公开(公告)号：WO2014160598A1

公开(公告)日：2014-10-02

申请号：PCT/US2014/031405

申请日：2014-03-21

申请人： CORNING INCORPORATED ,  BADDING, Michael Edward ,  BROWN, Jacqueline Leslie ,  KESTER, Lanrik Wayne ,  LIU, Xinyuan

发明人： BADDING, Michael Edward ,  BROWN, Jacqueline Leslie ,  KESTER, Lanrik Wayne ,  LIU, Xinyuan

IPC分类号： H01M2/14 ,  H01M2/16 ,  H01M10/052

CPC分类号： H01M10/0562 ,  H01M2/145 ,  H01M2/1646 ,  H01M10/052 ,  H01M10/0525 ,  H01M12/06 ,  Y02T10/7011

摘要： There is disclosed a polycrystalline lithium-ion conductive membrane for a lithium-air battery that comprises at least one surface, a polycrystalline lithium-ion conductive material comprising grain boundaries, and at least one modifying phase, wherein (a) the at least one modifying phase is incorporated into the grain boundaries to form a modified polycrystalline lithium-ion conductive material comprising modified grain boundaries, (b) the at least one modifying phase is incorporated into the at least one surface to form a modified surface, or both (a) and (b). Various lithium based batteries, including lithium ion, lithium-air, and lithium-water batteries are disclosed, as well as methods for modifying the polycrystalline lithium-ion conductive membrane to allow it to be used in such battery applications.

摘要翻译： 公开了一种用于锂空气电池的多晶锂离子传导膜，其包括至少一个表面，包含晶界的多晶锂离子传导材料和至少一个改性相，其中（a）至少一个修饰 （b）将所述至少一个改性相并入所述至少一个表面以形成改性表面，或者（a）至少一个修饰相结合在所述晶界中， 和（b）。 公开了各种锂电池，包括锂离子，锂空气和锂 - 水电池，以及用于修改多晶锂离子传导膜以允许其用于这种电池应用中的方法。

公开(公告)号：WO2018118964A1

公开(公告)日：2018-06-28

申请号：PCT/US2017/067376

申请日：2017-12-19

申请人： CORNING INCORPORATED ,  BADDING, Michael Edward ,  BOMBA, Richard Dominic ,  BROWN, Jacqueline Leslie ,  BOUTON, William Joseph ,  HRDINA, Kenneth Edward ,  KETCHAM, Thomas Dale ,  MERZ, Gary Edward ,  MILLER, Eric Lee ,  SHASHIDHAR, Nagaraja ,  ST. JULIEN, Dell Joseph ,  SONG, Zhen ,  TANNER, Cameron Wayne ,  WALSH, Conor James

发明人： BADDING, Michael Edward ,  BOMBA, Richard Dominic ,  BROWN, Jacqueline Leslie ,  BOUTON, William Joseph ,  HRDINA, Kenneth Edward ,  KETCHAM, Thomas Dale ,  MERZ, Gary Edward ,  MILLER, Eric Lee ,  SHASHIDHAR, Nagaraja ,  ST. JULIEN, Dell Joseph ,  SONG, Zhen ,  TANNER, Cameron Wayne ,  WALSH, Conor James

IPC分类号： C09J7/21 ,  C09J7/30 ,  C09J1/00

摘要： A system is provided for sintering thin, wide, and/or long tape materials such as in a roll to roll process. The system is arranged to control sintering and limit deformation of the tape during sintering to produce sintered material.

公开(公告)号：WO2014052391A1

公开(公告)日：2014-04-03

申请号：PCT/US2013/061585

申请日：2013-09-25

申请人： CORNING INCORPORATED ,  BADDING, Michael Edward ,  BROWN, Jacqueline Leslie ,  FEKETY, Curtis Robert ,  SONG, Zhen

发明人： BADDING, Michael Edward ,  BROWN, Jacqueline Leslie ,  FEKETY, Curtis Robert ,  SONG, Zhen

