SULFONATED POLYMERS AND METHOD OF SULFONATING POLYMERS
    2.
    发明申请
    SULFONATED POLYMERS AND METHOD OF SULFONATING POLYMERS 审中-公开
    磺化聚合物和硫化聚合物的方法

    公开(公告)号:WO1997011989A1

    公开(公告)日:1997-04-03

    申请号:PCT/US1996013938

    申请日:1996-08-29

    Abstract: Methods of sulfonating a polymer are provided. One method of sulfonating a polymer includes exposing sulfur dioxide and oxygen to free radical producing energy and contacting the polymer with the product of preceding step. Desirably, the steps of exposing sulfur dioxide and oxygen to free radical producing energy and contacting the polymer with this product are performed in a reduced pressure environment. Another method of sulfonating a polymer includes contacting the polymer with sulfur dioxide and oxygen and exposing the contacted polymer to free radical producing energy. The polymer may be contacted with a mixture of sulfur dioxide and oxygen or the polymer may be separately contacted with sulfur dioxide and oxygen. When the polymer is separately contacted with sulfur dioxide and oxygen, the polymer may first be contacted with sulfur dioxide and then contacted with oxygen. The source of the free radical producing energy may be ultra-violet light, electron beam, noble gas radio frequency (rf) plasma, corona discharge, or gamma radiation.

    Abstract translation: 提供磺化聚合物的方法。 磺化聚合物的一种方法包括将二氧化硫和氧气暴露于自由基产生能量并使聚合物与前述步骤的产物接触。 理想地,将二氧化硫和氧气暴露于自由基产生能量并使聚合物与该产物接触的步骤在减压环境中进行。 磺化聚合物的另一种方法包括使聚合物与二氧化硫和氧接触并使接触的聚合物暴露于产生自由基的能量。 聚合物可以与二氧化硫和氧气的混合物接触,或者聚合物可以分开与二氧化硫和氧气接触。 当聚合物与二氧化硫和氧气分开接触时,聚合物可以首先与二氧化硫接触,然后与氧接触。 自由基产生能量的来源可以是紫外光,电子束,惰性气体射频(rf)等离子体,电晕放电或γ辐射。

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