), is suitable as photolatent catalyst formulation for polymerizing compounds, which are capable to crosslink in the presence of a Lewis acid.

Abstract translation: 一种钛 - 氧代 - 螯合催化剂制剂，其包含：（i）至少一种式（I）化合物，其中R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9，R 10，R 11和R 12独立地 彼此是例如氢，卤素，未取代或取代的C 1 -C 20烷基，C 6 -C 14芳基; 或R 1，R 2和R 3和/或R 4，R 5和R 6和/或R 7，R 8和R 9和/或R 10，R 11和R 12与它们所连接的C原子一起形成C 6 -C 14芳基， 未取代或取代的; 或R 1和R 2和/或R 4和R 5和/或R 7和R 8和/或R 10和R 11与它们所连接的C原子一起形成5-至7-元碳环; 至少一种式（Ⅰla），（IIIb）或（IIIc）的螯合配体化合物，其中R 1，R 2，R 3，R 4，R 5和R 6如上文对式（I）所定义，适合作为用于 聚合化合物，其能够在路易斯酸存在下交联。

公开(公告)号：WO2011032875A1

公开(公告)日：2011-03-24

申请号：PCT/EP2010/063198

申请日：2010-09-09

Applicant: BASF SE ,  HINTERMANN, Tobias ,  BAUER, Didier ,  CARROY, Antoine ,  LORDELOT, Caroline ,  KOHLI STECK, Rachel

Inventor： HINTERMANN, Tobias ,  BAUER, Didier ,  CARROY, Antoine ,  LORDELOT, Caroline ,  KOHLI STECK, Rachel

IPC: B01J31/02 ,  B01J31/22 ,  C08G18/22

CPC classification number: B01J31/2234 ,  B01J31/0208 ,  B01J31/2213 ,  B01J31/2226 ,  B01J2231/34 ,  B01J2531/46 ,  C08G18/222 ,  C08G18/6216 ,  C08G18/792 ,  C09D175/04

Abstract: The present invention provides a photolatent Ti-chelate catalyst formulation, comprising (i) at least one compound of the formula (I) wherein R 1 is C 1 -C 20 alkyl or C 2 -C 20 alkyl which is interrupted by one or more non-consecutive O-atoms; Y is formula (II) or optionally substituted phenyl; Y 1 is formula (III) or optionally substituted phenyl; Y 2 is formula (IV) or optionally substituted phenyl; Y 3 is formula (V) or optionally substituted phenyl; R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 and R 13 independently of each other are hydrogen, halogen, optionally substituted C 1 -C 20 alkyl, or R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 and R 13 independently of each other are optionally substituted C 6 -C 14 aryl, provided that only one of R 2 , R 3 , R 4 is hydrogen and only one of R 5 , R 6 , R 7 is hydrogen and only one of R 8 , R 9 , R 10 is hydrogen and only one of R 11 , R 12 , R 13 is hydrogen; and (ii) at least one chelate ligand compound of the formula IIa, IIb or IIc, wherein Y' is formula (VI) or formula (VII); Y' 1 is formula (VIII) or formula (IX); R' 2 , R' 3 , R' 4 , R' 5 , R' 6 and R' 7 independently of each other have on of the meanings as given for R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 and R 13 ; and R' 14 , R' 15 and R' 16 independently of each other have on of the meanings as given for R 14 , R 15 and R 16 .

Abstract translation: 本发明提供了一种光催化剂钛螯合催化剂制剂，其包含（i）至少一种式（I）化合物，其中R 1是被一个或多个非连续O原子间隔的C 1 -C 20烷基或C 2 -C 20烷基; Y是式（II）或任选取代的苯基; Y1是式（III）或任选取代的苯基; Y2是式（IV）或任选取代的苯基; Y 3为式（Ⅴ）或任选取代的苯基; R2，R3，R4，R5，R6，R7，R8，R9，R10，R11，R12和R13彼此独立地是氢，卤素，任选取代的C 1 -C 20烷基，或者R 2，R 3，R 4，R 5，R 6，R 7 R 8，R 9，R 10，R 11，R 12和R 13彼此独立地是任选取代的C 6 -C 14芳基，条件是R 2，R 3，R 4中仅有一个是氢，并且R 5，R 6，R 7中只有一个是氢， R8，R9，R10为氢，R11，R12，R13中只有一个为氢; 和（ii）式IIa，IIb或IIc的至少一种螯合配体化合物，其中Y'为式（VI）或式（VII）; Y'1是式（VIII）或式（IX）; R'2，R'3，R'4，R'5，R'6和R'7彼此独立地具有对R2，R3，R4，R5，R6，R7，R8，R9给出的含义 ，R10，R11，R12和R13; 并且R 14，R'15和R 16彼此独立地具有对R 14，R 15和R 16给出的含义。

公开(公告)号：WO2011032837A1

公开(公告)日：2011-03-24

申请号：PCT/EP2010/062779

申请日：2010-09-01

Applicant: BASF SE ,  HINTERMANN, Tobias ,  BAUER, Didier ,  CARROY, Antoine ,  LORDELOT, Caroline ,  KOHLI STECK, Rachel

Inventor： HINTERMANN, Tobias ,  BAUER, Didier ,  CARROY, Antoine ,  LORDELOT, Caroline ,  KOHLI STECK, Rachel

IPC: B01J31/02 ,  B01J31/22 ,  C08G18/22

CPC classification number: B01J31/2234 ,  B01J31/0214 ,  B01J31/223 ,  B01J2231/34 ,  B01J2531/46 ,  B33Y70/00 ,  C08G18/222 ,  C08G18/6229 ,  C08G18/792 ,  C09D175/04

Abstract: The present invention provides photolatent Ti-chelate catalyst compounds of formula (I), wherein R 1 is for example C 6 -C 14 aryl which is substituted by one or more R' 2 , R' 3 or R' 4 ; or the two R 1 together are unsubstituted linear or branched C 1 -C 12 alkylene; R 2 , R 3 , R 4 , R' 2 , R' 3 , and R' 4 independently of each other are for example hydrogen, halogen or linear or branched C 1 -C 20 alkyl; R 5 , R 6 and R 7 independently of each other are hydrogen, linear or branched C 1 - C 20 alkyl, C 6 -C 14 aryl, Br or Cl, provided that not more than one of R 5 , R 6 and R 7 is hydrogen; as well as formulations comprising said compounds and defined 1,3-diketones.

Abstract translation: 本发明提供式（I）的光催化钛螯合催化剂化合物，其中R 1为例如被一个或多个R'2，R'3或R'4取代的C6-C14芳基; 或两个R 1一起是未取代的直链或支链C 1 -C 12亚烷基; R 2，R 3，R 4，R'2，R'3和R 4彼此独立地是例如氢，卤素或直链或支链C 1 -C 20烷基; R 5，R 6和R 7彼此独立地是氢，直链或支链C 1 -C 20烷基，C 6 -C 14芳基，Br或Cl，条件是不多于一个R 5，R 6和R 7是氢; 以及包含所述化合物和所定义的1,3-二酮的制剂。