IPC分类号： C04B35/447 ,  C04B35/626 ,  B82Y40/00 ,  H01M10/0562 ,  C01B25/37 ,  C01B25/45

CPC分类号： C04B35/6264 ,  B82Y30/00 ,  B82Y40/00 ,  C01B25/45 ,  C04B35/447 ,  C04B35/62665 ,  C04B2235/3203 ,  C04B2235/3217 ,  C04B2235/3232 ,  C04B2235/3287 ,  C04B2235/5454 ,  C04B2235/6025 ,  C04B2235/80 ,  H01M10/052 ,  H01M10/0562

摘要： A flame spray pyrolysis method for making nanoscale, lithium ion- conductive ceramic powders comprises providing a precursor solution comprising chemical precursors dissolved in an organic solvent, and spraying the precursor solution into an oxidizing flame to form a nanoscale, lithium ion-conductive ceramic powder, wherein a concentration of the chemical precursors in the solvent ranges from 1 to 5,5 M. The precursor solution can comprise 1-20% excess lithium with respect to a stoichiometric composition of the ceramic powder. Nominal compositions of the nanoscale, ceramic powders are Li 1.4 AI 0.4 M 1.6 (PO 4 ) 3 where M is Ti or Ge.

摘要翻译： 用于制备纳米级锂离子传导性陶瓷粉末的火焰喷射热解方法包括提供包含溶解在有机溶剂中的化学前体的前体溶液，并将前体溶液喷射到氧化火焰中以形成纳米尺寸的锂离子传导性陶瓷粉末， 其中溶剂中化学前体的浓度范围为1-5.5M。相对于陶瓷粉末的化学计量组成，前体溶液可以包含1-20％过量的锂。 纳米级陶瓷粉末的标称组成为Li1.4Al0.4M1.6（PO4）3，其中M为Ti或Ge。

公开(公告)号：WO2017003980A1

公开(公告)日：2017-01-05

申请号：PCT/US2016/039708

申请日：2016-06-28

申请人： CORNING INCORPORATED

发明人： BADDING, Michael Edward ,  BOUTON, William Joseph ,  BROWN, Jacqueline Leslie ,  CURRY, Timothy Joseph ,  HURNY, Roman E ,  KESTER, Lanrik Wayne ,  KETCHAM, Thomas Dale ,  OLENICK, John Albert

IPC分类号： C04B35/486 ,  C04B35/638 ,  C04B35/64 ,  B28B11/24

CPC分类号： C04B35/486 ,  B28B11/243 ,  C04B35/638 ,  C04B35/64 ,  C04B2235/3225 ,  C04B2235/6025 ,  C04B2235/9615 ,  C04B2235/9638

摘要： A manufacturing line includes a tape of green material that is directed through a furnace so that the furnace burns off organic binder material and then partially sinters the tape without the use of a setter board. Sintered articles resulting from the manufacturing line may be thin with relatively large surface areas; and, while substantially unpolished, have few sintering-induced surface defects. Tension may be applied to the partially sintered tape as it passes through a second furnace on the manufacturing line to shape resulting sintered articles. The furnace is preferably vertically oriented and is operated preferably continuously. Preferably ceramic materials are used for forming the tape.

摘要翻译： 生产线包括通过炉子引导的绿色材料带，使得炉子烧掉有机粘合剂材料，然后在不使用固定板的情况下部分地烧结带材。 由生产线产生的烧结物可能较薄，表面积相对较大; 并且在基本上未抛光的情况下，具有很少的烧结诱导表面缺陷。 当部分烧结带通过制造线上的第二炉以形成所得烧结制品时，可以施加张力。 炉子优选地是垂直取向的，并且优选连续地操作。 优选地，陶瓷材料用于形成带。

公开(公告)号：WO2014078648A1

公开(公告)日：2014-05-22

申请号：PCT/US2013/070288

申请日：2013-11-15

申请人： CORNING INCORPORATED ,  BROWN, Jacqueline Leslie

发明人： BROWN, Jacqueline Leslie

IPC分类号： H01M12/06 ,  C01F7/00 ,  C04B35/447 ,  B25B9/00 ,  G01N27/406 ,  H01M10/0525 ,  H01M10/0562

CPC分类号： H01M8/1016 ,  C04B35/447 ,  C04B35/6261 ,  C04B35/62645 ,  C04B35/64 ,  C04B2235/3203 ,  C04B2235/3206 ,  C04B2235/3217 ,  C04B2235/3232 ,  C04B2235/3409 ,  C04B2235/443 ,  C04B2235/6025 ,  C04B2235/786 ,  C04B2235/81 ,  H01M4/36 ,  H01M4/38 ,  H01M4/48 ,  H01M4/92 ,  H01M6/04 ,  H01M6/14 ,  H01M6/16 ,  H01M6/18 ,  H01M8/10 ,  H01M8/1004 ,  H01M8/12 ,  H01M8/124 ,  H01M10/0525 ,  H01M10/0562 ,  H01M12/06 ,  H01M2300/0068 ,  Y02P70/56

