公开(公告)号：WO2008118494A3

公开(公告)日：2009-03-19

申请号：PCT/US2008004080

申请日：2008-03-27

Applicant: DU PONT ,  ACOSTA ERICK JOSE ,  REINARTZ STEFAN

Inventor： ACOSTA ERICK JOSE ,  REINARTZ STEFAN

IPC: C07C229/08 ,  C07C229/12 ,  C07C229/24 ,  C08K5/17 ,  C08K5/19 ,  C09D7/47

CPC classification number: B01F17/0035 ,  C07C229/08 ,  C07C229/12 ,  C07C229/24 ,  C08K5/17

Abstract: A composition of formula (I) wherein m and d are each independently an integer of 1 or 2; n is independently O or 1;each R is independently hydrogen or a C1 to C4 alkyl group; A is independently hydrogen or -C(O)-O-B;Ro is a linear, branched or cyclic aliphatic group, or combination thereof, having from about 2 to about 100 carbon atoms, interrupted or substituted by 1 to about 50 hydrophilic groups, said hydrophilic groups selected from the group consisting of hydroxyl, amino, ether and mixtures thereof; wherein the ratio of hydrophilic groups to carbon atoms is from about 1 :1.1 to about 1 : 10, each carbon atom has at most one hydrophilic group bonded to it, and covalent bonding between hydrophilic groups is absent; each B is independently a monovalent group of formula (IIa), (IIb) or (IIc): (IIa) Rf 1(CH2)t(R)r- (lib) Rf 2(CH2CF2)p(CH2CH2)q(R1)r- (lie) Rf 3O(CF2CF2)p(CH2CH2)q(R1)r- wherein each of Rf 1 and Rf 2 are C1 - C6 linear or branched perfluoroalkyl; Rf 3 is a C1 to C7 linear or branched perfluoroalkyl group, optionally interrupted by one, two or three ether oxygen atoms; t is an integer of 1 to about 10; p and q are each independently integers of 1 to about 3; r is 0 or 1; R1 is a divalent radical selected from -S(CH2)r; and provided that when m is 1, n is 1; when m is 2, n is 0, A is hydrogen, and d is 1; and when d is 2, m is 1, A is -C(O)-O-B, R0has at least three carbon atoms, and nitrogens and hydrophilic groups are bonded to different carbon atoms, and its use as a surfactant is disclosed.

Abstract translation: 式（I）的组合物，其中m和d各自独立地为1或2的整数; n独立地为O或1;每个R独立地为氢或C 1至C 4烷基; A独立地是氢或-C（O）-OB; R o是具有约2至约100个碳原子的直链，支链或环状脂族基团或其组合，被1至约50个亲水基团间隔或取代，所述 选自羟基，氨基，醚及其混合物的亲水基团; 其中亲水基团与碳原子的比率为约1:1.1至约1:10，每个碳原子具有至多一个与其键合的亲水基团，并且不存在亲水基团之间的共价键; 每个B独立地是式（IIa），（IIb）或（IIc）的单价基团：（IIa）Rf 1（CH2）t（R）r-（lib）Rf2（CH2CF2）p（CH2CH2）q ）Rf（Rf）3 O（CF 2 CF 2）p（CH 2 CH 2）q（R 1）r - ，其中R f 1和R f 2各自为C 1 -C 6直链或支链全氟烷基; Rf 3是C1至C7直链或支链全氟烷基，任选地被一个，两个或三个醚氧原子间隔开; t为1〜10的整数; p和q各自独立地为1至约3的整数; r为0或1; R1是选自-S（CH2）r的二价基团; 并且条件是当m为1时，n为1; 当m为2时，n为0，A为氢，d为1; 当d为2时，m为1，A为-C（O）-O-B，R 0为至少3个碳原子，并且氮和亲水基团键合到不同的碳原子上，并且其用作表面活性剂。

公开(公告)号：WO2009020912A3

公开(公告)日：2009-04-09

申请号：PCT/US2008072090

申请日：2008-08-04

Applicant: DU PONT ,  ACOSTA ERICK JOSE ,  TAYLOR CHARLES KENNETH

Inventor： ACOSTA ERICK JOSE ,  TAYLOR CHARLES KENNETH

IPC: C07F9/09 ,  C11D1/34

CPC classification number: C07F9/091 ,  C11D1/004 ,  C11D1/345

Abstract: A compound of Formula 1 Rf-A-OP(O)(O" M +)(O-RH) Formula 1 wherein Rf is a C2 to CQ linear or branched perfluoroalkyl optionally interrupted by one, two or three ether oxygen atoms; A is (CH2CF2)m(CH2)n-, (CH2)OSO2N(CH3)(CH2)P-, O(CF2)q(CH2)n or OCHFCF2OE-; m is 1 to 4; n, o, p, and r are each independently 2 to 20; q is 2; E is a C2 to C2Q linear or branched alkyl group optionally interrupted by oxygen, sulfur, or nitrogen atoms; a cyclic alkyl group, or a CQ to Ci o ary' group; M is a Group I metal or an ammonium cation (NHxR^y)+ wherein R2 is a Ci to C4 alkyl, x is 1 to 4, y is O to 3 and x + y is 4; and RH is a Ci to C2o linear, branched, or cyclic alkyl, or a CQ to C10 aryl, and its use as a surfactant is disclosed.

