公开(公告)号：WO2018005318A1

公开(公告)日：2018-01-04

申请号：PCT/US2017/039191

申请日：2017-06-26

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  ROHM AND HAAS ELECTRONIC MATERIALS LLC

Inventor： SOKOLOV, Anatoliy N. ,  GOODFELLOW, Brian ,  GRIGG, Robert David ,  SPENCER, Liam P. ,  KRAMER, John W. ,  DEVORE, David D. ,  MUKHOPADHYAY, Sukrit ,  TREFONAS, Peter

IPC: H01L51/54

Abstract: The present invention provides a quantum dot light emitting diode comprising i) an emitting layer of at least one semiconductor nanoparticle made from semiconductor materials selected from the group consisting of Group II- VI compounds, Group II-V compounds, Group III- VI compounds, Group III-V compounds, Group IV- VI compounds, Group I-III- VI compounds, Group II-IV-VI compounds, Group II-IV-V compounds, or any combination thereof; and ii) a polymer for hole injection or hole transport layer; and the polymer comprises, as polymerized units, at least one or more monomers having a first monomer structure comprising a) a polymerizable group, b) an electroactive group with formula NAr 1 Ar 2 Ar 3 wherein Ar 1 , Ar 2 and Ar 3 independently are C 6 -C 50 aromatic substituents, and (c) a linker group connecting the polymerizable group and the electroactive group.

Abstract translation: 本发明提供了一种量子点发光二极管，该量子点发光二极管包括i）至少一个半导体纳米粒子的发光层，该半导体纳米粒子由选自II-VI族化合物，II-V族 化合物，III-VI族化合物，III-V族化合物，IV-VI族化合物，I-III-VI族化合物，II-IV-VI族化合物，II-IV-V族化合物或其任何组合; 和ii）用于空穴注入或空穴传输层的聚合物; 并且所述聚合物包含作为聚合单元的至少一种或多种具有第一单体结构的单体，所述第一单体结构包含a）可聚合基团，b）式NAr 1 Ar 2 2的电活性基团， 其中Ar 1，Ar 2和Ar 3独立地为C≡6，其中Ar 1，Ar 2和Ar 3独立地为C 1 -C 6烷基， （c）连接可聚合基团和电活性基团的连接基团。

公开(公告)号：WO2018085056A1

公开(公告)日：2018-05-11

申请号：PCT/US2017/057495

申请日：2017-10-20

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： GRIGG, Robert David ,  SPENCER, Liam P. ,  KRAMER, John W. ,  DEVORE, David D. ,  GOODFELLOW, Brian ,  LIU, Chun ,  MUKHOPADHYAY, Sukrit ,  PETERSON, Thomas H. ,  WOODWARD, William H. H. ,  SOKOLOV, Anatoliy N.

IPC: H01L51/54

CPC classification number: H01L51/5056 ,  H01L51/5088

Abstract: Provided is an organic light-emitting diode comprising a substrate, an anode layer, optionally one or more hole injection layers, one or more hole transport layers, optionally one or more electron blocking layers, an emitting layer, optionally one or more hole blocking layers, optionally one or more electron transport layers, an electron injection layer, and a cathode, wherein either the hole injection layer, or the hole transport layer, or both of the hole injection layer and the hole transport layer, or a layer that functions as both a hole injection layer and a hole transport layer, comprises a polymer that comprises one or more triaryl aminium radical cations having the structure (S1 ) wherein each of R 11 , R 12 , R 13 , R 14 , R 15 , R 21 , R 22 , R 23 , R 24 , R 25 , R 31 , R 32 , R 33 , R 34 , and R 35 is independently selected from the group consisting of hydrogen, deuterium halogens, amine groups, hydroxyl groups, sulfonate groups, nitro groups, and organic groups, wherein two or more of R 11 , R 12 , R 13 , R 14 , R 15 , R 21 , R 22 , R 23 , R 24 , R 25 , R 31 ; R 32 ; R 33 R 34 and R 35 are optionally connected to each other to form a ring structure; wherein one or more of R11, R 12 , R 13 , R 14 , R 15 , R 21 , R 22 , R 23 , R 24 , R 25 , R 31 , R 32 , R 33 , R 34 , and R 35 is covalently bound to the polymer, and wherein A" is an anion.

