OLEFIN POLYMERIZATION PROCESS
    3.
    发明申请
    OLEFIN POLYMERIZATION PROCESS 审中-公开
    OLEFIN聚合方法

    公开(公告)号:WO2005040237A1

    公开(公告)日:2005-05-06

    申请号:PCT/US2004/033062

    申请日:2004-10-07

    IPC分类号: C08F10/00

    摘要: A process for polymerizing olefins is disclosed. The process uses an organometallic complex with at least one non-bridged indenoindolyl ligand bonded to M. The substituent on the indole nitrogen contains an atom selected from the group consisting of S, O, P, and N. Polyolefins from the process have unexpectedly high molecular weight compared with polyolefins made using similar supported indenoindolyl complexes.

    摘要翻译: 公开了一种聚合烯烃的方法。 该方法使用与至少一个与M键合的至少一个非桥连茚基吲哚基配体的有机金属络合物。吲哚氮上的取代基含有选自S,O,P和N.的原子。该方法的聚烯烃意外高 分子量与使用类似支持的茚并吲哚基配合物制备的聚烯烃相比。

    OLEFIN POLYMERIZATION CATALYSTS BASED ON HYDROXYL-DEPLETED CALIXARENE LIGANDS
    5.
    发明申请
    OLEFIN POLYMERIZATION CATALYSTS BASED ON HYDROXYL-DEPLETED CALIXARENE LIGANDS 审中-公开
    基于羟基衍生的氯胺基配体的烯烃聚合催化剂

    公开(公告)号:WO2004094488A1

    公开(公告)日:2004-11-04

    申请号:PCT/US2004/006419

    申请日:2004-03-03

    发明人: NAGY, Sandor

    IPC分类号: C08F110/02

    摘要: A catalyst system useful for polymerizing olefins is disclosed. The catalyst system includes an organometallic complex that incorporates a Group 3 to 10 transition metal and a hydroxyl-depleted calixarene ligand that is chelated to the metal. Molecular modeling studies reveal that organometallic complexes incorporating such calixarene ligands, when combined with an activator such as MAO, should actively polymerize olefins.

    摘要翻译: 公开了一种可用于烯烃聚合的催化剂体系。 催化剂体系包括掺入第3至10族过渡金属的有机金属络合物和与金属螯合的羟基耗尽的杯芳烃配体。 分子建模研究表明,结合这种杯芳烃配体的有机金属配合物与活化剂如MAO组合时,应主动聚合烯烃。

    OLEFIN POLYMERIZATION CATALYSTS BASED ON CONVEX, POLYCYCLIC LIGANDS
    6.
    发明申请
    OLEFIN POLYMERIZATION CATALYSTS BASED ON CONVEX, POLYCYCLIC LIGANDS 审中-公开
    基于CONVEX,POLYCYCLIC LIGANDS的OLEFIN聚合催化剂

    公开(公告)号:WO2004076503A1

    公开(公告)日:2004-09-10

    申请号:PCT/US2004/002788

    申请日:2004-01-30

    IPC分类号: C08F10/00

    摘要: A catalyst system useful for polymerizing olefins is disclosed. The catalyst system includes an organometallic complex that incorporates a Group 3 to 10 transition metal and an anionic, polycyclic, convex ligand. Molecular modeling results indicate that the complexes, when combined with an activator, should actively polymerize olefins. The convex ligand uniquely stabilizes the active site while simultaneously minimizing steric interference. Calculations predict that complexes based on ligands with a high curvature index will have favorable reactivities with olefin monomers compared with similar complexes that incorporate Cp-like ligands.

    摘要翻译: 公开了一种可用于烯烃聚合的催化剂体系。 催化剂体系包括含有第3至10族过渡金属和阴离子多环凸配体的有机金属络合物。 分子模拟结果表明,当与活化剂组合时,络合物应主动聚合烯烃。 凸配体独特地稳定活性位点同时最小化空间干扰。 计算预测,与掺入Cp样配体的类似配合物相比,具有高曲率指数的配体的络合物将与烯烃单体具有良好的反应性。

    CATALYSTS AND PROCESS FOR MAKING POLYOLEFINS

    公开(公告)号:WO2004013194A3

    公开(公告)日:2004-02-12

    申请号:PCT/US2003/021540

    申请日:2003-07-10

    IPC分类号: C08F4/642

    摘要: A process for making ethylene copolymers is disclosed. Ethylene copolymerizes with an α-olefin in the presence of a catalyst system comprising an activator and a silica-supported, bridged indenoindolyl metal complex having "open architecture." The supported complex incorporates comonomers with exceptional efficiency, and the process gives ethylene copolymers having high molecular weights (Mw > 100K) and very low densities ( 3 ). Open architecture catalysts that include bridging through the indolyl nitrogen of the indenoindolyl framework are also described. Additionally, supported and unsupported indeno[1,2-b]indolyl catalysts provide exceptional activities in the preparation of elastomeric polypropylene and ethylene copolymers.