Abstract translation: 式1的化合物Rf-A-OP（O）（O“M +）（O-RH）式1其中Rf是任选被一个，两个或三个醚氧原子间隔的C2至CQ直链或支链全氟烷基; A 是（CH 2 CF 2）m（CH 2）n - ，（CH 2）OSO 2 N（CH 3）（CH 2）P - ，O（CF 2）q（CH 2）n或OCHFCF 2 OE-; m是1至4; n，o，p和 r各自独立地为2至20; q为2; E为任选被氧，硫或氮原子间隔的C2至C2Q直链或支链烷基;环状烷基或C 1 -C 10芳基; M 是I族金属或铵阳离子（NH x R y y）+，其中R 2是C 1至C 4烷基，x为1至4，y为0至3，x + y为4;且RH为C 1至C 20直链 ，支链或环状烷基，或C 10〜C 10芳基，及其作为表面活性剂的用途。

公开(公告)号：WO2009020906A2

公开(公告)日：2009-02-12

申请号：PCT/US2008072082

申请日：2008-08-04

Applicant: DU PONT ,  TAYLOR CHARLES KENNETH ,  MICHALCZYK MICHAEL JOSEPH ,  ACOSTA ERICK JOSE

Inventor： TAYLOR CHARLES KENNETH ,  MICHALCZYK MICHAEL JOSEPH ,  ACOSTA ERICK JOSE

IPC: C07F7/18 ,  C07C43/13 ,  C07C309/65 ,  C07F9/09 ,  C11D1/34

CPC classification number: C07C69/675 ,  C07C43/137 ,  C07C309/65 ,  C07F7/0852 ,  C07F7/1804 ,  C07F9/091 ,  C11D1/004

Abstract: A surfactant of formula (1) A surfactant of formula 1 (Rf-A)a- Q- ([B]k-R)b Formula 1 wherein a and b are each independently 1 or 2; Rf is a linear or branched perfluoroalkyl radical having from 2 to about 20 carbon atoms, optionally interrupted with at least one oxygen; R is a C1 to C20 linear, branched or cyclic alkyl, or a C6 to C10 aryl; B is -(CH2CHR1O)x-, k is 0 or 1, x is 1 to about 20, A is -(CH2)m[(CHR1 CH2O)]S - [(CH2)m (CH)tCHOH(CH2)m]e-, wherein each m is independently 0 to 3, s is 0 to about 30, t is 0 or 1, and e is 0 or 1, R1 is H or CH3, Q is: -OP(O)(O-M+)(O)-, -O-, -S-(CH2)m-C(O)-O-, -SO2-O- -CH2CH2O-C(O)CH2C(OH)(V)CH2C(O)O-; -(CH2CH2O)xCH2CH(OH)-(CH2CH2O)?-(CH2)m- Si[OSi(R2)3]2 -, -SO2NR2- -(CH2CH2O)ZC(O)CH(SO3-M+)CH2C(O)(OCH2CH2)Z - wherein z is 1 to about 15, or a bond when s is a positive integer, V is -C(O)OR3and R3 is H, CH3 or Rf; R2 is C1 to C4 alkyl, and M+ is a Group 1 metal or an ammonium (NHxR2y)+ cation wherein x + y = 4, and R2 is C1 to C4 alkyl, provided that when Q is -OP(O)(O-M+)(O)- or when Q is - (CH2CH2O)Z-C(O)CH(SO3-M+)CH2C(O)(OCH2CH2)Z- then at least one of s or e is a positive integer.

Abstract translation: 式（1）的表面活性剂式1的表面活性剂（Rf-A）a-Q-（[B] k-R）b式1其中a和b各自独立地为1或2; R f是具有2至约20个碳原子的直链或支链全氟烷基，任选地被至少一个氧中断; R为C1至C20直链，支链或环状烷基或C6至C10芳基; B是 - （CH 2 CHR 10）x - ，k是0或1，x是1至约20，A是 - （CH 2）m - [（CH 2 CH 2 O） 其中每个m独立地为0至3，s为0至约30，t为0或1，并且e为0或1，R 1为H或CH 3，Q为：-OP（O）（O- （O）-O-，-S-（CH 2）m -C（O）-O-，-SO 2 -O- -CH 2 CH 2 O-C（O）CH 2 C（OH） ; - （CH 2 CH 2 O）x CH 2 CH（OH） - （CH 2 CH 2 O）2 - （CH 2）m -Si [OSi（R 2）3] 2 - ， - SO 2 NR 2 - （CH 2 CH 2 O）ZC（O）CH（SO 3 - M +）CH 2 C ）（OCH 2 CH 2）z - ，其中z为1至约15，或者当s为正整数时为键，V为-C（O）OR 3且R 3为H，CH 3或R f; 条件是当Q为-OP（O）（O-甲基）时，R2为C1-C4烷基，M +为1族金属或铵（NHxR2y）+阳离子，其中x + y = 4，R2为C1- （O） - 或当Q是 - （CH2CH2O）ZC（O）CH（SO3-M +）CH2C（O）（OCH2CH2）Z-时，则s或e中的至少一个是正整数。

