公开(公告)号：WO2013116263A1

公开(公告)日：2013-08-08

申请号：PCT/US2013/023731

申请日：2013-01-30

Applicant: BATTELLE MEMORIAL INSTITUTE

Inventor： KIM, Jin, Yong ,  LI, Guosheng ,  LU, Xiaochuan ,  SPRENKLE, Vincent, L. ,  LEMMON, John, P. ,  YANG, Zhenguo ,  COYLE, Christopher, A.

IPC: H01M10/38 ,  H01M2/08 ,  H01B1/06

CPC classification number: H01M10/0563 ,  C01F7/002 ,  C01P2006/40 ,  H01M10/399 ,  H01M2300/0048 ,  H01M2300/0057

Abstract: Sodium metal-halide energy storage devices utilizing a substituting salt in its secondary electrolyte can operate at temperatures lower than conventional ZEBRA batteries while maintaining desirable performance and lifetime characteristics. According to one example, a sodium metal-halide energy storage device operates at a temperature less than or equal to 200 °C and has a liquid secondary electrolyte having M x Na 1 - y AlCl 4-y H y , wherein M is a metal cation of a substituting salt, H is an anion of the substituting salt, y is a mole fraction of substituted Na and CI, and x is a ratio of y over r, where r is the oxidation state of M. The melting temperature of the substituting salt is less than that of NaCl.

Abstract translation: 在其二次电解质中使用取代盐的金属卤化物储能装置可以在比常规ZEBRA电池低的温度下工作，同时保持期望的性能和寿命特性。 根据一个实例，钠金属卤化物能量储存装置在小于或等于200℃的温度下操作，并且具有MxNa1-yAlCl4-yHy的液体二次电解质，其中M是取代盐的金属阳离子，H 是取代盐的阴离子，y是取代的Na和Cl的摩尔分数，x是y与r的比值，其中r是M的氧化态。取代盐的熔融温度小于 氯化钠。

公开(公告)号：WO2014120970A1

公开(公告)日：2014-08-07

申请号：PCT/US2014/013935

申请日：2014-01-30

Applicant: BATTELLE MEMORIAL INSTITUTE

Inventor： HUANG, Qian ,  LEMMON, John, P. ,  CHOI, Daiwon ,  COSIMBESCU, Lelia

IPC: H01M4/60 ,  H01M4/137 ,  H01M4/485 ,  H01M10/0525

CPC classification number: H01M4/364 ,  H01M4/137 ,  H01M4/5825 ,  H01M4/604 ,  H01M10/0525 ,  Y02E60/122 ,  Y02P70/54

Abstract: Disclosed are embodiments of active materials for organometallic and organometallic-inorganic hybrid electrodes and particularly active materials for organometallic and organometallic-inorganic hybrid cathodes for lithium-ion batteries. In certain embodiments the organometallic material comprises a ferrocene polymer.

Abstract translation: 公开了用于有机金属和有机金属 - 无机杂化电极的活性材料的实施方案，特别是用于锂离子电池的有机金属和有机金属 - 无机混合阴极的活性材料。 在某些实施方案中，有机金属材料包含二茂铁聚合物。

公开(公告)号：WO2012047661A1

公开(公告)日：2012-04-12

申请号：PCT/US2011/053482

申请日：2011-09-27

Applicant: BATTELLE MEMORIAL INSTITUTE ,  LEMMON, John, P. ,  MEINHARDT, Kerry, D.

Inventor： LEMMON, John, P. ,  MEINHARDT, Kerry, D.

IPC: H01M10/39

CPC classification number: H01M10/3909 ,  H01M10/3918 ,  Y10T29/4911

Abstract: A method of making a molten sodium battery is disclosed. A first metallic interconnect frame having a first interconnect vent hole is provided. A second metallic interconnect frame having a second interconnect vent hole is also provided. An electrolyte plate having a cathode vent hole and an anode vent hole is interposed between the metallic interconnect frames. The metallic interconnect frames and the electrolyte plate are sealed thereby forming gaseous communication between an anode chamber through the anode vent hole and gaseous communication between a cathode chamber through the cathode vent hole.

Abstract translation: 公开了一种制备熔融钠电池的方法。 提供了具有第一互连通气孔的第一金属互连框架。 还提供了具有第二互连通气孔的第二金属互连框架。 具有阴极通气孔和阳极通气孔的电解质板介于金属互连框架之间。 金属互连框架和电解质板被密封，从而通过阳极通气孔在阳极室之间形成气体连通，并且通过阴极通气孔在阴极室之间形成气体连通。