Abstract:
Die Erfindung betrifft ein Verfahren zum Behandeln von Formkörpern mit einer Stahloberfläche mit einem Kohlenstoff-Gehalt im Bereich von 0 bis 2,06 Gew.-% und mit einem Chrom-Gehaltim Bereich von 0 bis 2 liegt, bei dem das Schichtgewicht einer getrockneten Konversionsschicht im Bereich von 1,5bis 15g/m 2 liegt, bei dem das Verhältnis von Beizabtrag zu Schichtgewicht BA : SG der getrockneten Konversionsschicht im Bereich von (0,30bis 0,75) : 1 liegt und bei dem die getrocknete Konversionsschicht eine fest haftende Beschichtung bildet.
Abstract:
The present invention relates to a method of pretreatment of a metallic substrate for a subsequent metal cold forming process, said method comprising at least steps (1) and (2), namely providing at least one substrate having at least one surface at least partially made of at least one metal (step (1)), contacting the at least one surface of the substrate provided in step (1) with an aqueous lubricant composition (B) (step (2)), wherein the aqueous lubricant composition (B) comprises besides water at least constituents (b1) to (b4) and optionally (b5), namely as (b1) at least one homopolymer and/or copolymer being prepared by polymerization of at least vinyl pyrrolidone as at least one monomer, wherein (b1) has a polydispersity index (PDI) in a range of from 1.5 to 8.0, as (b2) at least one wax, as (b3) at least one defoamer,and as (b4) (i) oxalate anions and/or phosphate anions or (ii) calcium cations, chloride anions and hydroxide anions, as well as optionally Fe(III) ions as (b5), wherein (b5) is present in case at least oxalate anions are present as (b4), a pretreated metallic substrate obtainable by the inventive method, a method of cold forming of a metallic substrate and an aqueous lubricant composition (B) as defined above.
Abstract:
The present invention relates to method for pretreatment of a metallic substrate for a subsequent metal cold forming process, said method comprising at least steps (1) and (2) and optionally step (3), namely providing at least one substrate having at least one surface at least partially made of at least one metal (1), contacting the at least one surface of the substrate provided in step (1) with an aqueous lubricant composition (A) having a pH value below 2.0 and comprising besides water oxalate anions (a1), thiosulfate anions (a2), chloride anions (a3), at least one film-forming polymer (a4), which is a homopolymer and/or copolymer being prepared by polymerization of at least one ethylenically unsaturated monomer, at least one wax (a5), and fluoride anions and/or bifluoride anions (a6), and optionally drying the coating film obtained after having performed step (2), a pretreated metallic substrate obtainable by the aforementioned inventive method, a method of cold forming of a metallic substrate including a step of subjecting the inventive pretreated metallic substrate to a cold forming process, an aqueous lubricant composition (A) as defined above and a master batch for preparing the aqueous composition (A).