Abstract translation: 提供了一种有机发光二极管，其包括衬底，阳极层，任选的一个或多个空穴注入层，一个或多个空穴传输层，任选的一个或多个电子阻挡层，发光层 ，任选的一个或多个空穴阻挡层，任选的一个或多个电子传输层，电子注入层和阴极，其中空穴注入层或空穴传输层或空穴注入层和空穴传输层 层或用作空穴注入层和空穴传输层两者的层包含聚合物，所述聚合物包含一种或多种具有结构（S1）的三芳基铵自由基阳离子，其中每个R 11， R 12，R 13，R 14，R 15，R 21， R 22，R 23，R 24，R 25，R 31， R 32，R 33，R 34和R 35独立地选自fr 在由氢，氘卤素，胺基，羟基，磺酸酯基，硝基和有机基团组成的组中，其中R 11，R 12和R 12中的两个或更多个是氢， ，R 13，R 14，R 15，R 21，R 22， ，R 23，R 24，R 25，R 31， [R ^{32 ; R 33，R 34和R 35任选彼此连接形成环结构; 其中R 11，R 12，R 13，R 14，R 15，R sup中的一个或多个 > 21，R 22，R 23，R 24，R 25，R sup > 31，R 32，R 33，R 34和R 35共价结合 到聚合物，并且其中A“ 是一个阴离子。}

公开(公告)号：WO2018000175A1

公开(公告)日：2018-01-04

申请号：PCT/CN2016/087408

申请日：2016-06-28

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  ROHM AND HAAS ELECTRONIC MATERIALS LLC ,  GRIGG, David D. ,  SPENCER, Liam P. ,  KRAMER, John W. ,  LIU, Chun ,  DEVORE, David D. ,  FENG, Shaoguang ,  FENG, Jichang ,  ZHU, Minrong ,  LI, Yang ,  MUKHOPADHYAY, Sukrit ,  SOKOLOV, Anatoliy N. ,  REMY, Matthew S. ,  TREFONAS, Peter ,  NEILSON, Bethany

Inventor： GRIGG, David D. ,  SPENCER, Liam P. ,  KRAMER, John W. ,  LIU, Chun ,  DEVORE, David D. ,  FENG, Shaoguang ,  FENG, Jichang ,  ZHU, Minrong ,  LI, Yang ,  MUKHOPADHYAY, Sukrit ,  SOKOLOV, Anatoliy N. ,  REMY, Matthew S. ,  TREFONAS, Peter ,  NEILSON, Bethany

IPC: C08F26/02 ,  C08F26/06 ,  H01L51/50

CPC classification number: H01L51/0039 ,  C08F12/22 ,  C08F12/26 ,  C08F12/32 ,  C08F12/34 ,  C08F112/14 ,  C08F112/32 ,  C09D5/24 ,  C09D125/18 ,  H01L51/0035 ,  H01L51/0043 ,  H01L51/5056

Abstract: A polymer which has M n at least 4,000 and comprises polymerized units of a compound of formula NAr 1 Ar 2 Ar 3 , wherein Ar 1 , Ar 2 and Ar 3 independently are C 6 -C 40 aromatic substituents; Ar 1 , Ar 2 and Ar 3 collectively contain no more than one nitrogen atom and at least one of Ar 1 , Ar 2 and Ar 3 contains a vinyl group attached to an aromatic ring..

Abstract translation: 具有至少4,000的M n且包含式NAr 1 Ar 2 2化合物的聚合单元的聚合物， Ar 3，其中Ar 1，Ar 2和Ar 3独立地为C≡6， 亚芳基取代基; -C芳基取代基; Ar 1，Ar 2和Ar 3共同含有不多于一个氮原子和至少一个Ar 1 / sup Ar 2和Ar 3含有与芳香环连接的乙烯基。＆lt; / p>

公开(公告)号：WO2018085055A1

公开(公告)日：2018-05-11

申请号：PCT/US2017/057494

申请日：2017-10-20

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： GRIGG, Robert David ,  SPENCER, Liam P. ,  KRAMER, John W. ,  DEVORE, David D. ,  GOODFELLOW, Brian ,  LIU, Chun ,  MUKHOPADHYAY, Sukrit ,  PETERSON, Thomas H. ,  WOODWARD, William H. H. ,  SOKOLOV, Anatoliy N.

IPC: H01L51/54

Abstract: Provided is an organic light-emitting diode comprising a substrate, an anode layer, optionally one or more hole injection layers, one or more hole transport layers, optionally one or more electron blocking layers, an emitting layer, optionally one or more hole blocking layers, optionally one or more electron transport layers, an electron injection layer, and a cathode, wherein either the hole injection layer, or the hole transport layer, or both of the hole injection layer and the hole transport layer, or layer that functions as both a hole injection layer and a hole transport layer, comprises a polymer that comprises one or more triaryl aminium radical cations having the structure (S1) wherein each of R 11 , R 12 , R 13 , R 14 , R 15 , R 21 , R 22 , R 23 , R 24 , R 25 , R 31 , R 32 , R 33 , R 34 , and R 35 is independently selected from the group consisting of hydrogen, deuterium halogens, amine groups, hydroxyl groups, sulfonate groups, nitro groups, and organic groups, wherein two or more of R 11 , R 12 , R 13 , R 14 , R 15 , R 21 , R 22 , R 23 , R 24 , R 25 , R 31 , R 32 , R 33 , R 34 , and R 35 are optionally connected to each other to form a ring structure; wherein one or more of R 11 , R 12 , R 13 , R 14 , R 15 , R 21 , R 22 , R 23 , R 24 , R 25 , R 31 , R 32 , R 33 , R 34 , and R 35 is covalently bound to the polymer, and wherein A is an anion.

