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    METHODS OF MAKING AND INSPECTING A WEB OF VITREOUS LITHIUM SULFIDE SEPARATOR SHEET AND LITHIUM ELECTRODE ASSEMBLIES
    4.
    发明申请
    METHODS OF MAKING AND INSPECTING A WEB OF VITREOUS LITHIUM SULFIDE SEPARATOR SHEET AND LITHIUM ELECTRODE ASSEMBLIES 审中-公开
    制造和检查硫酸锂分离器片和锂电极组件的方法

    公开(公告)号：WO2017112550A1

    公开(公告)日：2017-06-29

    申请号：PCT/US2016/067338

    申请日：2016-12-16

    Applicant: POLYPLUS BATTERY COMPANY, INC.

    Inventor： VISCO, Steven J., ,  NIMON, Yevgeniy S. ,  DE JONGHE, Lutgard C. ,  KATZ, Bruce D. ,  NIMON, Vitaliy

    IPC: H01M2/14 ,  H01M2/16 ,  H01M4/1397 ,  H01M10/0562 ,  G01N21/27 ,  G01N21/88

    CPC classification number: H01M10/0562 ,  G01N21/31 ,  G01N21/896 ,  G01N2021/8967 ,  H01M2/145 ,  H01M2/1646 ,  H01M2/1673 ,  H01M4/0407 ,  H01M4/134 ,  H01M4/1395 ,  H01M10/0525 ,  H01M10/0566 ,  H01M2300/0068

    Abstract: A lithium ion-conductive solid electrolyte including a freestanding inorganic vitreous sheet of sulfide-based lithium ion conducting glass is capable of high performance in a lithium metal battery by providing a high degree of lithium ion conductivity while being highly resistant to the initiation and/or propagation of lithium dendrites. Such an electrolyte is also itself manufacturable, and readily adaptable for battery cell and cell component manufacture, in a cost-effective, scalable manner. An automated machine based system, apparatus and methods assessing and inspecting the quality of such vitreous solid electrolyte sheets, electrode sub-assemblies and lithium electrode assemblies can be based on spectrophotometry and can be performed inline with fabricating the sheet or web (e.g., inline with drawing of the vitreous Li ion conducting glass) and/or with the manufacturing of associated electrode subassemblies and lithium electrode assemblies and battery cells.

    Abstract translation: 包括硫化物基锂离子导电玻璃的独立无机玻璃质片的锂离子传导性固体电解质通过提供高度的锂离子传导性同时在锂金属电池中具有高性能， 高度耐受锂枝晶的引发和/或传播。 这种电解质本身也是可制造的，并且可以以成本有效的，可扩展的方式容易地适用于电池单元和电池部件的制造。 评估和检查这种玻璃质固体电解质薄片，电极子组件和锂电极组件的质量的基于自动化机器的系统，设备和方法可以基于分光光度测量并且可以在制造薄片或薄片时在线执行（例如，与 拉制玻璃质Li离子导电玻璃）和/或制造相关的电极子组件和锂电极组件以及电池组电池。

    FLEXIBLE INORGANIC FUEL CELL MEMBRANE
    6.
    发明申请
    FLEXIBLE INORGANIC FUEL CELL MEMBRANE 审中-公开
    柔性无机燃料电池膜

    公开(公告)号：WO2016191608A1

    公开(公告)日：2016-12-01

    申请号：PCT/US2016/034448

    申请日：2016-05-26

    Applicant: ANGELL, Charles Austen ,  ANSARI, Younes ,  TUCKER, Telpriore Greg ,  KLEIN, Iolanda Santana

    Inventor： ANGELL, Charles Austen ,  ANSARI, Younes ,  TUCKER, Telpriore Greg ,  KLEIN, Iolanda Santana

    IPC: H01M8/1034 ,  H01M8/1051 ,  H01M8/1072

    CPC classification number: H01M8/1034 ,  H01M8/1016 ,  H01M8/1051 ,  H01M8/1072 ,  H01M2300/0008 ,  H01M2300/0068 ,  H01M2300/0085 ,  H01M2300/0091 ,  H01M2300/0094

    Abstract: A solid electrolyte includes an amorphous silica network and phosphoric acid. The phosphoric acid is contained in the amorphous silica network, and is typically in molecular form. The ratio of silicon to phosphorus in the solid electrolyte is about 1:4, and the silicon is in a four-coordinated state. The solid electrolyte is in the form of a dried (e.g., anhydrous) gel. The solid electrolyte may be used in a fuel cell membrane. Preparing the solid electrolyte includes reacting phosphoric acid in the liquid state with tetrachloride compound including silicon and a displaceable ligand to yield a fluid suspension, heating the fluid suspension to yield a liquid electrolyte comprising a particulate solid, separating the particulate solid from the liquid electrolyte, combining the particulate solid with water to yield a homogenous solution, forming a gel from the homogeneous solution, and removing water from the gel to yield the solid electrolyte.

