公开(公告)号：WO2006036554A3

公开(公告)日：2007-08-23

申请号：PCT/US2005032699

申请日：2005-09-14

Applicant: GEN MOTORS CORP

Inventor： TORGERSEN ALEXANDRA N ,  JORGENSEN SCOTT W ,  SIPORIN STACEY E

IPC: C01B6/24 ,  C01B3/00 ,  C01B6/04 ,  C01B21/00

CPC classification number: C01B3/065 ,  C01B3/0026 ,  C01B3/0078 ,  C01B6/24 ,  C01B6/243 ,  C01B6/246 ,  Y02E60/327 ,  Y02E60/362 ,  Y02E60/364

Abstract: In one aspect, the invention provides a hydrogen storage material that is formed by reacting solid precursors (a) and (b). The (a) precursor is a compound containing X-H and Y-H bonds, where X is a Group 13 and Y is a Group 15 element. Preferably X is boron (B-H) and Y is nitrogen (N-H). Most preferably, the precursor (a) is borazane. The (b) precursor is preferably a hydride, such as LiH or LiAIH 4 . Another feature of the present invention is a novel hydrogen storage composition material that is formed as an intermediate (INT) in the reaction of the (a) with the (b) precursors. The INT hydrogen storage material can be a quaternary B-H-Li-N composition. Other aspects of hydrogen storage materials are provided herein.

Abstract translation: 一方面，本发明提供了一种通过使固体前体（a）和（b）反应形成的储氢材料。 （a）前体是含有X-H和Y-H键的化合物，其中X是第13族，Y是第15族元素。 优选地，X是硼（B-H），Y是氮（N-H）。 最优选地，前体（a）是硼氮烷。 （b）前体优选为氢化物，例如LiH或LiAlH 4。 本发明的另一个特征是在（a）与（b）前体的反应中形成为中间体（INT）的新型储氢组合物材料。 INT储氢材料可以是四元B-H-Li-N组合物。 本文提供储氢材料的其它方面。

公开(公告)号：WO2005091764A3

公开(公告)日：2006-09-14

申请号：PCT/US2005002353

申请日：2005-01-27

Applicant: GEN MOTORS CORP

Inventor： VAJO JOHN J ,  MERTENS FLORIAN O ,  JORGENSEN SCOTT W

IPC: C01B3/08 ,  C01B3/06 ,  F17C11/00

CPC classification number: C01B3/065 ,  Y02E60/324 ,  Y02E60/362

Abstract: In one aspect, the invention provides a hydrogen storage composition having a hydrogenated state and a dehydrogenated state. In the hydrogenated state, such composition comprises a hydride and a hydroxide. In a dehydrogenated state, the composition comprises an oxide. The present invention also provides methods of and compositions for regenerating a species of a hydroxide and a hydride material.

Abstract translation: 一方面，本发明提供具有氢化状态和脱氢状态的储氢组合物。 在氢化状态下，这种组合物包含氢化物和氢氧化物。 在脱氢状态下，组合物包含氧化物。 本发明还提供用于再生氢氧化物和氢化物材料的种类的方法和组合物。

公开(公告)号：WO2006052473A3

公开(公告)日：2007-03-01

申请号：PCT/US2005038901

申请日：2005-10-28

Applicant: GEN MOTORS CORP

Inventor： TORGERSEN ALEXANDRA N ,  JORGENSEN SCOTT W

IPC: C01B6/24 ,  F17C11/00

CPC classification number: C01B3/0026 ,  C01B3/001 ,  C01B3/0031 ,  C01B3/0078 ,  C01B3/065 ,  C01P2006/12 ,  C01P2006/16 ,  F17C11/005 ,  Y02E60/321 ,  Y02E60/327 ,  Y02E60/362 ,  Y10S420/90

Abstract: In one aspect, the invention provides a hydrogen storage composite formed of a mesoporous scaffolding material and a hydrogen storage composition comprising precursors that react to form quarternary B-H-Li-N composition. In another aspect, the invention provides a process for forming hydrogen storage material. In each aspect, a high portion of hydrogen is released as hydrogen gas and a lesser portion of hydrogen is released as a hydrogen-containing byproduct.