Abstract translation: 提供了一种有机发光二极管，其包括衬底，阳极层，任选的一个或多个空穴注入层，一个或多个空穴传输层，任选的一个或多个电子阻挡层，发光层 ，任选的一个或多个空穴阻挡层，任选的一个或多个电子传输层，电子注入层和阴极，其中空穴注入层或空穴传输层或空穴注入层和空穴传输层 层或用作空穴注入层和空穴传输层两者的层包含聚合物，所述聚合物包含一种或多种具有结构（S1）的三芳基铵自由基阳离子，其中每个R 11，R R 12，R 14，R 14，R 15，R 21，R，R 21， 22，R 23，R 24，R 25，R 31，R 1，R 3，R 5， R 32，R 33，R 34和R 35独立地选自 由氢，氘卤素，胺基，羟基，磺酸酯基，硝基和有机基团组成的基团，其中两个或多个R 11，R 12， R 13，R 14，R 15，R 21，R 22， R 23，R 24，R 25，R 31，R 32， R 33，R 34和R 35任选彼此连接形成环结构; 其中R 11，R 12，R 13，R 14，R 15中的一个或多个 R 21，R 22，R 23，R 24，R 25， R 31，R 32，R 33，R 34和R 51，其中R 31，R 32， 35与共聚物共价结合，其中A是阴离子。

公开(公告)号：WO2018000180A1

公开(公告)日：2018-01-04

申请号：PCT/CN2016/087414

申请日：2016-06-28

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  ROHM AND HAAS ELECTRONIC MATERIALS KOREA LTD. ,  ROHM AND HAAS ELECTRONIC MATERIALS LLC ,  GRIGG, David D. ,  SPENCER, Liam P. ,  KRAMER, John W. ,  LIU, Chun ,  DEVORE, David D. ,  FENG, Shaoguang ,  FENG, Jichang ,  ZHU, Minrong ,  LI, Yang ,  MUKHOPADHYAY, Sukrit ,  SOKOLOV, Anatoliy N. ,  REMY, Matthew S. ,  TREFONAS, Peter ,  NEILSON, Bethany

Inventor： GRIGG, David D. ,  SPENCER, Liam P. ,  KRAMER, John W. ,  LIU, Chun ,  DEVORE, David D. ,  FENG, Shaoguang ,  FENG, Jichang ,  ZHU, Minrong ,  LI, Yang ,  MUKHOPADHYAY, Sukrit ,  SOKOLOV, Anatoliy N. ,  REMY, Matthew S. ,  TREFONAS, Peter ,  NEILSON, Bethany

IPC: H01L51/54 ,  C09K11/06

CPC classification number: H01L51/5056 ,  C08G61/12 ,  C08G2261/135 ,  C08G2261/1414 ,  C08G2261/148 ,  C08G2261/226 ,  C08G2261/3162 ,  C08G2261/411 ,  C08G2261/512 ,  C08G2261/76 ,  C08G2261/95 ,  H01L51/004 ,  H01L51/0042 ,  H01L51/0043 ,  H01L51/50 ,  H01L51/5088

Abstract: A polymer which has M n at least 4,000 and comprises polymerized units of a compound of formula NAr 1 Ar 2 Ar 3 ,wherein Ar 1 ,Ar 2 and Ar 3 independently are C 6 -C 50 aromatic substituents;Ar 1 ,Ar 2 and Ar 3 collectively contain at least two nitrogen atoms and at least 9 aromatic rings; and at least one of Ar 1 ,Ar 2 and Ar 3 contains a vinyl group attached to an aromatic ring.

Abstract translation: 具有至少4,000的M n且包含式NAr 1 Ar 2 2化合物的聚合单元的聚合物， Ar 3，其中Ar 1，Ar 2和Ar 3独立地为C≡6， C 5 -C 50芳族取代基; Ar 1，Ar 2和Ar 3共同含有至少两个氮原子 原子和至少9个芳香环; 并且Ar 1，Ar 2和Ar 3中的至少一个含有连接到芳环上的乙烯基。

公开(公告)号：WO2018084899A1

公开(公告)日：2018-05-11

申请号：PCT/US2017/039188

申请日：2017-06-26

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  ROHM AND HAAS ELECTRONIC MATERIALS LLC

Inventor： SOKOLOV, Anatoliy N. ,  GOODFELLOW, Brian ,  GRIGG, Robert David ,  SPENCER, Liam P. ,  KRAMER, John W. ,  DEVORE, David D. ,  MUKHOPADHYAY, Sukrit ,  TREFONAS, Peter

IPC: H01L51/50

Abstract: The present invention provides a quantum dot light emitting diode comprising i) an emitting layer of at least one semiconductor nanoparticle made from semiconductor materials selected from the group consisting of Group II-VI compounds, Group II-V compounds, Group III-VI compounds, Group III-V compounds, Group IV-VI compounds, Group I-III-VI compounds, Group II-IV-VI compounds, Group II-IV-V compounds, or any combination thereof; and ii) a polymer for hole injection or hole transport layer, comprising one or more triaryl aminium radical cations having the structure (S1).