摘要： A solid ceramic electrolyte may include an ion-conducting ceramic and at least one grain growth inhibitor. The ion-conducting ceramic may be a lithium metal phosphate or a derivative thereof. The grain growth inhibitor may be magnesia, titania, or both. The solid ceramic electrolyte may have an average grain size of less than about 2 microns. The grain growth inhibitor may be between about 0.5 mol.% to about 10 mol.% of the solid ceramic electrolyte.

摘要翻译： 固体陶瓷电解质可以包括离子导电陶瓷和至少一种晶粒生长抑制剂。 离子导电陶瓷可以是磷酸锂金属或其衍生物。 晶粒生长抑制剂可以是氧化镁，二氧化钛或二者。 固体陶瓷电解质可以具有小于约2微米的平均粒度。 晶粒生长抑制剂可以在固体陶瓷电解质的约0.5mol％至约10mol％之间。

公开(公告)号：WO2014035753A1

公开(公告)日：2014-03-06

申请号：PCT/US2013/055943

申请日：2013-08-21

申请人： CORNING INCORPORATED ,  BADDING, Michael Edward ,  BROWN, Jacqueline Leslie ,  FINK, Katherine A. ,  GAGOV, Atanas Valentinov ,  TANNER, Cameron Wayne

发明人： BADDING, Michael Edward ,  BROWN, Jacqueline Leslie ,  FINK, Katherine A. ,  GAGOV, Atanas Valentinov ,  TANNER, Cameron Wayne

IPC分类号： H01M2/16 ,  H01M10/056 ,  H01M10/39 ,  H01M8/02 ,  H01M8/10 ,  H01M6/18 ,  H01M10/0525

CPC分类号： H01M8/1058 ,  C08J5/22 ,  C25B13/04 ,  C25B13/08 ,  G01N27/40 ,  H01G11/56 ,  H01M2/1646 ,  H01M2/166 ,  H01M6/18 ,  H01M6/36 ,  H01M8/1048 ,  H01M10/0525 ,  H01M10/056 ,  H01M10/0562 ,  H01M2300/0091 ,  Y02E60/122 ,  Y02E60/13 ,  Y02E60/521

摘要： An ion-conducting composite electrolyte is provided comprising path-engineered ion-conducting ceramic electrolyte particles and a solid polymeric matrix. The path-engineered particles are characterized by an anisotropic crystalline structure and the ionic conductivity of the crystalline structure in a preferred conductivity direction H associated with one of the crystal planes of the path-engineered particle is larger than the ionic conductivity of the crystalline structure in a reduced conductivity direction L associated with another of the crystal planes of the path-engineered particle. The path-engineered particles are sized and positioned in the polymeric matrix such that a majority of the path-engineered particles breach both of the opposite major faces of the matrix body and are oriented in the polymeric matrix such that the preferred conductivity direction H is more closely aligned with a minimum path length spanning a thickness of the matrix body than is the reduced conductivity direction L.

摘要翻译： 提供了一种离子导电复合电解质，其包括路径工程离子导电陶瓷电解质颗粒和固体聚合物基质。 路径工程化颗粒的特征在于各向异性晶体结构，并且在与路径工程化颗粒的一个晶面相关联的优选导电方向H中的晶体结构的离子电导率大于晶体结构的离子电导率 与路径工程化颗粒的另一个晶面相关联的导电方向L减小。 路径设计的颗粒的大小和位置在聚合物基质中，使得大部分路径工程化的颗粒破坏基体的两个相对的主面，并且在聚合物基质中取向，使得优选的导电方向H更多 与沿导电方向下降的矩阵体的最小路径长度紧密对齐。