公开(公告)号：WO2023049515A1

公开(公告)日：2023-03-30

申请号：PCT/US2022/044906

申请日：2022-09-27

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： ZHAI, Yian ,  HULSE, Ryan ,  SINGH, Rajiv, Ratna ,  NALEWAJEK, David

IPC: C11D7/50 ,  C08J9/14 ,  C08K5/02 ,  C08K5/07 ,  A62D1/06

Abstract: Compositions for uses such as solvent cleaning and solvent extraction, comprising a compound according to Formula (I) or Formula (II) or Formula (III): where each R and each R' is independently selected from H, F, Cl, R1, and OR1, each R1 is independently: a C1 to C3 alkane that is unsubstituted or substituted with F and/or Cl; or C1 to C3 alkene that is unsubstituted or substituted with F and/or Cl; or Bz, where Bz is an unsubstituted benzene ring, and provided that the molecule has at least three F substituents bonded to a carbon in the cyclobutene ring.

公开(公告)号：WO2023049513A1

公开(公告)日：2023-03-30

申请号：PCT/US2022/044904

申请日：2022-09-27

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： ZHAI, Yian ,  HULSE, Ryan ,  SINGH, Rajiv, Ratna ,  NALEWAJEK, David

IPC: C09K5/04 ,  H01M10/6557 ,  F25B9/00

Abstract: A heat transfer composition for transferring heat and/or energy to and/or from an article, device or fluid, wherein the heat transfer composition comprises, consists essentially of or consists of a compound according to Formula (I) or Formula (II) or Formula (III).

公开(公告)号：WO2013122790A1

公开(公告)日：2013-08-22

申请号：PCT/US2013/024835

申请日：2013-02-06

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： NAIR, Haridasan K. ,  SINGH, Rajiv Ratna ,  NALEWAJEK, David ,  POSS, Andrew Joseph

IPC: C07C17/20 ,  C07C21/18 ,  B01J23/46 ,  B01J23/72

CPC classification number: C07C17/25 ,  C07C17/206 ,  C07C17/23 ,  C07C17/278 ,  C07C19/01 ,  C07C19/10 ,  C07C21/18 ,  C07C21/04

Abstract: The present invention describes a process for making CF 3 CH=CHF (HFO-1234ze). The process involves the addition of carbon tetrachloride (CCl 4 ) to 1,2-dichloroethylene to form CCl 3 CHClCHCl 2 . The compound CCl 3 CHClCHCl 2 thus can then either be treated with HF to produce CF 3 CHClCHClF as the main product, or it can be converted to CCl 2 =CHCHCl 2 (1230za) by dechlorination. CCl 2 =CHCHCl 2 can be treated with HF such that the main product obtained is CF 3 CHClCHClF. CF 3 CH=CHCl may be produced as a by-product, but upon treatment with HF, it affords the compound CF 3 CHClCHClF. The desired compound, CF 3 CH=CHF (HFO-1234ze), is obtained as a trans/cis mixture by dehydrochlorination of CF 3 CH2CHClF or by dechlorination of CF 3 CHClCHClF.

Abstract translation: 本发明描述了制备CF 3 CH = CHF（HFO-1234ze）的方法。 该方法包括向1,2-二氯乙烯中加入四氯化碳（CCl 4）以形成CCl 3 CHClCHCl 2。 因此，可以用HF处理化合物CCl 3 CHClCHCl 2以产生CF 3 CHClCHClF作为主要产物，或者可以通过脱氯将其转化为CCl 2 = CHCHCl 2（1230za）。 CCl 2 = CHCHCl 2可用HF处理，得到的主要产物为CF 3 CHClCHClF。 CF 3 CH = CHCl可以作为副产物来制备，但是在用HF处理时，得到化合物CF 3 CHClCHClF。 通过CF 3 CH 2 CHClF的脱氯化氢或通过CF 3 CHClCHClF的脱氯，获得期望的化合物CF 3 CH = CHF（HFO-1234ze），为反式/顺式混合物。

公开(公告)号：WO2012134984A1

公开(公告)日：2012-10-04

申请号：PCT/US2012/030255

申请日：2012-03-23

Applicant: HONEYWELL INTERNATIONAL INC. ,  MUKHOPADHYAY, Sudip ,  NALEWAJEK, David

Inventor： MUKHOPADHYAY, Sudip ,  NALEWAJEK, David

IPC: G02B1/11 ,  G02B1/10 ,  C09D5/00

CPC classification number: H01L31/02168 ,  C09D127/12 ,  H01L31/0392 ,  Y02E10/50 ,  Y10T428/3154

Abstract: Anti-reflective coatings and coating solutions, optically transparent elements and improved processes for preparing AR coatings and coating solutions are described. The anti-reflective coatings are formed from a fluoropolymer derived from at least one fluoropropene compound. The fluoropolymer may applied as a coating solution that is curable at low temperatures.

