公开(公告)号：WO2018208785A1

公开(公告)日：2018-11-15

申请号：PCT/US2018/031613

申请日：2018-05-08

Applicant: CORNING INCORPORATED

Inventor： DRAKE, Melinda Ann ,  MORENA, Robert Michael

IPC: C01B25/37 ,  C03C3/16 ,  C03C8/08 ,  C03C8/24 ,  C03C10/00 ,  C03B23/20 ,  C04B37/00 ,  C04B37/02

Abstract: A method of making a stoichiometric monazite (LaPO 4 ) composition or a mixture of LaPO 4 and LaP 3 O 9 composition, as defined herein. Also disclosed is a method of joining or sealing materials with the compositions, as defined herein.

公开(公告)号：WO2013166367A1

公开(公告)日：2013-11-07

申请号：PCT/US2013/039434

申请日：2013-05-03

Applicant: CORNING INCORPORATED ,  DRAKE, Melinda Ann ,  LAMBERSON, Lisa Ann ,  MORENA, Robert Michael

Inventor： DRAKE, Melinda Ann ,  LAMBERSON, Lisa Ann ,  MORENA, Robert Michael

IPC: C03C3/16 ,  B60J1/00 ,  C03C3/19 ,  C03C3/21 ,  C03C8/02 ,  C03C8/04 ,  C03C8/08 ,  C03C17/04 ,  C03C21/00

CPC classification number: C03C8/08 ,  C03C3/17 ,  C03C3/19 ,  C03C3/21 ,  C03C4/02 ,  C03C4/18 ,  C03C17/04 ,  C03C2204/00 ,  C03C2207/00 ,  Y10T428/24942 ,  Y10T428/315

Abstract: Strengthened glass substrates with glass frits and methods for forming the same are disclosed. According to one embodiment, a method for forming a glass frit on a glass substrate may include providing a glass substrate comprising a compressive stress layer extending from a surface of the glass substrate into a thickness of the glass substrate, the compressive stress having a depth of layer DOL and an initial compressive stress CS i . A glass frit composition may be deposited on at least a portion of the surface of the glass substrate. Thereafter, the glass substrate and the glass frit composition are heated in a furnace to sinter the glass frit composition and bond the glass frit composition to the glass substrate, wherein, after heating, the glass substrate has a fired compressive stress CS f which is greater than or equal to 0.70*CS i .

Abstract translation: 公开了用玻璃料加强的玻璃基板及其形成方法。 根据一个实施例，在玻璃基板上形成玻璃料的方法可以包括提供一种玻璃基板，其包括从玻璃基板的表面延伸到玻璃基板的厚度的压缩应力层，压缩应力的深度为 层DOL和初始压应力CSi。 可以在玻璃基板的表面的至少一部分上沉积玻璃料组合物。 然后，将玻璃基板和玻璃料组合物在炉内加热烧结玻璃料组合物并将玻璃料组合物粘合到玻璃基板上，其中，加热后玻璃基板的烧制压缩应力CSf大于 或等于0.70 * CSi。

公开(公告)号：WO2013063238A1

公开(公告)日：2013-05-02

申请号：PCT/US2012/061867

申请日：2012-10-25

Applicant: CORNING INCORPORATED ,  DANIELSON, Paul Stephen ,  DeMARTINO, Steven Edward ,  DRAKE, Melinda Ann ,  MORENA, Robert Michael ,  PAL, Santona ,  SCHAUT, Robert Anthony

Inventor： DANIELSON, Paul Stephen ,  DeMARTINO, Steven Edward ,  DRAKE, Melinda Ann ,  MORENA, Robert Michael ,  PAL, Santona ,  SCHAUT, Robert Anthony

IPC: C03C3/087 ,  C03C3/091 ,  C03C21/00

CPC classification number: C03C3/091 ,  A61J1/00 ,  C03C3/087 ,  C03C4/18 ,  C03C4/20 ,  C03C21/002 ,  C03C2204/00 ,  Y10T428/131 ,  Y10T428/1317 ,  Y10T428/26 ,  Y10T428/315

Abstract: The embodiments described herein relate to chemically and mechanically durable glass compositions and glass articles formed from the same. In another embodiment, a glass composition may include from about 70 mol.% to about 80 mol.% SiO 2 ; from about 3 mol.% to about 13 mol.% alkaline earth oxide; X mol.% Al 2 O 3 ; and Y mol.% alkali oxide. The alkali oxide may include Na 2 O in an amount greater than about 8 mol.%. A ratio of Y:X may be greater than 1 and the glass composition may be free of boron and compounds of boron. In some embodiments, the glass composition may also be free of phosphorous and compounds of phosphorous. Glass articles formed from the glass composition may have at least a class S3 acid resistance according to DIN 12116, at least a class A2 base resistance according to ISO 695, and a type HGA1 hydrolytic resistance according to ISO 720.

