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公开(公告)号：WO2014018546A1
公开(公告)日：2014-01-30
申请号：PCT/US2013/051711
申请日：2013-07-23
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： LU, Xiaochuan , KIM, Jin Yong , LI, Guosheng , LEMMON, John P. , SPRENKLE, Vincent L.
IPC: H01M10/39 , H01M10/0562 , H01M4/136
CPC classification number: H01M10/3909 , H01M10/399
Abstract: Sodium energy storage devices employing aspects of both ZEBRA batteries and traditional Na-S batteries can perform better than either battery alone. The hybrid energy storage devices described herein can include a sodium anode, a molten sodium salt catholyte, and a positive electrode that has active species containing sulfur. Additional active species can include a transition metal source and NaCl. As a product of the energy discharge process, Na 2 S x forms in which x is less than three.
Abstract translation: 使用ZEBRA电池和传统Na-S电池的钠储能装置可以比单独使用电池的性能更好。 本文所述的混合储能装置可包括钠阳极，熔融钠盐阴极电解液和具有含硫活性物质的正电极。 另外的活性物质可以包括过渡金属源和NaCl。 作为能量放电过程的产物，形成其中x小于3的Na 2 S x。
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公开(公告)号：WO2016025062A1
公开(公告)日：2016-02-18
申请号：PCT/US2015/035149
申请日：2015-06-10
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： LI, Guosheng , KIM, Jin, Yong , LU, Xiaochuan , MEINHARDT, Kerry, D. , SPRENKLE, Vincent, L.
CPC classification number: H01M4/136 , H01M4/381 , H01M4/582 , H01M10/3954 , H01M10/399
Abstract: An energy storage device comprising a cathode comprising: (i) an Fe source; (ii) at least one sulfur species and (iii) NaCl, wherein the mol percent of S is less than 10, based on the total moles of (i), (ii) and (iii).
Abstract translation: 一种能量存储装置，包括阴极，包括：（i）Fe源; （ii）至少一种硫物质和（iii）NaCl，其中S的摩尔百分比小于10，基于（i），（ii）和（iii）的总摩尔数。
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3.发明申请COMPLIANT POLYMER SEAL AND PROCESS FOR SEALING SODIUM ENERGY STORAGE DEVICES 审中-公开合适的聚合物密封和密封钠能储存装置的方法
公开(公告)号：WO2016028351A1
公开(公告)日：2016-02-25
申请号：PCT/US2015/033012
申请日：2015-05-28
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： LI, Guosheng , MEINHARDT, Kerry D. , LU, Xiaochuan , KIM, Jin Yong , SPRENKLE, Vincent L.
CPC classification number: H01M2/08 , H01M10/3909
Abstract: A new compliant polymer seal and process for sealing sodium conducting energy storage devices and batteries are disclosed. Compliant polymer seals become viscous at the operation temperature which seals cathode and anode chambers and other components together following assembly. Seals can accommodate thermal expansion mismatches between selected components during operation.
Abstract translation: 公开了一种新的合适的聚合物密封件和用于密封钠导电储能装置和电池的方法。 合适的聚合物密封件在操作温度下变得粘稠，在组装之后将阴极和阳极室和其它部件密封在一起。 在操作期间，密封件可以适应所选组件之间的热膨胀不匹配。
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公开(公告)号：WO2013116263A1
公开(公告)日：2013-08-08
申请号：PCT/US2013/023731
申请日：2013-01-30
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： KIM, Jin, Yong , LI, Guosheng , LU, Xiaochuan , SPRENKLE, Vincent, L. , LEMMON, John, P. , YANG, Zhenguo , COYLE, Christopher, A.
CPC classification number: H01M10/0563 , C01F7/002 , C01P2006/40 , H01M10/399 , H01M2300/0048 , H01M2300/0057
Abstract: Sodium metal-halide energy storage devices utilizing a substituting salt in its secondary electrolyte can operate at temperatures lower than conventional ZEBRA batteries while maintaining desirable performance and lifetime characteristics. According to one example, a sodium metal-halide energy storage device operates at a temperature less than or equal to 200 °C and has a liquid secondary electrolyte having M x Na 1 - y AlCl 4-y H y , wherein M is a metal cation of a substituting salt, H is an anion of the substituting salt, y is a mole fraction of substituted Na and CI, and x is a ratio of y over r, where r is the oxidation state of M. The melting temperature of the substituting salt is less than that of NaCl.