Abstract translation: 本发明提供了一种量子点发光二极管，该量子点发光二极管包括i）由选自II-VI族化合物，II-V族半导体材料的半导体材料制成的至少一个半导体纳米颗粒的发光层 化合物，III-VI族化合物，III-V族化合物，IV-VI族化合物，I-III-VI族化合物，II-IV-VI族化合物，II-IV-V族化合物或其任意组合。 和ii）用于空穴注入或空穴传输层的聚合物，其包含一种或多种具有结构（S1）的三芳基铵自由基阳离子。

公开(公告)号：WO2018000177A1

公开(公告)日：2018-01-04

申请号：PCT/CN2016/087410

申请日：2016-06-28

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  ROHM AND HAAS ELECTRONIC MATERIALS KOREA LTD. ,  ROHM AND HAAS ELECTRONIC MATERIALS LLC ,  DEVORE, David D. ,  DOH, Yoo Jin ,  FENG, Shaoguang ,  GRIGG, David D. ,  LI, Yang ,  LIU, Chun ,  MUKHOPADHYAY, Sukrit ,  NA, Hong-Yeop ,  REMY, Matthew S. ,  SPENCER, Liam P. ,  SOKOLOV, Anatoliy N. ,  TREFONAS, Peter ,  ZHU, Minrong ,  INMAN, Ashley ,  KRAMER, John W.

Inventor： DEVORE, David D. ,  DOH, Yoo Jin ,  FENG, Shaoguang ,  GRIGG, David D. ,  LI, Yang ,  LIU, Chun ,  MUKHOPADHYAY, Sukrit ,  NA, Hong-Yeop ,  REMY, Matthew S. ,  SPENCER, Liam P. ,  SOKOLOV, Anatoliy N. ,  TREFONAS, Peter ,  ZHU, Minrong ,  INMAN, Ashley ,  KRAMER, John W.

IPC: H05B33/14 ,  H05B33/12 ,  H05B33/10 ,  C09K11/06 ,  H01L51/50 ,  H01L27/32

CPC classification number: H01L51/0035 ,  C07D209/82 ,  H01L51/00 ,  H01L51/0007 ,  H01L51/0034 ,  H01L51/006 ,  H01L51/0072 ,  H01L51/5056 ,  H01L51/5072

Abstract: A single liquid phase formulation useful for producing an organic charge transporting film. The formulation contains: (a) a polymer having M n at least 4,000 and comprising polymerized units of a compound of formula NAr 1 Ar 2 Ar 3 , wherein Ar 1 , Ar 2 and Ar 3 independently are C 6 -C 50 aromatic substituents and at least one of Ar 1 , Ar 2 and Ar 3 contains a vinyl group attached to an aromatic ring; provided that said compound contains no arylmethoxy linkages; (b) an acid catalyst which is is an organic Bronsted acid with pKa≤4; a Lewis acid comprising a positive aromatic ion and an anion which is (i) a tetraaryl borate having the formula (I) wherein R represents zero to five non-hydrogen substituents selected from D, F and CF 3 , (ii) BF 4 - , (iii) PF 6 - , (iv) SbF 6 - , (v) AsF 6 - or (vi) ClO 4 - ; or a thermal acid generator.

Abstract translation: 可用于制备有机电荷输送膜的单一液相制剂。 该制剂含有：（a）M n为至少4,000的聚合物，其包含式NAr 1 Ar 2 Ar的化合物的聚合单元 其中Ar 1，Ar 2和Ar 3独立地为C≡6，其中Ar 1，Ar 2和Ar 3独立地为C 6， -C≡50芳族取代基和Ar 1，Ar 2和Ar 3中的至少一个含有乙烯基基团 连接到芳香环上; 条件是所述化合物不含芳基甲氧基键; （b）酸催化剂，其是pKa≤4的有机布朗斯台德酸; （i）具有式（I）的四芳基硼酸酯，其中R表示0至5个选自D，F和CF 3的非氢取代基的阴离子， ，（ii）BF 4 -4，（iii）PF 6 -p-，（iv）SbF 4， （v）AsF6-O-或（vi）ClO4- / sup- - ; 或热酸发生器。