Abstract translation: 本文所述的实施方案涉及由其形成的化学和机械耐久的玻璃组合物和玻璃制品。 在另一个实施方案中，玻璃组合物可以包括约70mol％至约80mol％的SiO 2; 约3mol％至约13mol％的碱土金属氧化物; X mol。％Al2O3; 和Y摩尔％碱金属氧化物。 碱金属氧化物可以包括大于约8mol％的量的Na 2 O。 Y：X的比例可以大于1，玻璃组合物可以不含硼和硼化合物。 在一些实施方案中，玻璃组合物还可以不含磷和磷的化合物。 由玻璃组合物形成的玻璃制品可以具有根据DIN 12116的至少S3级耐酸性，至少根据ISO 695的A2级耐碱性和根据ISO 720的HGA1型耐水解性。

公开(公告)号：WO2016123273A1

公开(公告)日：2016-08-04

申请号：PCT/US2016/015246

申请日：2016-01-28

Applicant: CORNING INCORPORATED

Inventor： DRAKE, Melinda Ann ,  DUPREY, Jody Ann ,  GUILFOYLE, Diane Kimberlie ,  HALSTEAD, Susan Kay ,  MORENA, Robert Michael ,  RUSSELL, Andrew Lawrence

IPC: C03C3/21 ,  C03C8/08 ,  C03C8/24 ,  C03C27/06

CPC classification number: C03C8/24 ,  C03C3/21 ,  C03C8/08 ,  C03C27/06

Abstract: A vanadium phosphate glass, a glass frit and a glass assembly including glass plates sealed with a frit seal formed from the glass frit, the glass including a glass transition temperature T g equal to or less than about 330°C, for example equal to or less than about 310°C.

Abstract translation: 一种磷酸钒玻璃，玻璃料和玻璃组合件，包括用由玻璃料形成的玻璃料密封件密封的玻璃板，玻璃化转变温度Tg等于或小于约330℃，例如等于或小于 比约310℃。

公开(公告)号：WO2015031187A1

公开(公告)日：2015-03-05

申请号：PCT/US2014/052259

申请日：2014-08-22

Applicant: CORNING INCORPORATED

Inventor： DRAKE, Melinda Ann ,  MORENA, Robert Michael

IPC: C03C3/21 ,  C03C8/08 ,  C03C8/24 ,  C03B23/20

CPC classification number: C03C3/21 ,  B32B17/06 ,  B32B2315/08 ,  B32B2457/206 ,  C03C3/16 ,  C03C8/08 ,  C03C8/14 ,  C03C8/24 ,  C03C2207/00 ,  H01L51/5246

Abstract: An antimony-free glass suitable for use in a frit for producing a hermetically sealed glass package is described. The hermetically sealed glass package, such as an OLED display device, is manufactured by providing a first glass substrate plate and a second glass substrate plate and depositing the antimony-free frit onto the first substrate plate. OLEDs may be deposited on the second glass substrate plate. An irradiation source (e.g., laser, infrared light) is then used to heat the frit which melts and forms a hermetic seal that connects the first glass substrate plate to the second glass substrate plate and also protects the OLEDs. The antimony-free glass has excellent aqueous durability, good flow, low glass transition temperature and low coefficient of thermal expansion.

Abstract translation: 描述适用于玻璃料生产密封玻璃包装的无锑玻璃。 通过提供第一玻璃基板和第二玻璃基板并将无锑玻璃料沉积到第一基板上来制造诸如OLED显示装置的密封玻璃封装。 OLED可以沉积在第二玻璃基板上。 然后使用照射源（例如，激光，红外光）来加热玻璃料，其熔化并形成将第一玻璃基板与第二玻璃基板连接的气密密封，并且也保护OLED。 无锑玻璃具有优异的水性耐久性，良好的流动性，低的玻璃化转变温度和低的热膨胀系数。

公开(公告)号：WO2014085379A1

公开(公告)日：2014-06-05

申请号：PCT/US2013/071845

申请日：2013-11-26

Applicant: CORNING INCORPORATED ,  BORRELLI, Nicholas Francis ,  DRAKE, Melinda Ann ,  MORENA, Robert Michael

Inventor： BORRELLI, Nicholas Francis ,  DRAKE, Melinda Ann ,  MORENA, Robert Michael