Abstract translation: 在其二次电解质中使用取代盐的金属卤化物储能装置可以在比常规ZEBRA电池低的温度下工作，同时保持期望的性能和寿命特性。 根据一个实例，钠金属卤化物能量储存装置在小于或等于200℃的温度下操作，并且具有MxNa1-yAlCl4-yHy的液体二次电解质，其中M是取代盐的金属阳离子，H 是取代盐的阴离子，y是取代的Na和Cl的摩尔分数，x是y与r的比值，其中r是M的氧化态。取代盐的熔融温度小于 氯化钠。
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Patent Agency Ranking
公开(公告)号：WO2016064474A1
公开(公告)日：2016-04-28
申请号：PCT/US2015/047252
申请日：2015-08-27
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： ZHANG, Ji-Guang , LU, Xiaochuan , XU, Wu , QIAN, Jiangfeng , XIAO, Jie , LIU, Bo , SHAO, Yuyan , LU, Dongping , DENG, Daniel , LIU, Tianbiao , LI, Qiuyan
IPC: H01M10/0562 , H01M10/052 , H01M10/0585 , H01M10/056
CPC classification number: H01M10/0562 , H01M4/043 , H01M4/382 , H01M4/386 , H01M4/485 , H01M10/052 , H01M10/056 , H01M10/0585 , H01M2300/008
Abstract: A solid-state lithium ion battery is disclosed. The battery includes an anode containing an anode active material. The battery also includes a cathode containing a cathode active material. The battery further includes a solid-state electrolyte material. The electrolyte material contains a salt or salt mixture with a melting point below approximately 300 degrees Celsius. The battery has an operating temperature of less than about 80 degrees Celsius
Abstract translation: 公开了一种固态锂离子电池。 电池包括含阳极活性材料的阳极。 电池还包括含有正极活性物质的阴极。 电池还包括固态电解质材料。 电解质材料含有熔点低于约300摄氏度的盐或盐混合物。 电池的工作温度低于约80摄氏度
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公开(公告)号：WO2014042761A2
公开(公告)日：2014-03-20
申请号：PCT/US2013/050615
申请日：2013-07-16
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： LU, Xiaochuan , LEMMON, John P. , LI, Guosheng , SPRENKLE, Vincent L.
CPC classification number: H01M4/9016 , H01M4/92 , H01M12/08 , H01M2300/0017 , H01M2300/0045 , H01M2300/0071 , Y02E60/128
Abstract: A metal-air battery is disclosed. The battery includes a sodium anode and an air cathode. The battery further includes a solid electrolyte. The sodium anode may be a molten sodium anode, and the solid electrolyte may be a beta alumina solid electrolyte. The battery has an operating temperature between 100° C and 200° C.
Abstract translation: 公开了一种金属空气电池。 电池包括钠阳极和空气阴极。 电池还包括固体电解质。 钠阳极可以是熔融的钠阳极，固体电解质可以是β氧化铝固体电解质。 电池的工作温度在100°C至200°C之间。
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">7.发明申请PROCESS FOR FABRICATION OF ENHANCED β"-ALUMINA SOLID ELECTROLYTES FOR ENERGY STORAGE DEVICES AND ENERGY APPLICATIONS 审中-公开用于能源储存装置和能源应用的增强β“ - 铝固体电解质的制备方法
公开(公告)号：WO2016028348A1
公开(公告)日：2016-02-25
申请号：PCT/US2015/032228
申请日：2015-05-22
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： LU, Xiaochuan , KIM, Jin Yong , LI, Guosheng , MEINHARDT, Kerry D. , SPRENKLE, Vincent L.
