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    METHOD TO MANUFACTURE PLA USING A NEW POLYMERIZATION CATALYST
    4.
    发明申请
    METHOD TO MANUFACTURE PLA USING A NEW POLYMERIZATION CATALYST 审中-公开
    使用新的聚合催化剂制备PLA的方法

    公开(公告)号：WO2014177543A1

    公开(公告)日：2014-11-06

    申请号：PCT/EP2014/058688

    申请日：2014-04-29

    申请人： PURAC BIOCHEM BV

    发明人： GOBIUS DU SART, Gerrit ,  DAVIDSON, Matthew, Gwilym ,  CHUCK, Christopher, James

    IPC分类号： C08G63/82 ,  C08G63/85

    CPC分类号： C08G63/85 ,  C07F7/006 ,  C08F4/76 ,  C08F2410/03 ,  C08G18/428 ,  C08G63/08 ,  C08G63/823

    摘要： The invention relates to a method for manufacturing polylactide, comprising the steps of mixing lactide and a metal-coordination compound as polymerization catalyst to obtain a reaction mixture, polymerizing the lactide in liquid phase at a temperature of at least 150°C to form polylactide in liquid phase and allowing the polylactide to solidify, characterized in that the polymerization catalyst comprises a metal-ligand coordination compound whereby the parent ligand answers the formula (I), whereby R represents an H atom, an aliphatic group, a halide atom or a nitro group and the metal is at least one of Zr and Hf. The invented catalysts show kinetics which is comparable to the kinetics of the known Sn-octoate catalyst.

    摘要翻译： 本发明涉及一种制备聚丙交酯的方法，包括以下步骤：将丙交酯和金属配位化合物作为聚合催化剂混合以获得反应混合物，在至少150℃的温度下将丙交酯在液相中聚合以形成聚丙交酯 液相，并允许聚丙交酯固化，其特征在于聚合催化剂包含金属 - 配体配位化合物，由此母体配体应答式（I），其中R表示H原子，脂族基团，卤素原子或硝基 并且金属是Zr和Hf中的至少一种。 本发明的催化剂显示出与已知的Sn-辛酸酯催化剂的动力学相当的动力学。

    PROCESS FOR POLYMERIZING OLEFIN-BASED POLYMERS
    7.
    发明申请
    PROCESS FOR POLYMERIZING OLEFIN-BASED POLYMERS 审中-公开
    用于聚合烯烃的聚合物的方法

    公开(公告)号：WO2009088701A1

    公开(公告)日：2009-07-16

    申请号：PCT/US2008/087581

    申请日：2008-12-19

    申请人： DOW GLOBAL TECHNOLOGIES INC. ,  JORGENSEN, Robert ,  WAGNER, Burkhard ,  TURNER, Michael

    发明人： JORGENSEN, Robert ,  WAGNER, Burkhard ,  TURNER, Michael

    IPC分类号： C08F10/14 ,  C08F8/00

    CPC分类号： C08F210/16 ,  C08F10/00 ,  C08F2400/02 ,  C08F2410/03 ,  C08F4/6495 ,  C08F2/005 ,  C08F4/6457 ,  C08F2/00 ,  C08F2/34 ,  C08F210/14 ,  C08F2500/18 ,  C08F2500/12 ,  C08F2500/07 ,  C08F2500/24 ,  C08F4/6545

    摘要： A process for producing an olefin-based polymer, said process comprising polymerizing at least one monomer, in the gas phase, or in a slurry process, in the presence of at least the following components: A) at least one catalyst; B) at least one cocatalyst; C) a composition comprising at least one compound selected from formula (I), and/or at least one compound selected from formula (II): (R1CO 2 ) 2 A1OH (I), (R2) x N(R3OH) y (II); wherein R1 is a hydrocarbon radical containing from 13 to 25 carbons; R2 is a hydrocarbon radical containing from 14 to 26 carbons; R3 is a hydrocarbon radical containing from 1 to 4 carbons; and x + y = 3, and x has a value of 1 or 2. A process for producing an olefin-based polymer, said process comprising polymerizing at least one monomer in the presence of at least the following components: A) a Ziegler Natta type catalyst comprising at least two transition metals; B) a trialkylaluminum compound; C) optionally a composition comprising at least one compound selected from formula (I), and/or at least one compound selected from formula (II): (R1CO 2 ) 2 A1OH (I), (R2) x N(R3OH) y (II); wherein R1 is a hydrocarbon radical containing from 13 to 25 carbons; R2 is a hydrocarbon radical containing from 14 to 26 carbons; R3 is a hydrocarbon radical containing from 1 to 4 carbons; and x + y = 3, and x has a value of 1 or 2.