Abstract translation: 一方面，本发明提供一种由介孔性支架材料和含有储存组合物形成的储氢复合材料，该储氢组合物包含反应形成三元B-H-Li-N组合物的前体。 另一方面，本发明提供一种形成储氢材料的方法。 在每个方面，氢的大部分作为氢气释放，较少部分的氢作为含氢副产物释放。

公开(公告)号：WO2006036553A3

公开(公告)日：2007-01-18

申请号：PCT/US2005032698

申请日：2005-09-14

Applicant: GEN MOTORS CORP

Inventor： TORGERSEN ALEXANDRA N ,  JORGENSEN SCOTT W ,  SIPORIN STACEY E

IPC: C01B3/00

CPC classification number: C01B3/065 ,  C01B3/0026 ,  C01B3/0078 ,  C01B6/24 ,  C01B6/243 ,  C01B6/246 ,  Y02E60/327 ,  Y02E60/362 ,  Y02E60/364

Abstract: In one aspect, the invention provides a method of storing hydrogen that comprises reacting two precursors to form a hydrogen storage composition comprising hydrogen, nitrogen, a Group 13 element, and an element selected from Group 1, Group 2 or mixtures thereof. In other aspects, the present invention provides a method of storing hydrogen by ball-milling two precursors at a temperature in a range sufficient to prevent pre-mature release of hydrogen, while the temperature is still sufficient to induce reaction between the precursors. The precursors preferably have X-H, Y-H and A-H bonds where X represents a Group 13 element, Y represents a Group 15 element, and A represents an element from Group 1, Group 2, or mixtures thereof. Other variations of the methods of storing hydrogen are further provided.

Abstract translation: 一方面，本发明提供一种储存氢气的方法，其包括使两种前体反应形成包含氢，氮，第13族元素和选自组1，组2或其混合物的元素的储氢组合物。 在其他方面，本发明提供了一种通过在足以防止氢的预成熟释放的温度下球磨两种前体的方法，同时温度仍足以引起前体之间的反应。 前体优选具有X-H，Y-H和A-H键，其中X表示第13族元素，Y表示第15族元素，A表示第1族，第2族或其混合物中的元素。 进一步提供存储氢的方法的其它变化。

公开(公告)号：WO2005091765A3

公开(公告)日：2006-09-21

申请号：PCT/US2005002354

申请日：2005-01-27

Applicant: GEN MOTORS CORP

Inventor： MERTENS FLORIAN O ,  JORGENSEN SCOTT W ,  VAJO JOHN J

IPC: C01B3/08 ,  C01B3/06 ,  F17C11/00

CPC classification number: C01B3/065 ,  Y02E60/324 ,  Y02E60/362

Abstract: In one aspect, the present invention provides a system for methods of producing and releasing hydrogen from hydrogen storage compositions having a hydrogenated state and a dehydrogenated state. In the hydrogenated state, such a composition comprises a hydride and a hydroxide. In a dehydrogenated state, the composition comprises an oxide. A first reaction in conducted between a portion of the hydride and water to generate heat sufficient to cause a second hydrogen production reaction between a remaining portion of the hydride and the hydroxide.

Abstract translation: 一方面，本发明提供一种从具有氢化状态和脱氢状态的储氢组合物制备和释放氢的方法的系统。 在氢化状态下，这种组合物包含氢化物和氢氧化物。 在脱氢状态下，组合物包含氧化物。 在一部分氢化物和水之间进行的第一反应是产生足以在氢化物的剩余部分和氢氧化物之间引起第二次氢产生反应的热量。

公开(公告)号：WO2005091767A3

公开(公告)日：2005-11-17

申请号：PCT/US2005002518

申请日：2005-01-27

Applicant: GEN MOTORS CORP

Inventor： VAJO JOHN J ,  MERTENS FLORIAN O ,  JORGENSEN SCOTT W

IPC: C01B3/00 ,  C01B3/02 ,  C01B3/06 ,  C09K3/00 ,  F01B31/00

CPC classification number: C01B3/065 ,  C01B3/0026 ,  Y02E60/327 ,  Y02E60/328 ,  Y02E60/362

Abstract: In one aspect, the invention provides a hydrogen storage composition having a hydrogenated state and a dehydrogenated state. In the hydrogenated state, such composition comprises a hydride and a hydroxide. In a dehydrogenated state, the composition comprises an oxide. The present invention also provides methods of producing hydrogen, including for mobile fuel cell device applications.

Abstract translation: 一方面，本发明提供了具有氢化态和脱氢态的储氢组合物。 在氢化状态下，这种组合物包含氢化物和氢氧化物。 在脱氢状态下，组合物包含氧化物。 本发明还提供了制造氢气的方法，包括用于移动式燃料电池装置应用。