    Abstract translation: 固体电解质包括无定形二氧化硅网络和磷酸。 磷酸包含在无定形二氧化硅网络中，并且通常为分子形式。 固体电解质中硅与磷的比例约为1:4，硅处于四配位状态。 固体电解质是干燥（例如无水）凝胶的形式。 固体电解质可以用于燃料电池膜。 制备固体电解质包括使液体中的磷酸与包括硅和可置换配体的四氯化物化合物反应以产生流体悬浮液，加热流体悬浮液以产生包含颗粒状固体的液体电解质，将颗粒状固体与液体电解质分离， 将颗粒固体与水结合以产生均匀溶液，从均匀溶液形成凝胶，并从凝胶中除去水以产生固体电解质。

    SODIUM-ALUMINUM BATTERY WITH SODIUM ION CONDUCTIVE CERAMIC SEPARATOR
    8.
    发明申请
    SODIUM-ALUMINUM BATTERY WITH SODIUM ION CONDUCTIVE CERAMIC SEPARATOR 审中-公开
    带铝离子导电陶瓷分离器的铝 - 铝电池

    公开(公告)号：WO2016168727A1

    公开(公告)日：2016-10-20

    申请号：PCT/US2016/027930

    申请日：2016-04-15

    Applicant: CERAMATEC, INC.

    Inventor： ROBINS, Mathew ,  BHAVARAJU, Sai

    IPC: H01M10/60 ,  H01M10/054 ,  H01M10/056 ,  H01M10/058

    CPC classification number: H01M10/399 ,  H01M4/381 ,  H01M4/582 ,  H01M10/0562 ,  H01M10/0563 ,  H01M2300/0068 ,  H01M2300/0074

    Abstract: The present invention provides a sodium-aluminum secondary cell. The cell includes a sodium metal negative electrode, a positive electrode compartment that includes an aluminum positive electrode disposed in a positive electrolyte mixture of NaAl 2 X 7 and NaAlX 4 , where X is a halogen atom or mixture of different halogen atoms selected from chlorine, bromine, and iodine, and a sodium ion conductive electrolyte membrane that separates the negative electrode from the positive electrolyte. In such cases, the electrolyte membrane can include any suitable material, including, without limitation, a NaSICON-type membrane. Generally, when the cell functions, both the sodium negative electrode and the positive electrolyte are molten and in contact with the electrolyte membrane. Additionally, the cell is functional at an operating temperature between about 100 °C and about 200 °C.

    Abstract translation: 本发明提供一种钠 - 铝二次电池。 电池包括钠金属负极，正极室，其包括设置在NaAl 2 X 7和NaAlX 4的正电解质混合物中的铝正电极，其中X是卤素原子或选自氯，溴和碘的不同卤素原子的混合物 ，以及将负极与正极电解质分离的钠离子传导性电解质膜。 在这种情况下，电解质膜可以包括任何合适的材料，包括但不限于NaSICON型膜。 通常，当电池功能时，钠负极和正电解质都熔融并与电解质膜接触。 此外，电池在约100℃至约200℃的工作温度下起作用。

    RECHARGEABLE BATTERY AND METHOD FOR MANUFACTURING THE SAME
    9.
    发明申请
    RECHARGEABLE BATTERY AND METHOD FOR MANUFACTURING THE SAME 审中-公开
    可充电电池及其制造方法

    公开(公告)号：WO2016163878A1

    公开(公告)日：2016-10-13

    申请号：PCT/NL2016/050239

    申请日：2016-04-07

    Applicant: STICHTING ENERGIEONDERZOEK CENTRUM NEDERLAND

    Inventor： SOPPE, Wilhelmus Jozef

    IPC: H01M4/04 ,  H01M4/134 ,  H01M4/1395 ,  H01M4/36 ,  H01M4/38 ,  H01M10/0525

    CPC classification number: H01M4/134 ,  B82Y30/00 ,  C23C16/24 ,  C23C16/511 ,  H01M4/0423 ,  H01M4/0428 ,  H01M4/1395 ,  H01M4/364 ,  H01M4/386 ,  H01M4/661 ,  H01M10/0525 ,  H01M10/0562 ,  H01M2004/021 ,  H01M2300/0068

    Abstract: A rechargeable battery includes at least an electrolyte layer (2), a cathode layer (4) and an anode layer (6). The electrolyte layer (2) includes a lithium salt compound arranged between a cathode surface (8) of the cathode layer (4) and an anode surface (10) of the anode layer (6). The anode layer (6) is a nanostructured silicon containing thin film layer including a plurality of columns (12), wherein the columns (12) are directed in a first direction perpendicular or substantially perpendicular to the anode surface (10) of the silicon thin film layer. The columns are arranged adjacent to each other while separated by grain-like column boundaries (14) running along the first direction. The columns (12) include silicon and have an amorphous structure in which nano-crystalline regions exist.

    Abstract translation: 可再充电电池至少包括电解质层（2），阴极层（4）和阳极层（6）。 电解质层（2）包括布置在阴极层（4）的阴极表面（8）和阳极层（6）的阳极表面（10）之间的锂盐化合物。 阳极层（6）是包括多个列（12）的纳米结构的含硅薄膜层，其中所述列（12）沿与所述硅薄片的阳极表面（10）垂直或基本垂直的第一方向 电影层。 列彼此相邻布置，同时沿着沿第一方向延伸的颗粒状列边界（14）分开。 柱（12）包括硅并且具有其中存在纳米晶区的非晶结构。

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