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    PROCESS FOR MAKING CYCLOHEXANONE
    1.
    发明申请
    PROCESS FOR MAKING CYCLOHEXANONE 审中-公开
    制备环己酮的方法

    公开(公告)号：WO2017023429A1

    公开(公告)日：2017-02-09

    申请号：PCT/US2016/037989

    申请日：2016-06-17

    Applicant: EXXONMOBIL CHEMICAL PATENTS INC.

    Inventor： DAKKA, Jihad, M. ,  POUCHER, Ashley, J. ,  BECKER, Christoper, L. ,  DAVIS, Jason, D. ,  NADLER, Kirk, C. ,  VARGAS, Jose, M. ,  CHEN, Tan-Jen ,  WASHBURN, Seth, M. ,  WEBER, Jorg, F.W.

    IPC: C07C45/82 ,  C07C45/00 ,  C07C49/403 ,  C07C37/74 ,  C07C39/04

    CPC classification number: C07C45/82 ,  C07C37/74 ,  C07C45/006 ,  C07C2601/14 ,  Y02P20/52 ,  C07C49/403 ,  C07C39/04

    Abstract: Disclosed are novel processes for making cyclohexanone compositions, from a mixture comprising phenol, cyclohexanone, and cyclohexylbenzene. The process includes hydrogenation of a feed stream comprising phenol, cyclohexanone, and cyclohexylbenzene. The feed stream may be subjected to one or more pre-hydrogenation treatments, such as passing through one or more sorbents, addition of basic chemical agents, and/or addition of water, so as to improve catalyst activity, minimize undesired side reactions, and/or remove catalyst poisons from the feed stream. The feed stream may be provided to a hydrogenation reaction zone in the vapor phase, with periodic alterations to hydrogenation reaction conditions such that the feed is provided in mixed liquid and vapor phase in order to carry out liquid washing of a hydrogenation catalyst bed within the hydrogenation reaction zone.

    Abstract translation: 公开了由包含苯酚，环己酮和环己基苯的混合物制备环己酮组合物的新方法。 该方法包括氢化包含苯酚，环己酮和环己基苯的进料流。 进料流可以进行一种或多种预氢化处理，例如通过一种或多种吸附剂，添加碱性化学试剂和/或加入水，以便改善催化剂活性，最小化不期望的副反应，以及 /或从进料流中除去催化剂毒物。 可以将进料流提供到气相中的氢化反应区，对氢化反应条件进行周期性改变，使得进料在混合液相和气相中提供，以便在氢化反应中进行氢化催化剂床的液体洗涤 反应区。

    PROCESS FOR MAKING PHENOL AND/OR CYCLOHEXANONE
    6.
    发明申请
    PROCESS FOR MAKING PHENOL AND/OR CYCLOHEXANONE 审中-公开
    制备苯酚和/或环己酮的方法

    公开(公告)号：WO2015050649A1

    公开(公告)日：2015-04-09

    申请号：PCT/US2014/052891

    申请日：2014-08-27

    Applicant: EXXONMOBIL CHEMICAL PATENTS INC.

    Inventor： BENITEZ, Francisco, M. ,  BECKER, Christopher, L. ,  KUECHLER, Keith, H. ,  DAVIS, Jason, D.

    IPC: C07C37/08 ,  C07C45/53 ,  C07C407/00

    CPC classification number: C07C37/08 ,  C07C45/00 ,  C07C45/53 ,  C07C407/00 ,  C07C407/003 ,  C07C2601/14 ,  C07C39/04 ,  C07C49/403 ,  C07C409/14

    Abstract: A process for making phenol and/or cyclohexanone, the process comprising: (A) oxidizing a cyclohexylbenzene feed to obtain an oxidation product comprising cyclohexylbenzene, cyclohexylbenzene hydroperoxide and water; (B) removing at least a portion of the water from at least a portion of the oxidation product to obtain a cleavage feed; and (C) contacting at least a portion of the cyclohexylbenzene hydroperoxide in the cleavage feed with an acid catalyst in a cleavage reactor under cleavage conditions to obtain a cleavage product comprising phenol and cyclohexanone. The removing step may also comprises a step of removing a portion of the cyclohexylbenzene contained in the oxidation product. Water removal may be advantageously conducted in a water flashing drum before a cyclohexylbenzene hydroperoxide concentrator.

    Abstract translation: 一种制备苯酚和/或环己酮的方法，该方法包括：（A）氧化环己基苯进料以获得包含环己基苯，环己基苯氢过氧化物和水的氧化产物; （B）从氧化产物的至少一部分去除至少一部分水以获得切割进料; 和（C）在切割反应器中使切割进料中的环己基苯氢过氧化物的至少一部分与酸催化剂在裂解条件下接触，得到包含苯酚和环己酮的裂解产物。 除去步骤还可以包括除去氧化产物中所含的一部分环己基苯的步骤。 在环己基苯氢过氧化物浓缩器之前，可以有利地在清水桶中进行除水。

    PROCESS FOR CONCENTRATING A MIXTURE CONTAINING ORGANIC HYDROPEROXIDE
    7.
    发明申请
    PROCESS FOR CONCENTRATING A MIXTURE CONTAINING ORGANIC HYDROPEROXIDE 审中-公开
    浓缩含有机氢过氧化物的混合物的方法

    公开(公告)号：WO2014209578A1

    公开(公告)日：2014-12-31

    申请号：PCT/US2014/041410

    申请日：2014-06-06

    Applicant: EXXONMOBIL CHEMICAL PATENTS INC.