公开(公告)号：WO2007035936A3

公开(公告)日：2007-06-14

申请号：PCT/US2006037325

申请日：2006-09-22

Applicant: DU PONT ,  ACOSTA ERICK JOSE ,  MURPHY PETER MICHAEL ,  MCCALL ANDREW JOSEPH ,  SWOREN JOHN CHRISTOPHER

Inventor： ACOSTA ERICK JOSE ,  MURPHY PETER MICHAEL ,  MCCALL ANDREW JOSEPH ,  SWOREN JOHN CHRISTOPHER

IPC: C08G63/00 ,  C07D249/04

CPC classification number: C07D249/04 ,  C08F220/18 ,  C08F220/34

Abstract: A copolymer for imparting repellency and stain resistance to substrates is disclosed of Formula 1 [R f -X 1 -A-X 1 -Y-C(O)-CZCH 2 ]m-[W q ]p Formula 1 wherein R f is a straight or branched perfluoroalkyl group having from about 2 to about 20 carbon atoms, or a mixture thereof, which is optionally interrupted by at least one oxygen atom, each X 1 is independently an organic divalent linking group having from about 1 to about 20 carbon atoms, optionally containing a triazole, oxygen, nitrogen, or sulfur, or a combination thereof., A is a 1, 2, 3-triazole, Y is O or N(R) 2 wherein R is H or C 1 to C 20 alkyl, Z is H, a straight or branched alkyl group having from about 1 to about 4 carbon atoms, or halide, m is a positive integer, q is zero or a positive integer, p is zero or a positive integer, and W is insert W here wherein X 1 , Y, and Z are as defined above, Rx is C(O)O(R 1 ), C(O)N(R 2 ) 2 , OC(O)(R 1 ), SO 2 (R 1 ), C 6 (R 3 ) 5 , O(R 1 ), halide, or R 1 ; each R 1 is independently H, C N H 2n+1 , C n H 2n -CH(O)CH 2 , [CH 2 CH 2 O] i R 4 , [C n C 2n ]N(R 4 ) 2 or [C n H 2n ]C n F 2n+1 , n is 1 to 40, R 4 is H or C s H 2s+1 , s = 0 to 40, i = 1 to 200, each R 2 is independently H, or C t H 2t+1 wherein t is 1 to 20, each R 3 is independently H, COOR 1 , halogen, N(R 1 ) 2 , OR 1 , SO 2 NHR 1 , CH=CH 2 , or SO 3 M, M is H, alkali metal salt, alkaline earth metal salt, or ammonium.

Abstract translation: 公开了一种用于赋予基材防排斥性和抗污染性的共聚物。式1 [R 1-X 1 -Z 1 -Y 1 -Y C（O） 其中R 1是直链或支链全氟烷基，其具有约2至约2个碳原子的直链或支链全氟烷基 20个碳原子或其混合物，其任选被至少一个氧原子间隔，每个X 1独立地为具有约1至约20个碳原子的有机二价连接基团，任选地含有 三唑，氧，氮或硫，或其组合，A是1,2,3,4-三唑，Y是O或N（R）2，其中R是H或C _{C 1至C 20烷基，Z为H，具有约1至约4个碳原子的直链或支链烷基或卤素，m为正整数，q为零 或正整数，p为零或正整数，W为插入W，其中X 1，Y和Z如上所定义，Rx为C（O）O（R 0 > 1 1），卤化物或R 1; 每个R 1独立地为H，C N H 2n + 1，C H n H 2n， -CH（O）CH 2，[CH 2 CH 2 CH 2 O] n R O > 4 ，N（R 4）2 N 2或[C n n 2n + 1 n，n为1至40，R 4为 H或C 2 H 2 s + 1，s = 0至40，i = 1至200，每个R 2 = 独立地是H或C 1 H 2t + 1，其中t为1至20，每个R 3独立地为H，COOR 1，卤素，N（R 1）2，或1，SO 2，NHR， CH 2 CH 2 CH 2，SO 3 M，M是H，碱金属盐，碱土金属盐或铵。}