Abstract translation: 描述了抗反射涂层和涂层溶液，光学透明元件和改进的制备AR涂层和涂层溶液的方法。 抗反射涂层由衍生自至少一种氟丙烯化合物的含氟聚合物形成。 含氟聚合物可以作为在低温下可固化的涂布溶液使用。

公开(公告)号：WO2011146820A3

公开(公告)日：2011-11-24

申请号：PCT/US2011/037310

申请日：2011-05-20

Applicant: HONEYWELL INTERNATIONAL INC. ,  POSS, Andrew Joseph ,  NALEWAJEK, David ,  NAIR, Haridasan K. ,  VAN DER PUY, Michael

Inventor： POSS, Andrew Joseph ,  NALEWAJEK, David ,  NAIR, Haridasan K. ,  VAN DER PUY, Michael

IPC: C07C17/25 ,  C07C17/23 ,  C07C21/18

Abstract: Disclosed is a process for preparing cis-1,1,1,4,4,4-hexafluoropropene comprising the steps of (a) reacting CCl 4 with a compound having the formula CF 3 CX=CXH, where each X is independently halogen or hydrogen, to form a compound having the formula CF 3 CXClCXHCCl 3 ; (b) fluorinating the compound formed in step (a) to form a compound having the formula CF 3 CXHCXHCF 3 ; (c) converting the compound formed in step (b) by a reaction selected from the group consisting of dehydrohalogenation, dehalogenation and both reactions, to form a compound having the formula CF 3 C = CCF 3 ; and (d) catalytically reducing the compound formed in step (c) with hydrogen to form the compound having the formula (I).

公开(公告)号：WO2010036841A3

公开(公告)日：2010-04-01

申请号：PCT/US2009/058287

申请日：2009-09-25

Applicant: HONEYWELL INTERNATIONAL INC. ,  POSS, Andrew, J. ,  VAN DER PUY, Michael ,  SINGH, Rajiv, R. ,  SAMUELS, George, J. ,  NALEWAJEK, David ,  CANTLON, Cheryl, L.

Inventor： POSS, Andrew, J. ,  VAN DER PUY, Michael ,  SINGH, Rajiv, R. ,  SAMUELS, George, J. ,  NALEWAJEK, David ,  CANTLON, Cheryl, L.

IPC: A01N29/02 ,  A01P21/00

Abstract: Chloropentafluoropropene is employed as a herbicide for the effective control of undesirable spermatophyte growth.

公开(公告)号：WO2009151764A2

公开(公告)日：2009-12-17

申请号：PCT/US2009/040422

申请日：2009-04-14

Applicant: HONEYWELL INTERNATIONAL INC. ,  NALEWAJEK, David ,  CANTLON, Cheryl L. ,  POSS, Andrew J. ,  SINGH, Rajiv Ratna ,  SHANKLAND, Ian

Inventor： NALEWAJEK, David ,  CANTLON, Cheryl L. ,  POSS, Andrew J. ,  SINGH, Rajiv Ratna ,  SHANKLAND, Ian

IPC: A61B5/117

CPC classification number: A61B5/1172

Abstract: A method and composition for transforming a latent physiological biometric into a visible physiological biometric are provided, the method comprising: providing a latent biometric disposed on a surface of an article, wherein said biometric comprises at least one eccrine-derived compound; contacting said latent biometric with a developing solution, wherein said developing solution comprises at least one imaging reagent selected from ninhydrin and 1,8-diazafluoren-9-one and a carrier solvent comprising at least one C 3 - C 4 hydrofluorocarbon; and reacting said imaging reagent with said eccrine-derived compound to produce a visible physiological biometric.