IPC: C03C3/085 ,  C03C3/089 ,  C03C3/093 ,  C03C3/097 ,  C03C8/02 ,  C03C8/04 ,  C03C8/08 ,  C03C14/00 ,  C03C17/04

CPC classification number: A01N59/20 ,  A01N59/16 ,  C03C3/085 ,  C03C3/089 ,  C03C3/093 ,  C03C3/097 ,  C03C8/02 ,  C03C8/04 ,  C03C8/08 ,  C03C14/006 ,  C03C17/04 ,  C03C2204/02 ,  C03C2214/16 ,  C03C2217/452 ,  C03C2217/479 ,  C03C2218/324

Abstract: Articles have a glass layer on a substrate. The glass layer has antimicrobial properties via a metal or metal alloy. The glass layer is made using a doped glass frit which may be deposited by screen printing. The CTE of the glass layer and the substrate can be matched.

Abstract translation: 制品在基材上具有玻璃层。 玻璃层通过金属或金属合金具有抗菌性能。 玻璃层使用可通过丝网印刷沉积的掺杂玻璃料制成。 可以匹配玻璃层和基板的CTE。

公开(公告)号：WO2014035954A3

公开(公告)日：2014-03-06

申请号：PCT/US2013/056780

申请日：2013-08-27

Applicant: CORNING INCORPORATED ,  DRAKE, Melinda Ann ,  MORENA, Robert Michael

Inventor： DRAKE, Melinda Ann ,  MORENA, Robert Michael

IPC: C03C3/21 ,  C03C8/24 ,  H01L51/52

Abstract: An antimony-free glass comprising TeO 2 and/or Bi 2 O 3 suitable for use in a frit for producing a hermetically sealed glass package is described. The hermetically sealed glass package, such as an OLED display device, is manufactured by providing a first glass substrate plate and a second glass substrate plate and depositing the antimony-free frit onto the first substrate plate. OLEDs may be deposited on the second glass substrate plate. An irradiation source (e.g., laser, infrared light) is then used to heat the frit which melts and forms a hermetic seal that connects the first glass substrate plate to the second glass substrate plate and also protects the OLEDs disposed therein. The antimony-free glass has excellent aqueous durability, good flow, and low glass transition temperature.

公开(公告)号：WO2014014798A1

公开(公告)日：2014-01-23

申请号：PCT/US2013/050442

申请日：2013-07-15

Applicant: CORNING INCORPORATED ,  COMTE, Marie Jacqueline Monique ,  DRAKE, Melinda Ann ,  GEISINGER, Karen Leslie ,  GOMEZ, Sinue ,  MORENA, Robert Michael ,  SMITH, Charlene Marie ,  YOUNGMAN, Randall Eugene

Inventor： COMTE, Marie Jacqueline Monique ,  DRAKE, Melinda Ann ,  GEISINGER, Karen Leslie ,  GOMEZ, Sinue ,  MORENA, Robert Michael ,  SMITH, Charlene Marie ,  YOUNGMAN, Randall Eugene

IPC: C03C3/083 ,  C03C3/085 ,  C03C3/087 ,  C03C3/089 ,  C03C3/091 ,  C03C3/093 ,  C03C3/097 ,  C03C21/00

CPC classification number: C03C3/097 ,  C03C3/083 ,  C03C3/085 ,  C03C3/087 ,  C03C3/089 ,  C03C3/091 ,  C03C3/093 ,  C03C4/18 ,  C03C21/002 ,  Y10T428/315

Abstract: According to one embodiment, a glass article may include SiO 2 , Al 2 O 3 , Li 2 O and Na 2 O. The glass article may have a softening point less than or equal to about 810°C. The glass article may also have a high temperature CTE less than or equal to about 27x10 -6 /°C. The glass article may also be ion exchangeable such that the glass has a compressive stress greater than or equal to about 600 MPa and a depth of layer greater than or equal to about 25 μm after ion exchange in a salt bath comprising KNO 3 at a temperature in a range from about 390°C to about 450°C for less than or equal to approximately 15 hours.

Abstract translation: 根据一个实施方案，玻璃制品可以包括SiO 2，Al 2 O 3，Li 2 O和Na 2 O。 玻璃制品可具有小于或等于约810℃的软化点。 玻璃制品也可以具有小于或等于约27×10 -6 /℃的高温CTE。 玻璃制品也可以是可离子交换的，使得玻璃具有大于或等于约600MPa的压缩应力，并且在包含KNO 3的盐浴中的温度在离子交换后的层的深度大于或等于约25μm 在约390℃至约450℃的范围内小于或等于约15小时。