    Inventor： DAVIS, Jason, D. ,  BECKER, Christopher, L. ,  REINE, Travis, A. ,  PATEL, Bryan, A.

    IPC: C07C407/00 ,  C07C409/14

    CPC classification number: C07C407/00 ,  C07C29/132 ,  C07C37/08 ,  C07C45/53 ,  C07C407/003 ,  C07C2601/14 ,  C07C409/14 ,  C07C39/04 ,  C07C49/403 ,  C07C409/02

    Abstract: Method for concentrating an organic hydroperoxide mixture comprising a hydrocarbon and a hydroperoxide corresponding thereto comprises evaporating a first liquid mixture in a thin- film evaporation device followed by separation in a separation zone. Both the evaporation device and the separation zone operate at a low absolute pressure at a temperature lower than the thermal degradation temperature of the hydroperoxide to prevent thermal decomposition thereof. The process is particularly useful for concentrating an oxidation product made from the oxidation of cyclohexylbenzene.

    Abstract translation: 用于浓缩包含对应于其的烃和氢过氧化物的有机氢过氧化物混合物的方法包括在薄膜蒸发装置中蒸发第一液体混合物，然后在分离区中分离。 蒸发装置和分离区都在低于氢过氧化物的热降解温度的温度下在低绝对压力下操作，以防止其热分解。 该方法对于浓缩由环己基苯氧化制得的氧化产物特别有用。

    PROCESS FOR PRODUCING PHENOL
    8.
    发明申请
    PROCESS FOR PRODUCING PHENOL 审中-公开
    生产苯酚的方法

    公开(公告)号：WO2014088841A1

    公开(公告)日：2014-06-12

    申请号：PCT/US2013/071420

    申请日：2013-11-22

    Applicant: EXXONMOBIL CHEMICAL PATENTS INC.

    Inventor： KUECHLER, Keith, H. ,  DAVIS, Jason, D.

    IPC: C07C37/08 ,  C07C37/74

    CPC classification number: C07C29/48 ,  C07B41/00 ,  C07C2/66 ,  C07C2/74 ,  C07C37/08 ,  C07C37/74 ,  C07C45/28 ,  C07C45/53 ,  C07C2523/06 ,  C07C2523/14 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2529/70 ,  C07C2601/14 ,  C07C39/04 ,  C07C49/403 ,  C07C13/28

    Abstract: In a process for producing phenol and/or cyclohexanone, a cleavage reaction mixture containing cyclohexyl-1 -phenyl-hydroperoxide and cyclohexylbenzene is contacted with sulfuric acid and water under cleavage conditions effective to form a cleavage reaction effluent containing phenol, cyclohexanone, cyclohexylbenzene, water, sulfuric acid and 1-phenylcyclohexanol. At least a portion of the cleavage reaction effluent is neutralized with a basic material to produce a neutralized cleavage product and at least a portion of the neutralized cleavage product is supplied in the absence of an added dehydration catalyst to a distillation column. The distillation column is operated so that at least a portion of the neutralized cleavage product is exposed to a temperature greater than 70°C at least one location in the distillation column whereby at least a portion of the 1 -phenylcyclohexanol in the neutralized cleavage product is dehydrated to phenylcyclohexene.

    Abstract translation: 在生产苯酚和/或环己酮的方法中，含有环己基-1-苯基 - 氢过氧化物和环己基苯的裂解反应混合物在有效形成裂解反应流出物的裂解条件下与硫酸和水接触，所述裂解反应流出物含有苯酚，环己酮，环己基苯，水 ，硫酸和1-苯基环己醇。 至少一部分裂解反应流出物用碱性物质中和以产生中和的裂解产物，并且在没有加入的脱水催化剂的情况下将至少一部分中和的裂解产物供应到蒸馏塔。 操作蒸馏塔使得至少一部分中和的裂解产物在蒸馏塔中暴露于高于70℃至少一个位置的温度，由此中和的裂解产物中至少一部分1-苯基环己醇为 脱水至苯基环己烯。

    PROCESS FOR MAKING CYCLOHEXANONE
    10.
    发明申请
    PROCESS FOR MAKING CYCLOHEXANONE 审中-公开
    制备环己酮的方法

    公开(公告)号：WO2016053583A1

    公开(公告)日：2016-04-07

    申请号：PCT/US2015/048972

    申请日：2015-09-08

    Applicant: EXXONMOBIL CHEMICAL PATENTS INC.

    Inventor： BECKER, Christopher, L. ,  DAVIS, Jason, D. ,  DAKKA, Jihad, M. ,  NADLER, Kirk, C.

    IPC: C07C45/62

    CPC classification number: C07C45/82 ,  C07C37/74 ,  C07C45/006 ,  C07C2602/14 ,  C07C49/403 ,  C07C39/04

    Abstract: Disclosed are processes and systems for making cyclohexanone from a mixture comprising phenol, cyclohexanone, and cyclohexylbenzene, comprising a step of or a device for subjecting at least a portion of the mixture to hydrogenation and a step of or a device for distilling a phenol/cyclohexanone/cyclohexylbenzene mixture to obtain an effluent rich in cyclohexanone.

    Abstract translation: 公开了由包含苯酚，环己酮和环己基苯的混合物制备环己酮的方法和系统，包括用于使至少一部分混合物经受氢化的步骤或设备，和步骤 用于蒸馏苯酚/环己酮/环己基苯混合物以获得富含环己酮的流出物的装置。

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