公开(公告)号：WO1997040120A1

公开(公告)日：1997-10-30

申请号：PCT/US1997001594

申请日：1997-01-30

Applicant: EXXON RESEARCH AND ENGINEERING COMPANY

Inventor： EXXON RESEARCH AND ENGINEERING COMPANY ,  LAPINSKI, Mark, P. ,  RILEY, Kenneth, L. ,  HALBERT, Thomas, R. ,  LASKO, William ,  KAUFMAN, Jeffrey, L. ,  ALDRIDGE, Clyde, L. ,  TOUVELLE, Michele, S.

IPC: C10G21/00

CPC classification number: B01J23/882 ,  B01J35/023 ,  B01J35/026 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  C10G45/08

Abstract: A catalyst and process for hydrodesulfurizing naphtha feedstreams wherein the reactor inlet temperature is below the dew point of the feedstock at the reactor inlet so that the naphtha will completely vaporize within the catalyst bed. The catalyst is comprised of about 1 to about 10 wt.% MoO3, about 0.1 to about 5 wt.% CoO supported on a suitable support material. They are also characterized as having an average medium pore diameter from about 60 ANGSTROM to 200 ANGSTROM , a Co/Mo atomic ratio of about 0.1 to about 1.0, a MoO3 surface concentration of about 0.5 x 10 to about 3.0 x 10 g MoO3/m , and an average particle size of less than about 2.0 mm in diameter.

Abstract translation: 用于加氢脱硫石脑油原料流的催化剂和方法，其中反应器入口温度低于反应器入口处原料的露点，使得石脑油在催化剂床内完全蒸发。 催化剂由约1至约10重量％的MoO 3，约0.1至约5重量％的CoO负载在合适的载体材料上。 它们的特征还在于具有平均中等孔径从约60至200，Co / Mo原子比为约0.1至约1.0，MoO 3表面浓度为约0.5×10 -4至约3.0×10 平均粒径小于约2.0mm的直径的MoO 3 / m 2。

公开(公告)号：WO1997039979A1

公开(公告)日：1997-10-30

申请号：PCT/US1997006869

申请日：1997-04-23

Applicant: EXXON RESEARCH AND ENGINEERING COMPANY

Inventor： EXXON RESEARCH AND ENGINEERING COMPANY ,  KOVEAL, Russell, J. ,  RILEY, Kenneth, L. ,  CORKERN, Keith, E.

IPC: C01B03/58

CPC classification number: C10K1/34 ,  B01D53/04 ,  B01D53/14 ,  B01D53/8621 ,  B01D2253/104 ,  B01D2253/112 ,  B01D2256/16 ,  B01D2256/20 ,  B01D2257/406 ,  B01D2257/408 ,  C01B3/52 ,  C01B3/58 ,  C01B2203/0415 ,  C01B2203/0435 ,  C01B2203/0465

Abstract: Hydrogen cyanide is removed from an HCN containing synthesis gas, CO + H2, by contact with a metal oxide catalyst comprised of the oxides of molybdenum, titanium and aluminum in the presence of water vapor, and subsequently water washing the resulting synthesis gas.

Abstract translation: 通过在水蒸气存在下与由钼，钛和铝的氧化物组成的金属氧化物催化剂接触，然后将所得合成气水洗，从含HCN的合成气CO + H 2中除去氰化氢。

公开(公告)号：WO1998019792A1

公开(公告)日：1998-05-14

申请号：PCT/US1997020854

申请日：1997-11-05

Applicant: EXXON RESEARCH AND ENGINEERING COMPANY

Inventor： EXXON RESEARCH AND ENGINEERING COMPANY ,  WITTENBRINK, Robert, J. ,  RYAN, Daniel, F. ,  BAIRD, William, C., Jr. ,  RILEY, Kenneth, L. ,  JOHNSON, Jack, W.

IPC: B01J23/885

CPC classification number: C10G45/60 ,  B01J23/85 ,  B01J23/885

Abstract: Hydroconversion of paraffin containing hydrocarbon feeds is effected over a supported Group VIII and Group VI metal containing catalyst also containng a hydrocracking suppressant such as a Group IB metal, wherein the catalyst is preferably prepared by fixing the Group IB metal onto the support prior to incorporating the Group VI metal onto the support.

Abstract translation: 含有烃的烃进料的加氢转化在负载的第VIII族和第VI族金属催化剂上进行，还含有加氢裂化抑制剂如IB族金属，其中催化剂优选通过将IB族金属固定在载体上而制备， 将VI族金属固定在支架上。