Abstract translation: 提供了一种用于将潜在生理学生物转化为可见生理生物学的方法和组合物，所述方法包括：提供设置在制品表面上的潜伏生物测定，其中所述生物测定法包含至少一种衍生化合物; 使所述潜在生物测定与显影溶液接触，其中所述显影溶液包含至少一种选自茚三酮和1,8-二氮杂芴-9-酮的成像剂和包含至少一种C 3 -C 4氢氟烃的载体溶剂; 并使所述成像试剂与所述外分泌衍生的化合物反应以产生可见的生理学生物学特征。

公开(公告)号：WO2005103188A1

公开(公告)日：2005-11-03

申请号：PCT/US2005/013183

申请日：2005-04-18

Applicant: HONEYWELL INTERNATIONAL INC. ,  THOMAS, Raymond H. ,  PHAM, Hang T. ,  SINGH, Rajiv R. ,  WILSON, David P. ,  NALEWAJEK, David

Inventor： THOMAS, Raymond H. ,  PHAM, Hang T. ,  SINGH, Rajiv R. ,  WILSON, David P. ,  NALEWAJEK, David

IPC: C09K5/04

CPC classification number: C08J9/146 ,  C08J2205/052 ,  C08J2207/04 ,  C09K3/30 ,  C09K5/045 ,  C09K2205/122 ,  C09K2205/126 ,  C11D7/5063

Abstract: Provided are azeotrope-like compositions comprising tetrafluoropropene and pentafluoropropene and uses thereof, including use in refrigerant compositions, blowing agent compositions, foamable compositions, foams, sterilant compositions, sprayable compositions, and systems and methods using same.

Abstract translation: 提供包含四氟丙烯和五氟丙烯的类共沸组合物及其用途，包括用于制冷剂组合物，发泡剂组合物，可发泡组合物，泡沫，灭菌剂组合物，可喷雾组合物，以及使用它们的系统和方法。

公开(公告)号：WO2005051880A2

公开(公告)日：2005-06-09

申请号：PCT/US2004/038869

申请日：2004-11-19

Applicant: HONEYWELL INTERNATIONAL, INC. ,  BELL, Robert, L. ,  NALEWAJEK, David ,  BRADLEY, David, E. ,  DEMMIN, Timothy, R.

Inventor： BELL, Robert, L. ,  NALEWAJEK, David ,  BRADLEY, David, E. ,  DEMMIN, Timothy, R.

IPC: C07C51/00

CPC classification number: C07C51/58 ,  C07C53/48

Abstract: The invention pertains to a process for preparing chlorodifluoroacetyl fluoride (CDAF) by oxidation of chlorotrifluoroethylene (CTFE) in a solvent using a continuously stirred tank reactor. It provides a process for the production of chlorodifluoroacetyl fluoride by comprises reacting a solvent solution of chlorotrifluoroethylene with oxygen in a reactor to form a product which comprises chlorodifluoroacetyl fluoride. The reacting may be conducted in a continuous or batch mode.

Abstract translation: 本发明涉及一种通过使用连续搅拌罐式反应器在溶剂中氧化三氟氯乙烯（CTFE）来制备氯二氟乙酰氟（CDAF）的方法。 它提供了一种生产氯二氟乙酰氟的方法，包括使三氟氯乙烯的溶剂溶液与氧在反应器中反应，形成包含氯二氟乙酰氟的产物。 反应可以以连续或分批模式进行。

公开(公告)号：WO2004026799A2

公开(公告)日：2004-04-01

申请号：PCT/US2003/029694

申请日：2003-09-18

Applicant: HONEYWELL INTERNATIONAL, INC.

Inventor： NAIR, Haridasan, K. ,  POSS, Andrew, J. ,  NALEWAJEK, David

IPC: C07C29/00

CPC classification number: C07C29/44 ,  C07C31/34 ,  C07C31/38

Abstract: Provided are methods of producing fluorinated alcohols from non-perfluorinated fluoroolefins and methanol. Certain preferred embodiments of such methods involve advantageously reacting a non-perfluorinated fluoroolefin with methanol under ambient-pressure and/or low-temperature conditions.

Abstract translation: 提供从非全氟化氟烯烃和甲醇制备氟化醇的方法。 这些方法的某些优选实施方案涉及在环境压力和/或低温条件下有利地使非全氟化氟烯烃与甲醇反应。