公开(公告)号：WO2016108867A1

公开(公告)日：2016-07-07

申请号：PCT/US2014/072927

申请日：2014-12-31

Applicant: HALLIBURTON ENERGY SERVICES, INC.

Inventor： NATALI, Sanja ,  DYKSTRA, Jason D. ,  XUE, Yuzhen ,  SUN, Zhijie

IPC: E21B43/22 ,  C09K8/52

CPC classification number: E21B43/34 ,  C09K8/52 ,  C09K8/584 ,  C10G33/04 ,  C10G2300/1033 ,  C10G2300/201 ,  C10G2300/4037 ,  E21B21/068 ,  E21B49/086

Abstract: Systems comprising a main tubular coupled to a pump and extending from a surface into a subterranean formation, wherein produced bulk fluid is pumped to the surface, and wherein the bulk fluid comprises at least water and a hydrocarbon, and has certain constituent parameters; a storage container for retaining the bulk fluid; a sampling tubular in fluid communication with the main tubular for sampling the bulk fluid, thereby forming at least one sampled fluid; and a dosing system coupled to the sampling tubular and configured to receive the sampled fluid, the dosing system configured to determine a constituent parameter of the sampled fluid, identify a type and concentration of separating surfactant to include in the bulk fluid to obtain a hydrophilic-lipophilic deviation (HLD) substantially equal to 0, and introduce the identified type and concentration of the separating surfactant into the storage container retaining the bulk fluid.

Abstract translation: 系统包括耦合到泵并从表面延伸到地下地层中的主管，其中所产生的散装流体被泵送到所述表面，并且其中所述散装流体至少包括水和烃，并且具有某些构成参数; 用于保持散装流体的储存容器; 与主管流体连通的取样管，用于对本体流体进行采样，由此形成至少一个采样流体; 以及配量系统，其耦合到所述采样管并且被配置为接收所述采样流体，所述配量系统被配置为确定所述采样流体的构成参数，识别分离表面活性剂的类型和浓度以包括在所述散装流体中以获得亲水 - 亲油偏差（HLD）基本上等于0，并将所识别的分离表面活性剂的类型和浓度引入保留大量流体的储存容器中。

公开(公告)号：WO2016108874A1

公开(公告)日：2016-07-07

申请号：PCT/US2014/072953

申请日：2014-12-31

Applicant: HALLIBURTON ENERGY SERVICES, INC.

Inventor： NATALI, Sanja

IPC: E21B47/00 ,  E21B49/00

CPC classification number: C09K8/584 ,  E21B43/20 ,  E21B43/26 ,  E21B43/38 ,  E21B49/08

Abstract: Methods including obtaining a sampled fluid from a subterranean formation, the sampled fluid comprising at least water and a hydrocarbon, and having certain constituent parameters; determining constituent parameters of the sampled fluid using the hydrophilic-lipophilic deviation (HLD) model; determining an optimal surfactant or surfactant blend to achieve an oil-water separation morphological phase of the sampled fluid; and introducing the optimal surfactant or surfactant blend into the subterranean formation as part of a surfactant flooding enhanced oil recovery operation.

Abstract translation: 方法包括从地层获得取样的流体，所述取样流体至少包含水和烃，并且具有某些构成参数; 使用亲水亲油偏差（HLD）模型确定采样流体的构成参数; 确定最佳表面活性剂或表面活性剂混合物以实现所述采样流体的油 - 水分离形态相; 并将最佳的表面活性剂或表面活性剂混合物引入到地层中，作为表面活性剂浸渍强化采油操作的一部分。

公开(公告)号：WO2016108879A1

公开(公告)日：2016-07-07

申请号：PCT/US2014/072970

申请日：2014-12-31

Applicant: HALLIBURTON ENERGY SERVICES, INC.

Inventor： NATALI, Sanja ,  DYKSTRA, Jason D. ,  SUN, Zhijie ,  XUE, Yuzhen

IPC: E21B49/08 ,  E21B43/22 ,  C09K8/58

CPC classification number: E21B49/08 ,  B01D17/02 ,  B01D17/047 ,  C02F2209/02 ,  C02F2209/05 ,  C09K8/58 ,  C09K8/584 ,  C09K8/602 ,  E21B43/34 ,  E21B47/00 ,  E21B49/088 ,  G01N33/241 ,  G01N33/2823 ,  G06Q10/04 ,  G06Q50/00

Abstract: Methods including the step of producing a bulk fluid from a subterranean formation, the bulk fluid comprising at least water and a hydrocarbon. The bulk fluid is then sampled to form at least one sampled fluid. Next, constituent parameters of the sampled fluid are determined using the hydrophilic-lipophilic deviation (HLD) model. The constituent parameters include the salinity (S) of the sampled fluid, the salinity constant (b); the equivalent alkane carbon number for the hydrocarbon in the sampled fluid ( EACN ); T is temperature of the sampled fluid; the characteristic curvature for an ionic surfactant composition ( c c ) or for a nonionic surfactant composition ( c cn ); the surfactant temperature constant for the ionic surfactant composition ( α T ) or for a nonionic surfactant composition ( cT ). Also determining an optimal surfactant or optimal surfactant blend to achieve an oil-water separation morphological phase distribution of the sampled fluid.

Abstract translation: 包括从地层生产大量流体的步骤的方法，所述大体积流体至少包含水和烃。 然后对本体流体进行采样以形成至少一个采样流体。 接下来，使用亲水亲油偏差（HLD）模型确定取样流体的组成参数。 成分参数包括取样液体的盐度（S），盐度常数（b）; 采样液中烃类的等效烷烃碳数（EACN）; T是采样流体的温度; 离子表面活性剂组合物（c c）或非离子表面活性剂组合物（c cn）的特征曲率; 离子表面活性剂组合物（αT）或非离子表面活性剂组合物（cT）的表面活性剂温度常数。 还确定最佳表面活性剂或最佳表面活性剂混合物以实现取样流体的油 - 水分离形态相分布。

公开(公告)号：WO2016108870A1

公开(公告)日：2016-07-07

申请号：PCT/US2014/072937

申请日：2014-12-31

Applicant: HALLIBURTON ENERGY SERVICES, INC.

Inventor： NATALI, Sanja

IPC: E21B43/22 ,  C09K8/58

CPC classification number: E21B49/086 ,  C09K8/52 ,  C09K2208/22 ,  E21B43/34 ,  E21B2049/085

Abstract: Methods including producing a bulk fluid from a subterranean formation, the bulk fluid comprising at least water and a hydrocarbon, and having certain constituent parameters; sampling a portion of the bulk fluid, thereby forming at least one sampled fluid; determining constituent parameters of the sampled fluid using the hydrophilic-lipophilic deviation (HLD) model; and determining an optimal hydrate inhibitor surfactant (HIS) or HIS mixture to achieve a first oil-water separation morphological phase of the sampled fluid at temperatures above about 10C and a first water-in-oil morphological phase of the sampled fluid at temperatures below about 5C.

Abstract translation: 方法包括从地层生产大量流体，所述主体流体至少包含水和烃，并且具有某些构成参数; 对本体流体的一部分进行采样，从而形成至少一个采样流体; 使用亲水亲油偏差（HLD）模型确定采样流体的构成参数; 以及确定最佳的水合物抑制剂表面活性剂（HIS）或HIS混合物，以在高于约10℃的温度下获得采样流体的第一个油 - 水分离形态相，并且在低于约 5C。