    摘要翻译： 一种制备烯烃基聚合物的方法，所述方法包括在至少以下组分的存在下，在气相或淤浆法中聚合至少一种单体：A）至少一种催化剂; B）至少一种助催化剂; C）包含至少一种选自式（I）的化合物和/或至少一种选自式（II）的化合物：（R 1 CO 2）2 AlOH（I），（R2）xN（R3OH）y（II） ; 其中R1是含有13-25个碳原子的烃基; R2是含有14-26个碳原子的烃基; R3是含有1至4个碳的烃基; 和x + y = 3，x的值为1或2.一种制备烯烃基聚合物的方法，所述方法包括在至少以下组分存在下聚合至少一种单体：A）齐格勒纳塔 型催化剂，其包含至少两种过渡金属; B）三烷基铝化合物; C）任选的包含至少一种选自式（I）的化合物和/或至少一种选自式（II）的化合物：（R 1 CO 2）2 AlOH（I），（R2）xN（R3OH）y ）; 其中R1是含有13-25个碳原子的烃基; R2是含有14-26个碳原子的烃基; R3是含有1至4个碳的烃基; x + y = 3，x为1或2。

    BINUCLEAR CATALYST AND PROCESS FOR PREPARATION OF TERMOELASTOPLASTIC POLYOLEFINS
    9.
    发明申请
    BINUCLEAR CATALYST AND PROCESS FOR PREPARATION OF TERMOELASTOPLASTIC POLYOLEFINS 审中-公开
    沸石催化剂及其制备方法

    公开(公告)号：WO2005097837A1

    公开(公告)日：2005-10-20

    申请号：PCT/RU2004/000134

    申请日：2004-04-09

    申请人： GAGIEVA, Svetlana Chermenovna ,  BULYCHEV, Boris Michailovich

    发明人： BULYCHEV, Boris Michailovich

    IPC分类号： C08F4/76

    CPC分类号： C07F7/006 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F2410/03 ,  C08F4/64048 ,  C08F2500/15 ,  C08F4/64186

    摘要： A catalyst combination ana a process for preparing physically crosslinked recyclable thermoplastic polyolefins of simplified processability. In particular the new catalyst combination and a process are useful and for preparing of super high molecular weight isotactic polymers and copolymers of monomodal Gauss like molecular weight distribution with both linear and cyclic olefinically unsaturated compounds as monomer having isotacticity being within the range of from 15 to 70% of [mmmm] pentad concentration, weight average molecular weight within the range from 300,000 to 4,000,000 gms/mol, polydispersity within the range from 1.4 to 12 and statistic distribution of stereoscopic errors along the polymer chain. The catalyst comprises bisphenoxyimine type complexes of transition metals in combination with MAO type activator.

    摘要翻译： 一种催化剂组合，以及一种制备物理交联的可回收热塑性聚烯烃的方法，其加工性能简单。 特别地，新的催化剂组合和方法是有用的，并且用于制备超高分子量全同立构聚合物和单峰高斯分子量分布的共聚物与直链和环状烯属不饱和化合物的共聚物，其具有的全同立构规整度在15〜 [mmmm]五单元组浓度的70％，重均分子量在30万至4,000,000克/摩尔的范围内，多分散性在1.4至12范围内，并且沿着聚合物链的立体误差的统计分布。 该催化剂包括过氧化物与MAO型活化剂组合的双苯氧亚胺型络合物。

    CLATHROCHELATES AS OLEFIN POLYMERIZATION CATALYST COMPONENTS
    10.
    发明申请
    CLATHROCHELATES AS OLEFIN POLYMERIZATION CATALYST COMPONENTS 审中-公开
    粘合剂作为烯烃聚合催化剂组分

    公开(公告)号：WO2005082955A1

    公开(公告)日：2005-09-09

    申请号：PCT/US2005/001610

    申请日：2005-01-21

    申请人： EQUISTAR CHEMICALS, LP

    发明人： NAGY, Sandor ,  TSUIE, Barbara, M.

    IPC分类号： C08F10/00

    CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F2410/03 ,  C08F4/659 ,  C08F4/7006 ,  C08F4/7081

    摘要： Catalyst systems and methods for olefin polymerization are disclosed. The polymerizations are performed in the presence of a clathrochelate which comprises a transition metal ion and an encapsulating macropolycyclic ligand. At least one of the capping atoms of the macropolycyclic ligand is a Group 3-10 transition metal or a Group 13 atom. When a capping atom is a Group 3-10 transition metal, the clathrochelate can be used with an activator to polymerize olefins. When a capping atom is a Group 13 atom, the clathrochelate can be used as an activator for an olefin polymerization. Clathrochelates allow polyolefin makers to fine tune catalyst reactivity and polyolefin properties.

    摘要翻译： 公开了用于烯烃聚合的催化剂体系和方法。 聚合反应在包含过渡金属离子和封装的大多环配体的笼形螯合物的存在下进行。 大环配体的至少一个封端原子是3-10族过渡金属或第13族原子。 当封端原子是3-10族过渡金属时，可以使用活化剂来使烯螯合物与烯烃聚合。 当封端原子是13族原子时，可以使用氯酸盐螯合物作为烯烃聚合的活化剂。 氯酸铜螯合剂允许聚烯烃制造商微调催化剂反应性和聚烯烃性能。