THERMOPLASTIC ELASTOMERS VIA REVERSIBLE ADDITION-FRAGMENTATION CHAIN TRANSFER POLYMERIZATION OF TRIGLYCERIDES
    5.
    发明申请
    THERMOPLASTIC ELASTOMERS VIA REVERSIBLE ADDITION-FRAGMENTATION CHAIN TRANSFER POLYMERIZATION OF TRIGLYCERIDES 审中-公开
    热塑性弹性体通过可逆添加分解链转移聚合物

    公开(公告)号:WO2014189939A2

    公开(公告)日:2014-11-27

    申请号:PCT/US2014/038799

    申请日:2014-05-20

    IPC分类号: C08F242/00

    摘要: The present invention relates to a thermoplastic block copolymer comprising at least one PA block and at least one PB block. The PA block represents a polymer block comprising one or more units of monomer A, and the PB block represents a polymer block comprising one or more units of monomer B, Monomer A is a vinyl, acrylic, diolefm, niirile, dinitrile, acrylonitrile monomer, a monomer with reactive functionality, or a crosslinking monomer. Monomer B is a radically polymerizable triglyceride or mixtures thereof, typically in the form of a plant or animal oil. The present invention aiso relates to a method of preparing a thermoplastic block copolymer or novel thermoplastic statistical copolymers by polymerizing a radically polymerizable monomer with a radically polymerizable triglyceride or mixtures thereof via reversible addition-fragmentation chain-transfer polymerization (RAFT), in the presence of an free radical initiator and a chain transfer agent.

    摘要翻译: 本发明涉及包含至少一个PA嵌段和至少一个PB嵌段的热塑性嵌段共聚物。 PA嵌段代表包含一个或多个单体单元A的聚合物嵌段,PB嵌段代表包含一个或多个单体单元B的聚合物嵌段,单体A是乙烯基,丙烯酸,二烯,二甲腈,二腈,丙烯腈单体, 具有反应性官能团的单体或交联单体。 单体B是可自由基聚合的甘油三酸酯或其混合物,通常为植物或动物油的形式。 本发明还涉及一种制备热塑性嵌段共聚物或新型热塑性统计共聚物的方法,其通过可逆加成 - 断裂链转移聚合(RAFT)将可自由基聚合的单体与可自由基聚合的甘油三酸酯或其混合物聚合, 自由基引发剂和链转移剂。