IPC: C01G25/02 , C01F7/02 , C01F17/00 , C01G25/00 , C04B35/113 , H01M10/054 , H01M10/0562 , H01M10/39
CPC classification number: H01M10/0562 , C01F7/002 , C01F7/028 , C01G25/00 , C01G25/02 , C01P2002/50 , C01P2002/54 , C01P2002/72 , C01P2006/40 , C04B35/113 , C04B35/119 , C04B35/4885 , C04B35/64 , C04B2235/3201 , C04B2235/3203 , C04B2235/3218 , C04B2235/3225 , C04B2235/3232 , C04B2235/3244 , C04B2235/3246 , C04B2235/3262 , C04B2235/441 , C04B2235/443 , C04B2235/6025 , C04B2235/604 , C04B2235/6567 , C04B2235/77 , H01M10/054 , H01M10/39 , H01M10/3918 , H01M10/399 , H01M2300/0071 , H01M2300/0077 , H01M2300/0091
Abstract: A dense β"-alumina/zirconia composite solid electrolyte and process for fabrication are disclosed. The process allows fabrication at temperatures at or below 1600 °C. The solid electrolytes include a dense composite matrix of β"-alumina and zirconia, and one or more transition metal oxides that aid the conversion and densification of precursor salts during sintering. The composite solid electrolytes find application in sodium energy storage devices and power grid systems and devices for energy applications.
Abstract translation: 公开了一种致密的β“ - 氧化铝/氧化锆复合固体电解质和制造方法，该方法允许在等于或低于1600℃的温度下制造固体电解质包括致密的β” - 氧化铝和氧化锆复合基质， 更多的过渡金属氧化物有助于烧结过程中前体盐的转化和致密化。 复合固体电解质可用于钠能量储存装置和能源应用的电网系统和装置。
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8.发明申请METALLIZATION PATTERN ON SOLID ELECTROLYTE OR POROUS SUPPORT OF SODIUM BATTERY AND PROCESS 审中-公开固体电解质的金属化模式或钠电池和工艺的多孔支持
公开(公告)号：WO2014130109A1
公开(公告)日：2014-08-28
申请号：PCT/US2013/070818
申请日：2013-11-19
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： KIM, Jin Yong , LI, Guosheng , LU, Xiaochuan , SPRENKLE, Vincent L. , LEMMON, John P.
CPC classification number: H01M10/0562 , H01M6/187 , H01M6/20 , H01M10/3927 , H01M10/3936 , H01M2300/0094
Abstract: Sodium battery configurations and a process for fabrication are detailed. The batteries include a solid electrolyte configured with an engineered metallization layer that distributes sodium across the surface of the electrolyte extending the active electrical transfer area of the cathode in electrical contact with the anode during operation. The metallization layer enhances performance, cycling efficiency, and capacity of the batteries.
Abstract translation: 详细说明了钠电池配置和制造工艺。 电池包括配置有工程化金属化层的固体电解质，其在操作期间将钠分布在电解质的表面上，延伸阴极的活性电传递区域与阳极电接触。 金属化层增强了电池的性能，循环效率和容量。
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9.发明申请ELECTROCHEMICAL ENERGY STORAGE DEVICES HAVING A METALLIC INTERFACIAL CONDUCTING AGENT AT THE ELECTRODE-ELECTROLYTE INTERFACE 审中-公开在电极 - 电解质界面处具有金属界面导电剂的电化学能量储存装置
公开(公告)号：WO2012026999A1
公开(公告)日：2012-03-01
申请号：PCT/US2011/035948
申请日：2011-05-10
Applicant: BATTELLE MEMORIAL INSTITUTE , LEMMON, John P. , LU, Xiaochuan , XIA, Guanguang , YANG, Zhenguo
Inventor： LEMMON, John P. , LU, Xiaochuan , XIA, Guanguang , YANG, Zhenguo
CPC classification number: H01M4/36 , H01M4/366 , H01M4/38 , H01M4/381 , H01M4/382 , H01M10/0562 , H01M2300/002 , Y10T29/49115
Abstract: Electrochemical energy storage devices having a metal anode and a solid-state, metal-ion exchange membrane and are characterized by an interfacial layer between the anode and the membrane, wherein the interfacial layer is a solid solution comprising the metal anode and a metallic interfacial conducting agent.
Abstract translation: 具有金属阳极和固态金属离子交换膜的电化学能量存储装置，其特征在于阳极和膜之间的界面层，其中界面层是包含金属阳极和金属界面导电的固溶体 剂。
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